• Title/Summary/Keyword: 화학종 분포

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Numerical Study of Heat and Mass Transfer Characteristics in Microchannel Steam Methane Reforming Reactor (마이크로채널 메탄 수증기 개질 반응기의 열 및 물질 전달 특성에 관한 수치해석 연구)

  • Jeon, Seung-Won;Lee, Kyu-Jung;Cho, Yeon-Hwa;Moon, Dong-Ju
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.9
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    • pp.885-894
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    • 2012
  • A numerical study of a microchannel steam methane reforming reactor has been performed to understand the characteristics of heat and mass transfer. The integration of Rh-catalyzed steam methane reforming and Pt-catalyzed methane combustion has been simulated. The reaction rates for chemical reactions have been incorporated into the simulation. This study investigated the effect of contact time, flow pattern (parallel or counter), and channel size on the reforming performance and temperature distribution. The parallel and counter flow have opposite temperature distribution, and they show a different type of reaction rate and species mole fraction. As the contact time decreases and channel size increases, mass transfer between the catalyst layer and the flow is limited, and the reforming performance is decreased.

Clinical Evaluation of the Primary Mediastinal Tumors and Cysts (원발성 종격동 종양 및 낭종의 임상적 고찰)

  • 이재덕;이계선
    • Journal of Chest Surgery
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    • v.29 no.7
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    • pp.763-768
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    • 1996
  • This report is an analysis of 43 cases of primary mediastinal tumors and cysts which were treated in the Department of Thoracic and Cardiovascular Surgery, Tae Jeon Eul li General Hospital from January, 1986 to April, 1995. There were 19 males and 24 females, and their ages ranged from 4 years to 68 years, with mean age of 31.3 years. The most common symptoms were dyspnea 48.8%, chest disconyort 39.5%, cough )4.9%, and chest pain 23.3%, and the most frequently encountered location of tumor was anterior mediastinum followed by posterior, and middle mediastinum. From the pathologic viewpoint, teratoma was the most frequent type followed by neurogenic tumors, cysts, thymoma, and Iymphoma. The most useful diagnostic method was plain X-ray examination of the chest, and final diagnosis could usually be made only after an operation. All of benign tumors were completely removed and malignant tumors were treated with chemotherapy and radiotherapy after operation There were 7 (16.3 %) cases of postoperative complications, and there was no postoperative mortality.

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Benthic Marine Algal Flora and Community Structure of Yongho-dong Area in Pusan, Korea (부산 용호동 일대의 저서 해조상 및 군집구조)

  • NAM Ki Wan;KIM Young Sik
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.32 no.3
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    • pp.374-384
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    • 1999
  • Benthic marine algal flora and community structure of Yongho-dong area in Pusan, Korea were investigated seasonally in intertidal and subtidal zones by a quadrat method along 5 transect lines from July 1996 to April 1997. In this area, a total of 99 species including 3 blue-green, 13 green, 26 brown and 57 red algae was found. Among them, 33 taxa, together with dominant Ulva pertusa and Corallina pilulifera, occurred throughout the year. Enteromorpha spp. and Ulva spp. vertically distributed in upper and middle zone, while Simphyocladia latiuscula, Chondria crassicaulis, Corallina pilulifera and Sargassum sup. in lower zones. Biomass per unit area exhibited a wide range of variation, from 1,241 g/$m^2$(spring) to 1,648 g/$m^2$(summer) in fresh weight. Maximum and minimum species diversity were recorded in spring and autumn, respectively. Results of the UPGAM cluster analysis suggest that the examined 5 sites can be divided into two groups, sites exposed to open sea (transects 1, 2, 3) and comparatively sheltered sites (transects 4, 5) faced with the Pusan Harbor. The former group is represented by large brown algae, Sargassum and Hizikia, while Ulva pertusa and Lomentaria species are mainly found in the latter group. A calcareous alga, Corallina pilulifera occurred dominantly in both groups throughout the year. In conclusion, number of species in this area was remarkably reduced as compared to the previous data. This result may suggest probably more change of algal vegetation in future, considering the physical and chemical pollutions loaded in the coastal marine environment of this area.

