• 제목/요약/키워드: 화학적 열화

검색결과 356건 처리시간 0.027초

Mesurement on Pollution Property of Polymer Composite Materials (고분자 재료의 오손 특성 측정)

  • 김한주;김규식;박종은;류부형;박대희;손원근;박수길
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 한국전기전자재료학회 1999년도 춘계학술대회 논문집
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    • pp.454-458
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    • 1999
  • 절연재료의 성능 개선과 전력계통의 신뢰성을 확보하기 위해 고분자 재료가 많이 사용되고 있다. 고분자 절연재료는 절연저항 및 절연파괴 강도가 우수하며, 유전손실이 낮고 기계적 강도가 우수하며 대량생산 및 제조가 용이하고, 경량이며 유지비용이 절감되는 등의 장점이 있으나 연구의 역사가 짧고 운전 실적이 적어 불분명한 점이 많으며, 내열성 및 내트랙킹성이 비교적 약하며 표면에 오손이 축적되어 열화가 발생, 진행되거나 수분침투에 의한 파괴사고가 발생하는 단점이 있다. 따라서, 고분자 절연재료의 기본적인 화학적 구조 및 인공적 인 오손 환경을 만들어, 오손 환경의 농도 및 시간대별로 오손환경하에서 우수한 특성을 보이는 샘플을 이용하여 LDPE전체에 대한 실험을 진행했다. 또한 측정법으로서는 화학적인 구조 및 함량을 측정하기 위하여 FT-lR, DSC, TGA를 이용했고, 전기적인 측정으로서는 각각의 조건별로 전도도 및 부분방전특성을 평가하였다.

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Degradation of Cement Mortar with Supplementary Cementitious Materials Submerged in Various Oils (각종 유지류에 침지된 혼화재 치환 시멘트 모르타르의 열화특성)

  • Han, Cheon-Goo;Hwang, Chan-Woo
    • Journal of the Korean Recycled Construction Resources Institute
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    • 제5권2호
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    • pp.137-143
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    • 2017
  • There has been a number of research on concrete durability. specially, as a research on chemical ingression, the research on the degradation against acid, alkali, and sulfate has been conducted. On the other hand, for the research on oils, especially, the influence of various oils on cement mortar with Supplementary Cementitious Materials(SCMs) is not sufficiently studied. hence, in this research, the degradation of cement mortar incorporated fly ash and blast furnace slag is researched when the cement mortar is submerged in various oils. For the result of experiment, as the content of fatty acid in the oils, the degradation of cement mortar with SCMs was occurred more, and the cement mortar with SCMs suffered more degradation than the ordinary portland cement regarding the oil submerging.

고분자절연재료의 방전열화

  • 이덕출
    • 전기의세계
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    • 제25권6호
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    • pp.40-44
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    • 1976
  • 근대산업의 에너지원으로서 전력수요의 급격한 증대에 수반하여 전력계통의 초고전압화, 관련기기의 소형화 및 장기간에 걸친 성능의 안정성, 신뢰성이 절실히 요망 하겠금 되었다. 이로 인하여 전기절욘재료에 요구되는 제성능도 일반적으로 고도화되고 점점 가혹한 조건이 부가되고 있는 실정이라 하겠다. 근년 고분자화학의 급속한 진보와 고분자성형기술의 발달에 의하여 등장한 합성고분자재료는 그 물리, 화학적 성질 특히 전기적 성질에 많은 특징을 가지고 있으며 그 성능이 점점 높이 평가되고 있어 고분자재료의 진출이야말로 전기기기절연의 양상에 일대 변화를 줄것이라 하여도 지나친 표현이 아니겠다. 이와같이 고분자가 전기절연재료로써의 가치는 물가구조로 부터 기대되는 우수한 유전성과 전기절연성이 높이 평가되고 있는 점이라 하겠다.

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Evaluation of Deterioration of Epoxy Primer for Steel Bridge Coating using Image Processing and Electrochemical Impedance Spectroscopy (화상처리 기법과 전기화학적 임피던스 분광법을 이용한 강교 도장용 에폭시 하도 도료의 열화 평가)

