• Title/Summary/Keyword: 화학설

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An Experimental Study on the Evaluation of Residual Tensile Load-carrying Capacity of Corroded Steel Plates of Temporary Structure (가시설 부식 강재의 잔존 인장 내하성능 평가에 관한 실험적 연구)

  • Kim, In-Tae;Chang, Hong-Ju;Cheung, Ji-Young
    • Journal of Korean Society of Steel Construction
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    • v.22 no.5
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    • pp.399-409
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    • 2010
  • Steel structures are threatened to reduce load-carrying capacity as the cross section is decreased by corrosion. However, there has been no method in definitely evaluating residual load-carrying capacity and the effect of corrosion to the load-carrying capacity of steel. This study evaluated tensile residual load-carrying capacity of corroded steel plates by using tensile tests of specimens, which were selected from the web of temporary structure's main beam. After the surface shapes were measured and tensile tests were examined, the rust of 21 corroded specimens was, first of all, removed using a chemical method. From the tensile test result, which of reference specimens that was picked off at the flange of the same main 13-mm-thick beam and corroded specimens were based, surface geometry and correlation with the reduction of corroded thickness and strain, yield strength or tensile strength was established as constant numbers. Effective thickness of corroded steel with irregular cross sections could be calculated using average residual thickness and standard deviation. The irregular cross sections could be the evaluated tensile strength that is equalized to non-corroded uniform steel's regardless of corrosion. Also, reasonable measuring intervals of residual thickness could be proposed by using this result to apply for executive work.

A Method to Develop for Emergency Response Guidelines using Business Continuity Plan in Chemical Plant (BCP 기법을 활용한 화학공장에서의 사고대응 가이드라인 개발 방법에 관한 연구)

  • Yang, Jae-Mo;Seol, Ji Woo;Yong, Jong-Won;Ko, Sang Wook;Park, Chulhwan;Yoo, Byungtae;Ko, Jae Wook
    • Korean Chemical Engineering Research
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    • v.52 no.6
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    • pp.743-749
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    • 2014
  • Even if many studies for the prevention of accidents in chemical plant have been carried out, recently more severe accidents in chemical plants have occurred continuously. These have a large potential impact and the loss of casualties and economic can vary according to the activities of early emergency responses. Thus, in order to mitigate the impact of accidents, the studies preparing the guidelines for emergency response have to be urgently needed. In this study, the current emergency responses guidelines and regulations in Korea were investigated to find out the drawbacks. And, to tackle these, BCP(Business continuity plan) method was used to improve the activities of early emergency responses as suggesting the basic components, response steps, feedback and procedures of the emergency responses.

Development of Intermediate Temperature Fuel Cell Using a Solid Proton Conductor (고체 수소이온 전도체를 이용한 중온형 연료전지 개발)

  • Seo, Dong-Ho;Kim, Hong-Rok;Shakkthivel, P.;Shul, Yong-Gun
    • Journal of the Korean Electrochemical Society
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    • v.11 no.1
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    • pp.22-32
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    • 2008
  • Because of an emerging importance of clean energy, fuel cells are attract more attention due to their ability to produce high efficient power without any harmful emission. Fuel cells are energy conversion device with directly convert chemical energy into electrical energy by the chemical reactions, which have potential applications in automobile, spacecraft, stationary, industrial and home appliances. Recently there are gaining demand to develop an intermediate temperature fuel cell and available proton conductors at $200{\sim}500^{\circ}C$, which promising operating temperatures range for both material science and energy conversion processes. In this paper, we have reviewed electrochemical properties and current technology of solid state proton conductors. In addition, development of intermediate temperature fuel cell using the perovskite-type solid protonic conductor is also discussed.

Surface Modification of Synthetic Graphite as an Electrode by Fluidized-bed Chemical Vapor Deposition for Lithium Secondary Batteries (유동상 화힉증착에 의한 리튬이차전지 전극용 탄소재료의 표면개질)

  • Ryu D. H.;Lee Joong Kee;Park D. G.;Yun K. S.;Cho B. W.;Shul Y. G.
    • Journal of the Korean Electrochemical Society
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    • v.3 no.3
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    • pp.173-177
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    • 2000
  • The synthetic carbon was coated with tin oxide and copper by fluidized-bed chemical vapor deposition method. $(CH_3)_4Sn\;and\;Cu(hfac)_{2s}$ were employed as the metallic organic precursor, respectively. The modified synthetic carbons were used for lithium secondary battery anode to investigate their coating effects on electrochemical characteristics as alternative anode materials for lithium secondary batteries. The electrode which prepared by the synthetic carbons(MCMB) coated with tin oxide gave the higher capacity than that of raw material. Their capacity decreased with the progress of cycling possibly due to severe volume changes. But the cyclability was improved by coating with copper on the surface of the tin oxide coated carbon, which plays an important role as an inactive matrix buffering volume changes.