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Modeling for the fate of Organic Chemicals in a Multi-media Environment Using MUSEM (다매체 환경 모델 MUSEM을 이용한 유해화학물질의 환경거동예측 모델링)

  • Roh, Kyong-Joon;Kim, Dong-Myung
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.10 no.4
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    • pp.201-210
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    • 2007
  • Pollution by chemical substances such as POPs, EDCs and PBTs in the ecosystem has become more complex and varied, increasing the possibility of irreversible damage to human health or the ecosystem. It is necessary to have a exposure assessment in a multi-media environment for various chemical substances is required for efficient management. This study applied MUSEM(Multi-media Simplebox-systems Environmental Model), a multimedia environmental model that can simultaneously evaluate the possibility of exposure of hundreds of chemical substances in order to efficiently manage chemical substances that can have negative impact on human health or ecological environment through environmental contamination. MUSEM executed the modeling for Japan by setting all 47 prefectures of japan as the regional area for 62 chemical substances and the rest of the territory of japan, excluding regional area, as the continental area and made the estimation of concentration among environment media in each administrative area and made the sensitivity analysis on Tokyo area. The results of simulation for chemical distribution showed that most of the target chemicals located in water region. The result of sensitivity analysis for octanol-water partition rate showed that the concentration change of soil in urban/industrial area and sediment in freshwater was high. In the case of sensitivity analysis for degradation rate showed that the concentration change of freshwater, soil in urban/industrial area, and sediment in freshwater was high.

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The Limnological Survey of a Coastal Lagoon in Korea (3): Lake Hwajinpo (동해안 석호의 육수학적 조사 (3): 화진포호)

  • Kwon, Sang-Yong;Lee, Jae-Il;Kim, Dong-Jin;Kim, Bom-Chul;Heo, Woo-Myung
    • Korean Journal of Ecology and Environment
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    • v.37 no.1 s.106
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    • pp.12-25
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    • 2004
  • Physicochemical parameters, plankton biomass, and sediment were surveyed from 1998 to 2000 at two months interval in a eutrophic coastal lagoon(Lake Hwajinpo, Korea). The lake is separated from the sea by a narrow sand dune. Littoral zone is well vegetated with leafing-leaved aquatic plants. The lake basin is divided into two subbasins by a shallow sill. It has intrusion of seawater by permeation and stormy waves. Stable chemoclines are formed by salinity difference at 1m depth all the year round. DO was often very low (< 1 mg$O_2\;L^{-1}$) at hypolimnion. Temperature inversions were observed in November. Nitrate and ammonium concentrations were very low(< (1.1 mgN $L^{-1}$), even though TN was usually 2.0 ${\sim}$ 3.5 mgN $L^{-1}$. TN/TP was generally lower than the Redfield ratio. Transparency was 0.2 ${\sim}$ 1.7 m, and COD, TP, and TN of sediment were 3.1 ${\sim}$ 40.3 mg$O_2\;g^{-1}$, 0.91 ${\sim}$ 1.39 mgP $g^{-1}$, and 0.34 ${\sim}$ 3.07 mgN $g^{-1}$, respectively. Phytoplankton chlorophyll- a concentrations were mostly over 40 mg $m^{-3}$. Two basins showed different phytoplankton communities with Oscillatoria so., Trachelomonas sp., Schizochlamys gelatinosa, and Anabaena spiroides dominant in South basin, and with Trachelomons sp., Schroederia so., schizochlamys gelatinosa, and Trachelomonas sp. dominant in the North basin. The seasonal succession of phytoplankton was very fast, possibly due to sudden changes in physical conditions, such as wind, turbidity, salinity and light.

