• Title/Summary/Keyword: 화학적산소요구량

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환경기술코너-방류수 수징 원격감시체계(TMS) 시범운영

  • Lee, Gyeong-Jin;Jo, Jae-Won;Hyeon, Mun-Sik;Gwon, Bong-Gyeong;Choe, Jun-Chang
    • Bulletin of Korea Environmental Preservation Association
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    • v.29 s.367
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    • pp.42-46
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    • 2007
  • 최근 수질환경보전법의 개정법률(안)에 의거하여 폐.하수종말처리장에 수온, pH, 생물학적산소요구량(BOD), 화학적산소요구량(COD), 총질소(TN), 총인(TP) 및 부유물질(SS)의 자동으로 측정할 수 있는 수질자동측정기의 부착이 의무화될 예정에 있다. 그러나, 현재 전국적으로 화학적산소요구량 측정장비와 같이 일부 항목에 대한 자동측정장치는 설치.운영 중인 곳이 많이 있으나, 수질 TMS 설치 규정에 나와 있는 전 항목을 측정할 수 있는 장비가 설치되어 운영하는 곳은 극히 일부에 불과한 실정이다. 따라서, 수온, pH, 화학적산소요구량(COD), 총질소(TN), 총인(TP), 부유물질(SS) 자동측정 장치를 설치하고, 무선통신(CDMA) 방식을 이용하여 '방류수 수질 원격감시체계(TMS) 시범 운영'을 통하여, 측정 장비들에 대한 자료의 정확성, 신뢰성을 파악하여 설치될 장비들에 대한 성능을 사전에 평가하고, 수질 TMS 시스템에 대한 현장 적응 능력 및 안정성을 파악하여 실질적으로 운영되는 시점에 좀 더 정확하고 실용적인 시스템을 적용하고자 한다.

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방류수 수질 원격감시체계'TMS' 시범 운영

  • Lee, Gyeong-Jin;Jo, Jae-Won;Gwon, Bong-Gyeong;Choe, Jun-Chang
    • Environmental engineer
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    • v.23 s.244
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    • pp.56-60
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    • 2006
  • 최근 수질환경보전법의 개정법률(안)에 의거하여 폐 · 하수종말처리장에 수온, pH, 생물학적산소요구량(BOD), 화학적산소요구량(COD), 총질소(TN), 총인(TP) 및 부유물질(SS)의 자동으로 측정할 수 있는 수질 자동측정기의 부착이 의무화될 예정에 있다. 그러나, 현재 전국적으로 화학적산소요구량 측정장비와 같이 일부 항목에 대한 자동측정장치는 설치 · 운영 중인 곳이 많이 있으나, 수질 TMS 설치 규정에 나와 있는 전 항목을 측정할 수 있는 장비가 설치되어 운영하는 곳은 극히 일부에 불과한 실정이다. 따라서, 수온, ph, 화학적 산소요구량(COD), 총질소(TN), 총인(TP), 부유물질(SS) 자동측정 장치를 설치하고, 무선통신(CDMA)방식을 이용하여 ‘방류수 수질 원격감시체계(TMS) 시범 운영'을 통하여, 측정 장비들에 대한 자료의 정확성, 신뢰성을 파악하여 설치된 장비들에 대한 성능을 사전에 평가하고, 수질 TMS 시스템에 대한 현장 적응 능력 및 안정성을 파악하여 실질적으로 운영되는 시점에 좀 더 정확하고 실용적인 시스템의 적용하고자 한다.

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Study on monitoring and prediction for the occurrence of red tide in the middle coastal area in the South Sea of Korea II: (원격탐사를 이용한 한국 남해 중부해역에서의 적조 예찰 연구 II: 적조발생과 해양인자간의 상관성 연구)

  • 윤홍주;김승철;김영섭;김상우
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2002.11a
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    • pp.505-509
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    • 2002
  • 남해 중부해역에서 적조발생과 관련해서 적조 다발월인 여름과 초가을에 기온과 마찬가지로 높은 수온을 유지한다. 또한 많은 강수량에 의하여 부유물질 및 영양염류가 증가하고 염분이 대체로 떨어지는 것을 알 수 있었다. 이때 적조의 bloom으로 인하여 대표적인 영양염류인 질소와 인의 값이 떨어진다. 그리고 적조생물의 사후 미생물 분해 작용이 활발하여 산소의 소모가 증가하여 용존산소가 급격히 떨어지고 화학적산소요구량이 높게 나타나는 것을 알 수 있었다. 즉, 해양인자와의 상관성은 적조의 발생조건인 수온이 적당하며 저염분과 부유물질, 클로로필, 질소, 인이 높게 나타났고 용존산소는 적조생물의 인해 낮게 나타났음을 알수 있었다.

