• Title/Summary/Keyword: 화학연대

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Zircon chemical age of the Precambrian gneisses from Gimcheon area in the central Yeongnam massif, Korea (중부 영남육괴 김천일대 선캠브리아기 편마암의 저어콘 화학연대)

  • 이호선;송용선;박계헌
    • The Journal of the Petrological Society of Korea
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    • v.11 no.3_4
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    • pp.157-168
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    • 2002
  • In Gimcheon area of the central Yeongnam massif granite gneiss occurrs with intercalated biotite gneiss at xenolith or restite. In order to understand the evolution of the central Yeongnam massif, it is essential to have absolute age information, but not many age data are available yet. Furthermore the previous age determinations from the study area are not compatible with the outcrop relationship. In this study we determined chemical ages from the zircon grains. We obtained ages of $1970\pm$ 78(l$\sigma$)Ma from the granite gneiss, $1814\pm$77(l$\sigma$)Ma from the outer rim of a rounded zircon and 1973$\pm$97(l$\sigma$)Ma from a longish zircon, both from the biotite gneiss. These ages seem to indicate the timing of granitic magma intrusion and subsequent metamorphism. Ages of $2954\pm$ 158($l\sigma$)Ma, 2440$\pm$58(l$\sigma$)Ma, and 2219$\pm$36($l\sigma$)Ma obtained from zoned core of the rounded zircon grain from the biotite gneiss suggest various geological events before such metamorphism of the biotite gneiss. Ages in the range of 1450~1670 Ma observed in zircons of both gniesses suggest later metamorphism that the granite gneiss and the biotite gneiss experienced together. The chemical age determination by electron probe micro-analyzer of this study utilized 1$\mu\textrm{m}$ beam diameter and it seems to be a very useful age determination from the zircons with complex growth history because of superior spatial resolution.

Geochemical Implication of Rare Earth Element pattern and Rb-Sr mineral isochron from consituent minerals in the Naedeokri-Nonggeori granite, Yeongnam Massif, Korea (영남육괴 북동부 내덕리-농거리 화강암내 구성광물의 희토류원소 분포도 및 Rb-Sr 광물연대의 지구화학적 의의)

  • Seung-Gu Lee;SeungRyeol Lee
    • Korean Journal of Mineralogy and Petrology
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    • v.36 no.2
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    • pp.125-134
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    • 2023
  • The Naedeokri and Nonggeori granites are early Proterozoic granites of the Taebaek-Sangdong area in the northeastern part of the Yeongnam Massif. In this paper, rare earth elements (REEs) concentrations of the minerals in Naedeokri and Nonggeori granites and Rb-Sr mineral isochron age are reported. Except zircon, the constituent minerals such as mica, feldspar, quartz, and tourmaline show LREE-enriched and HREE-depleted REE patterns with relatively large Eu negative anomaly. However, zircon has geochemical characteristic of LREE- and HREE-enriched REE pattern with large Eu positive anomaly. This pattern suggests that zircon should be hydrothermal zircon due to deuteric hydrothermal alteration. In addition, the Rb-Sr mineral age of Naedeokri granite indicates an age value of 1.814±142(2σ) Ma. The Rb-Sr whole rock age including pervious data of Naedeokri and Nogggeori granite indicates an age value of 1,707±74(2σ) Ma. This value is younger than the Sm-Nd isochron of 1.87 Ga, indicating that the Rb-Sr isotope system may be re-homogenized by hydrothermal alteration during the transition from a magmatic to a hydrothermal system.