  • Lee, Chan Young;Lee, Sang Hun;Park, Jin Hwan
    • Corrosion Science and Technology
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    • 제8권2호
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    • pp.53-61
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    • 2009
  • In this study, both evaluations by visual imaging for exterior view of coating and by EIS were executed for epoxy primer coated specimens deteriorated by accelerated test, and comparison and analysis were carried out for 2 evaluation methods. In the comparison between total damaged area ratio acquired by image processing method and deterioration point, higher deterioration points were appeared for rusted specimens than for non-rusted specimens. It is attributed that deterioration point per unit area ratio given for rust is higher than for peeling. In the comparison between total damaged area ratio and EIS result, impedance of coating was largely decreased as about TEX>$10^4{\Omega}{\cdot}cm^2$ or less when rust area ratio is more than about 0.1%, and blistering area ratio is more than about 3%. Charge transfer resistance ($R_{ct}$) and double layer capacitance ($C_{dl}$) values were appeared for all specimens except 2 ones, which shows that water is accumulated and steel substrate is corroded at coated film-steel interface. In the comparison between deterioration point and EIS result, more than 10 points as deterioration point were given for specimens of below $10^6{\Omega}{\cdot}cm^2$ of impedance at low frequency. For specimens deteriorated by NORSOK cyclic test, impedance was lowest of all, though deterioration point was not high. It is thought to be attributed that coating system and accelerated deterioration condition of cyclic tested specimens were different from those of main specimens. From the result, it is thought that coating resistance can be relatively more decreased than deterioration degree estimated from exterior view under more severe corrosion environment or in the present of more complex deterioration factors.

A Preservation of Materials for the Records (자료매체의 보존성)

  • 신종순;최찬호
    • Journal of the Korean BIBLIA Society for library and Information Science
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    • 제12권2호
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    • pp.71-84
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    • 2001
  • The purpose of this study is to provide the methods of preservation for paper, microfilm, digital media. First of all, for acidic papers produced in 19~20 centuries, this study evaluates and analyses deterioration and factors causing deterioration. For book, also, environmental condition for preservation, and a preservation mechanism through acid-free procedure were suggested. Second for microfilm, it emphasized physical and chemical properties, oxidised substance during developing film, materials related to preservation. Third, for digital storages, storage conditions and needs, such as life-cycle and capacity were introduced.

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Fault Diagnosis of M.tr using Acoustic Sensor Technique (초음파 기술을 이용한 변압기 이상상태 진단)

  • Jeong, Jae-Ki;Yoon, Si-Young;Kang, Chang-Ik;Jin, Young-Eun
    • Proceedings of the KIEE Conference
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    • 대한전기학회 2007년도 제38회 하계학술대회
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    • pp.744-745
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    • 2007
  • 변압기를 진단하는 분석 요소 중 흔히 사용하는 방법으로 유중가스분석을 이용하는 방식을 많이 사용하고 있다. 유중가스 분석은 변압기 내 Oil이 열과 Arc등에 의해 화학적으로 변화된 것을 측정하여 열화 정도를 추정하는 방식이지만 신속한 검출 및 위치추정이 불가능하다는 단점이 있다. 신속한 검출이 되지 않으면 신속한 보고가 이루어 질 수 없으므로 변압기 교체시점을 맞추지 못하여 사고로 인한 막대한 피해보상이 발생한다. 이런 단점을 보완하기 위해 변압기내 부분방전 및 Arc에 의해 발생하는 부분방전신호를 초음파 대역에서 검출하여 열화 및 위치를 추정할 수 있는 초음파 분석이 필요하게 되었고 실험을 통해 변압기에 대한 분석, 진단을 시행하였다.

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The Study on the New Renewal Methods for Rehabilitation of Deteriorated Sewerage by Chemical Attacks (화학침식에 의해 열화된 하수관로 갱생 공법에 관한 연구)

  • Lee, Hee Won
    • The magazine of the Korean Society for Advanced Composite Structures
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    • 제5권3호
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    • pp.38-52
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    • 2014
  • 도시주민생활에 없어서는 안 될 주요한 사회간접자본시설인 하수도, 하수도처리시설 등의 콘크리트 구조물에 대한 부식열화는 현재 세계 각국에서 급속히 진행되고 있다. 콘크리트 구조물은 반영구적인 것으로 인식하고 있다. 그러나 각종 열화 인자에 의해 구조물의 사용수명은 급속히 단축된다. 하수시설 내에서는 황산이외에도 다양한 염류에 의하여 콘크리트구조물이 부식될 가능성이 있지만 황산에 의한 부식이 가장 대상범위가 넓고 부식속도가 빠르기 때문에 부식현상이 발견되면 급속하고 적절한 대응조치가 필요하다. 열화예측결과 및 구조물의 공용연수를 감안한 신뢰성이 높은 공법의 도입이 필요하며 이러한 조건에 적합한 유기재료와 무기재료의 복합 특성을 발휘하는 갱생공법에 사용되는 주요 소재의 실험적 특성에 관하여 고찰하였다. 그 결과 경질염화비닐(이하 프로파일)은 내외수압 저항성에서 3분간 $1kgf/cm^2$의 압력에도 누수 및 압력의 이동이 없었으며 약품침지에 따른 중량변화량이 $0.2mg/cm^2$이하로 산에 대한 변화량은 거의 없었다. 주입재인 모르타르의 산성에 대한 저항성은 일반 콘크리트에 비해 우수하였으며 기존 모르타르에 비해 비확선성 또한 우수하였다. 장거리압송시험은 200m까지 안정적인 압송이 가능하여 이 기술에 필요한 요구 성능을 확보한 것으로 나타났다.