Localization of Dendroaspis natriuretic peptide (DNP) in the rat salivary glands (흰쥐 타액선내에서의 DENDROASPIS NATRIURETIC PEPTIDE(DNP)의 분포)

  • Kim, Jae-Gon;Lee, Young-Soo;Baik, Byeong-Ju;Park, Byung-Keon
    • Journal of the korean academy of Pediatric Dentistry
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    • v.28 no.3
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    • pp.447-463
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    • 2001
  • Dendroaspis natriuretic peptide (DNP), a fourth member of the natriuretic peptide isolated from the venom of the Dendroaspis angusticeps snake, has been reported to be present in human plasma and atrial myocardium and caused vasorelaxation and diuresis in experimental animals. However, it is uncertain whether they are present in peripheral organs other than the heart and its further physiological roles also remains to be clarified. To assess the possible physiological role of DNP in the salivary glands, I investigated the localization of DNP peptide in the rat salivary glands by immunohistochemistry and the binding sites for radiolabelled DNP in the rat salivary glands and oral mucosa using in vitro autoradiography. DNP immunoreactivity was widely distributed in the submandibular, sublingual and parotid glands, particularly in the ducts such as the intercalated and striated ducts, where atrial natriuretic peptide (ANP) was colocalized in consecutive sections, but not in acini. High density $^{125}I-DNP$ binding sites were localized in the epithelia of the tongue and hard palate, while low density binding sites for $^{125}I-DNP$ were also distributed in the submandibular, sublingual, and parotid glands. In the hard palate and tongue, the precise location of this binding was revealed on the basal and parabasal cells of the epithelia by emulsion microautoradiography. These results suggest that DNP may not only have a role in the salivary glands but also play a role in the regulation of growth in the oral epithelium, particularly in the hard palate and tongue.

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A Study on Process Safety System Analysis for Application Process Safety Performance Indicators (공정안전성과지표 적용을 위한 공정안전시스템 분석방안 연구)

  • Ko, Byung Seok;Lim, Dong-Hui;Kim, Min-Seop;Seol, Ji Woo;Yoo, Byung Tae;Ko, Jae-Wook
    • Journal of the Korean Institute of Gas
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    • v.26 no.2
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    • pp.27-38
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    • 2022
  • In developed countries, the number of accidents has significantly decreased with the introduction of the process safety management system, but it has a regulatory nature and it is difficult to show the actual situation of workplace safety management. Many organizations recommend the use of process safety performance indicators to comprehensively monitor process safety status. In this study, for the application of process safety performance indicators, the related guidelines were compared and analyzed, and the method of using the process safety system of the workplace as an indicator was reviewed. In literature indicators, compliance with procedures is mainly checked, whereas in system-based indicators, procedures or inspections for a specific purpose of the safety system can be clearly identified, and the operation status can be measured and monitored. It can be seen that this characteristic is more advantageous in terms of the clarity of the supplements derived in operating safety management activities. Using this, it is possible to effectively show the level of safety management in the workplace.

Growth and characterizations of INAlAs epilayers and InGaAs/INAlAs quantum well structures by low pressure metalorganic chemical vapor deposition (저압 유기금속 화학증착법을 이용한 InAIAs 에피층과 InGaAs/InAIAs 양자 우물 구조의 성장과 분석)

  • 유경란;문영부;이태완;윤의준
    • Journal of the Korean Vacuum Society
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    • v.7 no.4
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    • pp.328-333
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    • 1998
  • Lattice-matched InAIAs epilayers were grown on (001) InP substrate by low pressure metalorganic chemical vapor deposition. The effects of growth conditions on the properties of InAIAs were analyzed, and InGaAs/InAIAs single and multiple quantum wells were successfully grown. It was observed that the optical property of InAIAs epilayers was improved in the temperature range of 620~$700^{\circ}C$ as the growth temperature increased due to the reduction of oxygen incorporation, however, the crystallinity decreased at temperatures higher than $750^{\circ}C$ due to the degraded crystallinity of the bufter layers. The enhanced incorporation of AI into epilayer was observed at high $AsH_3$flow rates and it was explained in terms of the differences in bond strengths of AI-As and In-As. The measured photoluminescence peak energies from InGaAs/InAIAs single quantum wells were consistent with the calculated ones based on transfer matrix method. High-order satellite peaks and fine thickness fringes were observed by high-resolution x-ray diffraction, implying that the high-quality multiple quantum wells with abrupt heterointerfaces were grown.