스피츠버겐 페리도타이트에 대한 Lu-Hf 및 Re-Os 동위원소 시스템의 활용: 맨틀-지각간의 성인적 연계성에 대한 고찰

  • Choe, Seong-Hui;Shzuki, K.;Mukas, S.B.;Lee, Jong-Ik
    • 한국지구과학회:학술대회논문집
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    • 2010.04a
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    • pp.23-23
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    • 2010
  • 스발바드 서측에 위치하는 스피츠버겐 하부의 암석권맨틀의 분화시기를 규명하기 위하여, 두 개의 독립적인 방사성동위원소 시스템인 Lu-Hf과 Re-Os 시스템을 스피넬 페리도타이트(spinel peridotite)에 활용하였다. 전암에 대한 Re-Os 계통(Re-Os 에러크론, 알루미노크론, Re-결핍연대 등)은 연구지역의 페리도타이트가 대류하는 맨틀로부터 고기원생대/후기시생대에 분리되었음을 지시한다. 흥미롭게도 이런 연대는 페리도타이트내 단사휘석 결정들에 대하여 얻어진 Lu-Hf 에러크론 연대와 일치한다. 또한 시료 내에 지구화학적으로 기록된 현무암질 액의 결핍정도 역시 계통적으로 위의 연대를 지지한다. 위 연대는 스피츠버겐 서측부에 보고된 가장 오래된 지각의 연대와 일치한다. 따라서 연구지역의 암석권맨틀이 연약권으로부터 분리된 것은 접촉하고 있는 지각과 동시기적으로 이루어진 사건임을 알 수 있다. 연구지역은 팔레오세 이래로 복잡한 지구조적 응력장 변화(압축에서 신장환경으로의 변화)를 겪었다. 그럼에도 불구하고 지각과 커플링된 암석권맨틀이 현존한다는 것은 연구지역내 응력장변화가 대규모의 암석권 디라미네이션(delamination)을 유발하지는 않았다는 것을 의미한다. 그러므로 북극권의 화산활동을 설명하기 위하여 북극권 상부맨틀에 존재한다고 알려진 듀팔(DUPAL) 같은 부화된 물질의 성인으로 일부의 연구자들이 주장하여 온 디라미네이션된 암석권맨틀의 존재는 설득력이 없다고 판단된다.

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SHRIMP Zircon U-Pb Geochronology, Geochemistry and Sr-Nd Isotopic Study of the Cheongju granitoid rocks (청주 화강암의 SHRIMP 저어콘 U-Pb 연대, 지구화학 및 Sr-Nd 동위원소 연구)

  • Cheong, Won-Seok;Kim, Yoon-Sup;Na, Ki-Chang
    • The Journal of the Petrological Society of Korea
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    • v.20 no.4
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    • pp.191-206
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    • 2011
  • The emplacement ages, whole-rock geochemistry and Sr-Nd isotopic compositions of granitoid rocks from Cheongju area, South Korea, were investigated for delineating their petrogenetic link to the Jurassic Daebo granitoid rocks. Zircon crystals were collected from the diorite, biotite granite and acidic dyke samples in a single outcrop. Cross-cutting relationships show that the emplacement of diorite was postdated by the intrusion of biotite granite. Both rocks have been subsequently intruded by acidic dyke. The U-Pb isotopic compositions of zircon from the diorite, biotite granite, and acidic dyke were measured using a SHRIMP-II ion microprobe, yielding the crystallization ages of $174{\pm}2Ma$, $170{\pm}2Ma$, and $170{\pm}5Ma$, respectively, with 95% confidence limits ($t{\sigma}$). The emplacement ages are consistent with those determined from the above relative ages. The major and trace element patterns of the rocks are consistent with those of the Jurassic Daebo granitoid rocks, possibly suggesting a subduction-related I-type granite. The geochemical signature is, however, betrayed by the Sr and Nd isotopic compositions of these rocks. The isotopic signatures suggest that the rocks were produced either by the partial melting of lower-crust or by the mantle-derived magma contaminated by the basement rocks during its ascent and/or emplacement. In addition, the inherited ages of zircons of the rocks (ca. 2.1, 1.8, 0.8 and 0.4 Ga) suggest a possible assimilation with crustal rocks from the Gyeonggi massif and Ogcheon metamorphic belt.