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Differences of Physical, Mechanical and Chemical Properties of Korean Red Pine(Pinus densiflora) Between Old and New Wood (소나무 고목재와 건전재의 물리, 기계, 화학적 특성 차이)

  • Shim, Kug-Bo;Lee, Do-Sik;Park, Byung-Soo;Cho, Sung-Taig;Kim, Kwang-Mo;Yeo, Hwan-Myeong
    • Journal of Korea Foresty Energy
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    • 제25권2호
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    • pp.1-8
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    • 2006
  • The physical, mechanical and chemical properties of old and new Korean red pine (Pinus densiflora) were analyzed. The old woods were from dismantled timbers of Bonjungsa temple. The crystallized resin in the latewood was observed by microscopic analysis. Also, reduction of specific gravity, occurrence of microscopic cleavage of tracheid was observed in the old wood. The angle of microscopic cleavage of tracheid is estimated with the same angle of micro-fibril angle of 52 layer. The bending, compression and shear strength of old world were decreased about 35-27% than those of new wood. Dynamic modulus of elasticity measured by ultrasonic nondestructive test has the tendency of reducing by the time elapse of the wood usage. Therefore, deterioration of wood could be measured by reduction of specific gravity and dynamic MOE. The static MOE and mechanical properties of old wood could be predictable by measuring dynamic MOE in the longitudinal direction. Extractives of the old wood in 1-% NaOH solution are larger quantity than new wood. Therefore the decay of the wood could be evaluated by analyzing the chemical compound, especially 1-% NaOH solution. The results of this research could be used for understanding and prediction of the changing properties with elapsing time of wood.

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UV Degradation Characteristics and Applicability of Coating Agent for Conservation of FRP Artifacts (FRP 작품 보존을 위한 자외선 열화 특성 및 자외선 차단 코팅제 적용 연구)

  • Han, Ye Bin;Chung, Yong Jae
    • Journal of Conservation Science
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    • 제33권3호
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    • pp.203-214
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    • 2017
  • This study evaluated the degradation characteristics of FRP by ultraviolet (UV) rays and applied a UV-resistant coating to prevent the degradation of the surface of these sculptures. As a result of the degradation caused by UV rays, there were slight changes in the FRP surface and contact angle. The chromaticity sharply increased in the early phase of degradation. After applying the coating to the FRP, no significant surface changes were observed. However, it had lower changes in color as compared to the uncoated specimen, so it was verified that the control of discoloration could be possible. Some changes in the gloss and contact angle were observed depending on the extent of degradation, but the UV coating agent remained relatively stable. Analysis of the infrared light spectrum showed that there were almost no chemical changes, and it could be concluded that the coating treatment prevented degradation for a certain period. This study investigated the degradation of FRP used as materials in artwork exposed to UV rays, and it was found that there was a delay in the onset of degradation in the FRP with the UV-resistant coating when compared to the uncoated FRP.

Effects of Changes in Accelerated Degradation Conditions for Catalyst Supports in Polymer Electrolyte Fuel Cell (고분자전해질 연료전지(PEMFC)에서 촉매 지지체 가속 열화 조건 변화의 영향)

  • Sohyeong Oh;Yuhan Han;Donggeun Yoo;Myoung Hwan Kim;Ji Young Park;Youngjin Choi;Kwonpil Park
    • Korean Chemical Engineering Research
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    • 제62권1호
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    • pp.7-12
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    • 2024
  • The durability of the catalyst support has a significant effect on the durability of proton exchange membrane fuel cells (PEMFC). The accelerated durability evaluation of the catalyst support is performed at a high voltage (1.0 to 1.5 V), and the catalyst and ionomer binder in the catalyst layer are also deteriorated, hindering the evaluation of the durability of the support. The existing protocol (DOE protocol) was improved to find conditions in which the support, which is a durability evaluation target, deteriorates further. A protocol (MDOE) was developed in which the relative humidity was lowered by 35% and the number of voltage changes was reduced. After repeating the 1.0 ↔ 1.5 V voltage change cycle, the catalyst mass activitiy (MA), electrochemical active area (ECSA), electrical double layer capacity (DLC), Pt dissolution and particle growth were analyzed. Reaching 40% reduction in mass activity, the MDOE protocol took only 500 cycles, reducing the number of voltage changes compared to the DOE method and increasing the degradation of the carbon support by 50% compared to the DOE protocol.