Taxonomical and Ecological Study on the Vegetation of the Seungbong Island (승봉도 식물상에 관한 분류 및 생태학적 연구)

  • Lee, Ho Joon;Seon Choel Choi;Young Hee Lee
    • Journal of environmental and Sanitary engineering
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    • v.5 no.2
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    • pp.105-116
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    • 1990
  • Seungbong Island is situated about 100km away Inchon Port in the western sea of the Korean Peninsula. Field investigations were conducted for two days each from June 30 through July 1, 1981 and from August 20 through 21, 1981. The results obtained are summarized as follows: Plants growing in this island consist of a total of 193 species (70 families, 151 genera, 170 species, 22 varieties and 1 forma). Pinus thunbergii was confirmed to be the dominant species. The natural degree observed in this island was high, as a whole. The coefficient of ferny plants (Pte-Q) is 0.95, lower than grass. Atractylodes japonica Koidz., Miscanthus sinensis Anders. var. purpurascense Rendle, and Rhododendron mucronulatum Turz. are distributed mainly on the forest bed of Pinus thunbergii. The poor distribution of Chenopodium album var. centrorubrum Makino, Setaria viridis (L.) Beauv., Amaranthus mangostanus Linne is considered attributable to the phenomenon of allellopathy caused by a chemical substance secreted from the leaves of Pinus thunbergii. The component ratio of species in this island is lower than that of other islands due probably to the small area of arable land and grassland. The poor growth of plants in the forest of Pinus thunbergii, the dominant species in this island, seems to be attributed to the low relative light intensity of the forest. Seaside plants consisting of a total of 7 species were distributed mainly in the vicinity of sandy beaches. Naturalized plants comprising a total of 11 species were relatively diversified in the number of species.

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Chemical Water Quality and Multi-metric Eco-health Model Assessments in Baekma River (백마강의 화학적 수질특성 및 다변수 생태 건강도 모델 평가)

  • Han, Jeong-Ho;Kim, Hyun-Mac;An, Kwang-Guk
    • Korean Journal of Environmental Biology
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    • v.31 no.2
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    • pp.96-104
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    • 2013
  • The objectives of this study were to analyze chemical the water quality related to the fish community and to evaluate the ecosystem health based on the faunal composition and guild structure in 2007 in Baekma River. Mean concentrations of biological oxygen demand (BOD) and chemical oxygen demand (COD) were 2.8 and $4.0mg\;L^{-1}$, respectively and total nitrogen (TN) and total phosphorus (TP) were $5.0mg\;L^{-1}$ and $158{\mu}g\;L^{-1}$, which is indicating that the river is in an eutrophic state. Especially, organic pollution and eutrophication occurred in the downstream reach of Baekma River. A total of 19 fish species were collected during the study and the most dominant species was Opsariichthys uncirostris amurensis accounted 48% of the total abundances. The proportion of sensitive species was low (2.3%), compared with that of tolerant species (71.8%). These results suggest that tolerant species and the biotic quality of the fish community was severely degraded. According to the multi-metric model, the Index of Biological Integrity (IBI), the mean model value of the fish community in Baekma River was estimated as 14.8 indicating a "poor" condition. The minimum values of the IBI were observed in the downstreams, and this was mainly attributed to chemical pollutions of nutrients (N, P) and organic matters.

Vegetation of Liana Dominating in the Vicinity of Onsan Industrial Complex (공단지역에 우점하고 있는 덩굴식물류의 식생변화)