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The study of bloody fingerprint enhancement on paper with chemical reagents (화학시약들을 이용한 지류에서 혈흔지문 증강에 관한 연구)

  • Lim, Seung;Kim, Im-Soon;Noh, Jong-Yun;Kim, Sang-Il;Yu, Je-Sul
    • Analytical Science and Technology
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    • v.25 no.5
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    • pp.284-291
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    • 2012
  • Bloody fingerprint is a very important evidence. In this study, we confirmed the enhancement effects of ninhydrin, leucocrystal violet (LCV), fuchsin acid, iodine and dimethylaminocinnamaldehyde (DMAC) on bloody fingerprints which were deposited on paper. Bloody fingerprint were deposited on paper sequentially and used after drying at room temperature. If a ridge of bloody fingerprint was clear, ninhydrin and LCV was the most effective but was not good for invisible ridge. Fuchsin acid reagent dyed paper surface so that the contrast of enhanced bloody fingerprint was decreased. Although bloody fingerprint was enhanced with iodine reagent, but the developed color was very weak after reaction. We thought that the enhancement effect of iodine to bloody fingerprint was negligible. Also, the enhancement effect of DMAC reagent to relatively clear bloody fingerprint was not good. However, it was very effective to faint or invisible ridge. By washing with methanol, contrast of enhanced bloody fingerprint was increased.

Assessment of Relapsing Urolithiasis from K43 with Erosive Gastritis (미란성 위염 환자 K43에서 재발성 요로 결석에 관한 연구)

  • 김재웅
    • The Korean Journal of Food And Nutrition
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    • v.10 no.1
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    • pp.44-52
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    • 1997
  • Nephrolithiasis is the most common disorder of the urinary tract in hospitalized patients, more frequently increased in 30~50 years of age, more common in males than in females, prior right stone to left side, and than upper ureteral stone is found in cultural country, while lower ureteral stone is increased in uncultural country. Stone components are classified as calcium oxalate, calcium phosphate, magnesium ammonium phosphate, uric acid, cystine, and their mixed stone, respectively. According to the pathophysiology of urinary stones, supersaturation/crystalization of inorganic salt concentration in urine, organic matrix, inhibitor deficiency, and epitaxy theory could be based on the stone formation. Not only hypercalciuria, hyperparathyroidism, hyperoxaluria, hyperuricosuria, and cystinuria, but also renal tubular acidosis, hypervitaminosis D, and peptic ulcer, are significantly associated with nephrolithiasis. In this study upper ureteral stone component were analyzed with chemical analysis, infrared spectrum, and image analyzer from K43 patient wit erosive gastritis. As the results, mixed stone of calcium oxalate dihydrate and calcium phosphate apatite was identified, the values of clinical test in blood and urine maintained normal revels. The relapsing urinary stone from K43 have no correlation between factors for stone formation reported early, also have no evidence for risk from erosive gastritis.

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Metachromasy of Methylene Blue on the Bacteriorhodopsin Incorporated into L-${\alpha}$-lecithin Vesicle (L-${\alpha}$-lecithin으로 재구성된 Bacteriorhodopsin Vesicle에서 Methylene Blue의 Metachromasy)

  • Hong Lee;Huyn-Ock Pae;Chun-Ock Lim;Hoo-Seol Lee
    • Journal of the Korean Chemical Society
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    • v.36 no.4
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    • pp.504-510
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    • 1992
  • Absorption properties of methylene blue (MB) in L-${\alpha}$-lecithin vesicle, bacteriorhodopsin and incorporated bacteriorhodopsin (InBR) vesicle systems at 20∼$60^{\circ}C$ has been studied by adsorption spectroscopy. The equilibrium of MB between monomer and dimer in lecithin vesicles has been existed at low concentration of MB, but oligomer has been formed in vesicle at higher concentration of MB. In most cases, the MB cluster was redistributed to monomer at the concentration of lecithin vesicles. Adding BR to constanr concentration of MB deceased the adsorption ratio (${\alpha}/{\beta}$) of MB, and MB was formed oligomeric aggregate. Absorption ratio (${\alpha}/{\beta}$) of MB was increased during phase transition of InBR vesicles, but independent of phase transition of lecithin vesicles. It suggested that aggregate of MB on the surfaces of InBR vesicles were redistributed to monomer under the influence of lipid phase transition.

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