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Long-term Variation and Characteristics of Water Quality in the Gunsan Coastal Areas of Yellow Sea, Korea (군산연안 수질환경의 특성과 장기변동)

  • Park, Soung-Yun;Choi, Ok-In;Kwon, Jung-No;Jeon, Kyeong-Am;Jo, Jo-Yeong;Kim, Hyung-Chul;Kim, Pyoung-Joong;Park, Jong-Soo
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.15 no.4
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    • pp.297-313
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    • 2009
  • Long-term trends and distribution patterns of water quality were investigated in the Gunsan coastal areas of Yellow Sea, Korea from 1972 to 2006. Water samples were collected at 6 stations and physicochemical parameters were analyzed including water temperature, salinity, suspended solids(SS), chemical oxygen demand(COD), dissolved oxygen(DO) and nutrients. Spatial distribution patterns of temperature, DO and SS were not clear among stations but the seasonal variations were distinct except COD and SS. The trend analysis by principal component analysis(PCA) during 24 years revealed the significant variations in water quality in the study area. Spatial water qualities were clearly classified into 3 clusters by PCA; station cluster 1, 2~4, and 5~6. Annual water qualities were clearly classified into 4 surface water clusters and 5 bottom water clusters by PCA. By this multi-variate analysis. The annual trends were summarized as follows; Salinity, pH and DO tended to increase since late 1970's, COD to increase since 1987, and SS to decrease and nutrients to increase in Gunsan coastal waters due to the input of fresh water from land same as in Kyoungin coastal area, Asan coastal area and Choensoo bay.

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Long Tenn Water Quality Prediction using an Eco-hydrodynamic Model in the Asan Bay (생태-유체역학모델을 이용한 아산만 해양수질의 장기 예측)

  • Kwoun, Chul-Hui;Kang, Hoon;Cho, Kwang-Woo;Maeng, Jun-Ho;Jang, Kyu-Sang;Lee, Seung-Yong;Seo, Jeong-Bin
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.15 no.2
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    • pp.91-98
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    • 2009
  • The long-term water-quality change of Asan Bay by the influx of polluted disposal water was predicted through a simulation with an Eco-hydrodynamic model. Eco-hydrodynamic model is composed of a multi-level hydrodynamic model to simulate the water flow and an ecosystem model to simulate water quality. The water quality simulation revealed that the COD(Chemical Oxygen Demand), dissolved inorganic nitrogen(DIN) and dissolved inorganic phosphorus(DIP) are increased at 5 stations for the subsequent 6 months after the influx of the effluent. COD, DIN and DIP showed gradual decreases in concentration during the period of one to two years after the increase of last 6 months and reached steady state for next three to ten years. Concentration levels of COD, DIN, and DIP showed the increase by the ranges of $11{\sim}67%$, $10{\sim}67%$, and $0.5{\sim}7%$, respectively, which represents that the COD and DIN are the most prevalent pollutants among substances in the effluent through the sewage treatment plant. The current water quality of Asan Bay based on the observed COD, TN and TP concentrations ranks into the class II of the Korean standards for marine water quality but the water quality would deteriorate into class III in case that the disposal water by the sewage plant is discharged into the Bay.

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Evaluation of Organic Sediments Qualities for the Urban Streams in the Busan City (부산시 하천퇴적물의 유기 오염도 평가)

  • Lee, Jun-Ki;Kim, Seog-Ku;Song, Jae-Hong;Lee, Tae-Yoon
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.11
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    • pp.975-982
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    • 2009
  • The purpose of this study is to offer informations about the current conditions and basic data of stream sediments in Busan city. So we first select 14 urban streams and collect sediment samples. Then, COD, proximate analysis, volatile solid, organic carbon content and elemental analysis were conducted to determine characteristics of the sediments. Results show that COD, volatile solid, Organic carbon content, T-N of sediment are determined in the range of 1.20~75.07 mg/g, 0.19~11.54%, 0.23~34.21% and 0.76~3.46%, respectively. Analysis data of sediments were compared with USEPA sediment quality standards and ontario sediment quality guidelines. As a result, when compared with COD, volatile solid and organic carbon content values, Bosucheon and Gudeokcheon are relatively heavily contaminated than the remainder sampling sites. But when compared with T-N values, all of sites were evaluated as seriously contaminated. Finally, for the determination of the correlations between sediment COD and moisture contents, ash contents, volatile solid, total organic carbon, total nitrogen and total carbon, linear model was fitted to the data using a least-squares algorithm. As a result, Linear model was well fitted to each data with good values of the correlation coefficient (r=0.9664~0.8501).