  • Park, Eun-Hee;Kim, Jong-Kab;Lee, Jeong-Hwan;Cho, Hyun-Seo;Min, Jae-Ki
    • The Korean Journal of Ecology
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    • v.27 no.6 s.122
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    • pp.335-345
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    • 2004
  • This study was carried out to on liana dominating at the vicinity of Onsan Industrial Complex declining P. thunbergii foersts. It was surveyed 16 species, 30 species and 50 species at upper, middle and understory, respectively. It was dominant P. thunbergii at upperstory, and P. densiflora, P. thunbergii, Quercus dentata and Q. serrata at middlestory, and Smilax china, Paederia scandens, Symplocos chinensis var. sinuata, Styrax japonica, Lonicera japonica and Q. serrata etc. at understory. It was the highest importance value(13.2) of S. china among all liana, and in order of L. japonica (11.7), P. scandens (11.5) and Cocculus trilobus (7.7). Number of species, Species diversity, Maximum species diversity, Evenness and Dominance of woody plants at upperstory and middlestory by each survey site were higher in forest areas than industrial complex, but those of understory highly showed at industrial complex, and ratio of liana at understory was high. It showed total 50 species at herbaceous plants, and was high I.V. of Pteridium aquilinum var. latiusculum, Spodiopogon cotulifer, Commerelina commuris, Phytolacca americana, Rubus parvifolius, Miscanthussinensis var. purpurascens and Calamagrostis arundinacea, etc.

Target candidate fish species selection method based on ecological survey for hazardous chemical substance analysis (유해화학물질 분석을 위한 생태조사 기반의 타깃 후보어종 선정법)

  • Ji Yoon Kim;Sang-Hyeon Jin;Min Jae Cho;Hyeji Choi;Kwang-Guk An
    • Korean Journal of Environmental Biology
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    • v.41 no.2
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    • pp.109-125
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    • 2023
  • This study was conducted to select target fish species as baseline research for accumulation analysis of major hazardous chemicals entering the aquatic ecosystem in Korea and to analyze the impact on fish community. The test bed was selected from a sewage treatment plant, which could directly confirm the impact of the inflow of harmful chemicals, and the Geum River estuary where harmful chemicals introduced into the water system were concentrated. A multivariable metric model was developed to select target candidate fish species for hazardous chemical analysis. Details consisted of seven metrics: (1) commercially useful metric, (2) top-carnivorous species metric, (3) pollution fish indicator metric, (4) tolerance fish metric, (5) common abundant metric, (6) sampling availability (collectability) metric, and (7) widely distributed fish metric. Based on seven metric models for candidate fish species, eight species were selected as target candidates. The co-occurring dominant fish with target candidates was tolerant (50%), indicating that the highest abundance of tolerant species could be used as a water pollution indicator. A multi-metric fish-based model analysis for aquatic ecosystem health evaluation showed that the ecosystem health was diagnosed as "bad conditions". Physicochemical water quality variables also influenced fish feeding and tolerance guild in the testbed. Eight water quality parameters appeared high at the T1 site, indicating a large impact of discharging water from the sewage treatment plant. T2 site showed massive algal bloom, with chlorophyll concentration about 15 times higher compared to the reference site.

An Analysis of STS Materials in Chemistry Parts of Middle School Science Textbooks (제 6차 교육과정에 따른 중학교 과학 교과서(화학단원)의 STS 내용 분석)

  • Kim, Yun Hi;Kwon, Hyo Jin;Moon, Seong Bae
    • Journal of the Korean Chemical Society
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    • v.43 no.3
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    • pp.321-327
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    • 1999
  • The STS materials, emphasized in the 6th curriculum, in the chemistry part of middle school science textbooks were analyzed. The average value of the STS content of textbook was 13.2%. In the study of chapter of textbook, 15.9% of STS materials was included in the chapter of ?reaction of materials?, 12% in "character and separation of materials", and 10.8% in "composition of materials". When the STS topics classified by Piel were analyzed, the results were as follows; 40.2% on sociology of science, 28.8% on environmental quality and utilization of natural source, 20.4% on effects of technological developments, and 12.9% on energy. However, the topic on human engineering was only included in a textbook, and the topics on space research and national defence were not included in any textbooks. When the STS materials were analyzed by student activities of SATIS, the number of activities was 71. Most activities were consisted of solving problems and decision, simulation and data analysis, and there was no research design and role playing.

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