Water Chemistry and Age Dating of Springwater in Cheju Island (제주도 용천수의 수질 화학적 특성과 연대 측정에 관한 연구)

  • Kim Jong-Hun;Ahn Jong-Sung
    • Journal of the Korean Chemical Society
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    • v.36 no.5
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    • pp.727-737
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    • 1992
  • The water chemical characteristics and age dating of springwater in Cheju island had been investigated. C_1, C_4, C_7, C_9 springwaters were not affected by seawater intrusion by TDS and electrical conductivity, relationship of Cl and tritium, Cl and HCO_3 ratio, and total hardness and pseudo hardness. In this case only C_7 springwater was evaluated tasty and healthy mineral springwater by Hahimoto's Mineral Balance Index. On the basis of the mean tritium content of rainfalls and springwater, the average residence time of it, were calculated. Considering the hydrogeologic and hydrochemical condition, completely mixed model seems to be very fit. It was obtained the result that C_9 group springwater (C_{10}, C_{12}, C_{14}) was 1.2 months, C_7 springwater was 5.6 months, and deep groundwater C_{17} was 4 years.

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The age dating for an archaeological sample using pre-dose effect (Pre-dose effect를 이용한 고고학 시료의 연대측정)

  • Kim, Myung-Jin;Hong, Duk-Geun
    • Analytical Science and Technology
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    • v.18 no.4
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    • pp.329-337
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    • 2005
  • TL dating using pre-dose effect is concerned with the sensitivity increase of $110^{\circ}C$ TL peak in quartz following the pre-exposure of irradiation (pre-dose) in antiquity and heating to thermal activation temperature. Using the multiple activation (MA) method for determining an equivalent dose, the activation temperature was selected to $500^{\circ}C$ and the region of interest was selected from $85^{\circ}C$ to $105^{\circ}C$ on quartz sample from archaeological remains, roof-tile kiln. which was excavated at Chudong-Ri cultural site. It was concluded that the resultant date was determined to the age of $1725{\pm}25years$ AD (l ${\sigma}$ SD), which had more improved precision considering with e radiocarbon dates and was in good agreement with the age derived by archaeological assessment. Also it was concluded that the pre-dose dating should contribute significantly to future archaeological dating work in the range of the last 2000 years.

Geochemistry, Isotope Properties and U-Pb Sphene Age of the Jeongeup Foliated Granite, Korea (정읍엽리상화강암의 지구화학 및 동위원소 특성과 U-Pb 스핀 연대)

  • Jeong, Youn-Joong;Cheong, Chang-Sik;Park, Cheon-Young;Shin, In-Hyun
    • Journal of the Korean earth science society
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    • v.29 no.7
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    • pp.539-550
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    • 2008
  • In this paper, we investigate the geochemical and isotope properties of the Jeongeup foliated granite (hereafter, the JFG) in the Jeongeup area, aiming at establishing the movement age of the Honam shear zone by U-Pb sphene geochronology. In the AMF diagram, the JFG corresponds to the calc alkalic rock series, and belongs to the magnesia region in the diagram of silica versus $FeO^{total}/(FeO^{total}+MgO)$. Additionally, in the Rb-Ba-Sr diagram, it is classified as granodiorite and anomalous granite with distinctive negative Eu-anomaly in the REE patterns. According to the silica and trace element contents, the JFG falls on the type VAG+syn-COLG, which implies that this was formed under the circumstance of compressional continental margin or volcanic arc. $^{143}Nd/^{144}Nd$ isotope ratios range from 0.511495 to 0.511783 and $T_{DM}$ are calculated to be about $1.68{\sim}2.36Ga$. U-Pb sphene ages of the JFG are $172.9{\pm}1.7Ma$ and $170.7{\pm}2.8Ma$, based on $^{238}U-^{206}Pb$ and $^{235}U-^{207}Pb$ ages, respectively. Presumably, the dextral ductile shearing in the Jeongeup area has occurred after 173 Ma.