A Study on the Origin of Organic Matter in Seawater in Korean Estuaries Using Chemical Oxygen Demand (화학적산소요구량을 이용한 하구해역의 해수중 유기물 기원 고찰)

  • Kim, Young-Sug;Koo, Jun-Ho;Kwon, Jung-No;Lee, Won-Chan
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.24 no.6
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    • pp.735-749
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    • 2018
  • In this study, one studied the principal factors and water-quality components that determine the concentration of chemical oxygen demand (COD) in seawater in estuaries, such as the Han, Geum, Youngsan, Seomjin, and Nakdong rivers in Korea. The principal factors determining the concentration of COD in seawater indicated by the principal component analysis were salinity, exogenous origin and autochthonous resources based on chlorophyll-a. Moreover, organic matter in the submarine sediment layer also had a secondary effect. Regression slope assessed the contribution of water-quality components to determine the concentration of COD in the estuary. One found that the effect of salinity on the overall survey was significant. Moreover, the effect of chlorophyll-a was also appeared in April and August. In each estuary, the most significant contribution factor was chlorophyll-a in the Nakdong River and salinity in the Han and Yongsan rivers. The contribution of salinity and chlorophyll-a were found to be the largest in the Geum River. The salinity and chlorophyll-a in the Seomjin River showed a low contribution.

Comparison of the Methods to Analyze Freshwater Sediments (담수 퇴적물의 분석법간 비교 분석)

  • Yoon, Byeng-Seok;Kim, Eun-Mi;Kim, Hak-Chul;Lee, Jae-Hee;Jung, Sang-Gi;Lee, Sang-Tae
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.11
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    • pp.1207-1212
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    • 2006
  • In this study, Chemical Oxygen Demand(COD) which is the measure of organic substances, Total nitrogen(T-N), Total phosphorous(T-P), Fe and Mn were analyzed in the sediments of dam reservoir. The purpose of this study were to understand the relevances among the analytical methods adopted and the applicabilities of those methods. For the determination of COD, Standard Method for the Examination of Marine Environment(SMEME) and Standard Method for the Examination of Sanitary(SMES) was used. Both method had wide dynamic range and the deviations of the values obtained by two methods were small because $KMnO_4$ method closely reflected BOD and organic substances. For the determination of T-N and T-P, Standard Method for the Examination of Food(SMEF) and Standard Method for the Examination of Sanitary(SMES) were used. Two methods for T-N were both the acid-base titration but SMES gave less T-N values than SMEF because of the differences in digestion and distillation steps. Two methods for T-P gave the comparable values after acid digestion of $HNO_3$ and $HClO_4$. The determination of heavy metals as a Fe, Mn was mainly divided to the leaching method and acid digestion method. The values obtained by leaching method were less than those by digestion method. It is thought that the condition of acid digestion was more severe than that of leaching method.

Flocculating Activity and Dehydration Efficiency of Biopolymer Flocculant Biopol32 in Industrial Wastewater Treatment (생물고분자응집제 Biopol32의 산업폐수에 대한 응집활성 및 탈수효과)

  • Lee, Myoung Eun;Oh, Nara;Suh, Hyun-Hyo
    • Journal of Life Science
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    • v.29 no.3
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    • pp.362-368
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    • 2019
  • For the practical application and development of biopolymer flocculant Biopol32 produced by Pseudomonas sp. GP32, its flocculation effect on wastewater from food processing, slaughter houses, and the dyeing industry was investigated. In the food processing wastewater, Biopol32 led to a chemical oxygen demand (COD) reduction rate of 70% and a suspended solid (SS) removal rate of 49% at pH 6.0. In the slaughter house wastewater at pH 4.0, a COD reduction rate of 61% and SS removal rate of 91% were observed, and in the dyeing wastewater, the rates were 72% and 92%, respectively, at pH 5.0. The size of floc formed during the flocculation process was 10 mm at a final concentration of 20 ppm, and the dehydration efficiency was 62%. In both the bioflocculant Biopol32 group and a PAA synthetic flocculant group, optimal flocculant concentration that yielded the best overall dehydration efficiency was 20 ppm, and, at this concentration, the shortest filtration time to reach the natural critical moisture content of 78.1% was attained.

Characteristics and Effective Usage of Organic Indexes in Water Environments -Lakes in Nakdong River Basin- (물환경에서의 유기물질 지표 특성 및 효율적 이용방안 -낙동강수계 호소수를 대상으로-)

  • Kang, Meea
    • Journal of Wetlands Research
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    • v.16 no.1
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    • pp.153-160
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    • 2014
  • TOC environmental standard was established to understand the pollution level accurately and to improve the water quality. It was found that the relationship between COD and TOC showed a significant coefficient($R^2$=0.639) in four lakes for drinking water located in Nakdong River basin. The relationship between COD and TOC($R^2$=0.774) was higher with respect to the elevated concentration level when the data was added. Resulting in the oxidation(C) was $62{\pm}8%$ regardless of COD concentrations. It was difficult to find a significant difference by lakes. The result showed the similar organic property in study lakes. It was necessary to evaluate the level of organic matters in consideration of characteristics and utilization of lakes to use COD data wisely until TOC data be accumulated sufficiently.