Petrological, Geochemical and Geochronological Studies of Precambrian Basement in Notheast Asia Region: 1. Age of the Metamorphism of Jirisan Area (동북아시아지역 선캠브리아 지괴에 대한 암석학, 지구화학 및 지구연대학적 연구 : 1. 지리산 지역 변성암의 변성연대)

  • 박계현;송용선;박맹언;이승구;류호정
    • The Journal of the Petrological Society of Korea
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    • v.9 no.1
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    • pp.29-39
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    • 2000
  • For the determination of metamorphic age of the metamorphic rocks distributed in the Ji-san area of Youngnam massif, Sm and Nd isotopic compositions were analyzed for the whole rock and garnet separates. As the result, we obtained 1799 + 11 Ma from the porphyroblastic gneiss, 1776 +30 Ma from the metapelite, 1714+35 Ma from the mafic granulite xenolith within the porphyroblastic gneiss, and 1776+30 Ma from the metapelite occurred as a xenolith within the quartzofeldspathic gneiss. There have been reports of geologic ages similar to such metamorphic ages of Jirisan area from the other portion of the Youngnam massif, which reveals that very intense metamorphism took place over the vast area of Youngnam massif during the period of 1.7-1.8 Ga ago. The granulite facies metomorphism of the Gyeonggi massif also shows the age similar to this period. Such resemblance in their metamorphic ages suggests that these massifs experienced similar tectonothermal events occurred at about the same Precambrian periods, which implies the possibility that the extension of the collision belt between the north and south China blocks does not extend through some places between the Youngnam and Gyeonggi massifs. On the other hand a quarzofeldspathic xenolith of porphyroblastic gneiss show 1928 +42 Ma which is older than above age of the metamorphism and is identical with the zircon U-Pb age of porphyroblastic gneiss indicating the formation age of the protolith of the porphyroblastic gneiss.

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Petrological, Geochemical and Geochronological Studies of Precambrian Basement in Northeast Asia Region: 2. Zircon Ages of Some Metamorphic Rocks from Gyeonggi Massif (동북아시아지역 선캠브리아 지괴에 대한 암석학, 지구화학 및 지구연대학적 연구: 2. 경기육괴 일부 변성암의 저어콘 연대)

  • ;;Cao Lin;Jin Wei;Zhang Xingzhou
    • The Journal of the Petrological Society of Korea
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    • v.10 no.2
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    • pp.95-105
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    • 2001
  • U-Pb age determination was performed on the zircon fractions separated from the metamorphic rocks of three locations of the Gyeonggi Massif. The ages obtained from the upper and lower intersections between concordia curve and discordia lines made of the zircon fractions separated from the rocks of each locality we: $2168\pm$24 Ma and $1227\pm$40 Ma for the Yongduri Gneiss Complex, $1955\pm$22 Ma and $493\pm$32 Ma for the Euiam Group, and $3712\pm$244 Ma and $1613\pm$51 Ma for the Yongmunsan Group (2$\sigma$ errors). The upper intercept ages from the Yongduri Gneiss Complex and the Euiam Group of Gyeonggi massif are very similar to those obtained from the granitic gneisses and the porphyroblastic gneisses of Yeongnam massif respectively. Such similarities suggest that Gyeonggi and Yeongnam massifs might situate under the similar tectonic and geographic environment during ca. 2.2-1.9 Ga. The upper intercept age of Youngmunsan Formation (3.7 Ga) shows large error, because most of the zircon fractions are plotted very close to the lower intersection. It is necessary to investigate further to confirm this age. However, It may suggest the possibility of occurrence of the oldest crust of the northeast Asia similar to the one reported recently from the northeast China. The lower intercept age of the Yongmunsan Group is interpreted to indicate strong metamorphism. Such age postdates the 1.85-1.7 Ga metamorphism and igneous activities occurred in the Yeongnam massif, which might record the late Paleoproterozoic tectonic activities simultaneously occurred in both massifs.

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