• Journal of the Korean Chemical Society
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• v.47 no.2
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• pp.155-164
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• 2003

This study examined the types of explanations related to physical change and chemical change in the science textbooks of middle and high school based on the prior study of science teachers' understanding. For this research, the researchers analyzed 44 textbooks of middle school science and high school chemistry. As a result, there were no explanation or property type explanation represented in most of the textbooks related to physical and chemical change concepts. Also, there are few relationship represented between physical change and chemical change, and the examples related to physical change and chemical change were confused. These representations of textbooks can give rise to confusion of understanding of teachers and learners. So, it needs to re-design the explanation types correctly and constantly in science textbooks related to physical change and chemical change.

• Journal of the Korean Chemical Society
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• v.46 no.6
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• pp.561-568
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• 2002

This study examined secondary school science teachers' thinking on physical and chemical change. For this research, we analysed the answers of 80 secondary school science teachers. According to the result of the analysis,teachers had various opinions when they classified phenomena of dissolving ionic compound or diluting acid into phys-ical change and chemical change. Many teachers tended to classify similar phenomena into different change when those were represented with different focus. It means that teachers' opinions were not consistent.

• Journal of the Korean Chemical Society
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• v.48 no.1
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• pp.53-65
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• 2004

This study aimed to analyze the historical evolution of general ideas concerning the particles that represent matter properties and matter changes divided into physical change and chemical change. In the science historical viewpoint, the general ideas of the base that represent matter properties has been variously revised the 5types. The definition of the matter change have also changed the 3 types. From the analysis of the definitions in secondary school science textbooks and general chemistry textbooks, we found that a lot of confusion of eras in the contents that define the concepts. Sometimes, the definition presented in one textbook was contradictory to the definitions in other textbooks. This tendency has been sustained in the textbooks from the 4th to 7th science curriculum.

• Proceedings of the Korea Water Resources Association Conference
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• 2021.06a
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• pp.163-163
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• 2021

하천에서의 화학사고는 자연적 및 인위적인 원인으로 인해 발생할 수 있으며, 이러한 화학사고가 발생하게 되면 수환경 변화를 야기해 생태계나 인간에게 악영향을 발생시킬 수 있어 신속한 초기대응이 필요하다. 하천으로 유입된 화학물질의 평가에 대한 연구는 활발하게 진행되고 있지만, 화학사고 초기대응을 위한 연구는 미비한 실정이다. 초기대응을 위해서는 현장에서 측정이 용이한 지표를 활용해야하며, 이 지표를 이용해 유출된 화학물질에 대한 정보를 취득 할 수 있어야 한다. 하천의 주요 지점에는 pH 및 EC 등을 실시간으로 측정하는 자동측정망을 운영하고 있는데, 이러한 측정항목들을 지표로 활용한다면 하천 화학사고 대응을 위한 중요한 기초자료로 활용될 수 있을 것이다. 또한 측정된 데이터를 머신러닝 기법을 적용한다면 화학사고 발생 시 초기대응을 위한 기초자료로 활용될 수 있을 것이다. 본 연구에서는 분석한 유해화학물질은 총 26종이며, pH 및 EC를 화학물질들의 특성을 파악하기 위한 대체지표로 선정하였다. 화학물질의 농도변화에 따른 대체지표 변화를 측정하였으며, 실험결과를 바탕으로 성질이 유사한 화학물질들을 Group별로 분류하여 데이터베이스를 구축하였다. 구축된 데이터베이스를 바탕으로 머신러닝 기법인 Decision Tree, Random Forest, Gradient Boosting, XG Boosting에 적용해 각 알고리즘에 대한 성능 평가를 진행하여 가장 우수한 성능의 머신러닝 기법을 선정한다. 본 연구 결과를 바탕으로 선정된 머신러닝 기법을 활용한다면 향수 수환경 화학사고 발생 시 유출된 유해화학물질에 대한 정보를 제공할 수 있으며 그에 따른 신속한 대응의 기초자료로 활용될 수 있을 것으로 판단된다.

• Journal of Welding and Joining
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• v.2 no.2
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• pp.1-6
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• 1984

피복아아크 용접봉(이하 용접봉이라 함)의 피복제는 염기도에 따라 산성, 중성, 염기성으로 대별할 수 있다. 용접에서의 화학야금반응은 제강의 화학야금반응과 원리는 비슷하나 양자간 크게 다른 점은 용접시의 반응시간이 극히 짧다는 점이다. 이와같이 반응시간이 짧다는 점 이외에도 작업자가 직접 용융반응을 지켜 보면서 반응후에 나타나는 제반 문제점에 대비하여야 하는 어려운 점이 있다. 제강반응은 전문가만의 독특한 기술인 반면 용접은 용접봉 제조자 뿐만 아니라, 용접작업자 고유의 기술이므로 용접야금반응을 상식화 하고자 하는데 본 고는 의의를 두고 있다. 피복제 중에서의 염기도의 변화, 즉 염기도에 영향을 크게 미치는 탄산칼슘의 양을 임의로 변화시키므로서 다음과 같은 현상을 기대할 수 있다. (1)용접 작업성의 변화 (2)용착 금속의 화학성분 변화 (3)용착금속의 조직 변화 (4) 용착금속내의 수소 함유량 변화 (5)용착금속의 기계적 성질변화 등이다.

• Journal of the Korean Chemical Society
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• v.51 no.4
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• pp.365-374
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• 2007

The purpose of this study is to investigate the students' conceptions about the reaction rate changes during the chemical equilibrium shifts and also whether the questions about basic concepts of the reaction rate are helpful for the students' understanding of reaction rate changes during the chemical equilibrium shifts. The subjects were 100 students in the 12th grade. The questionnaires were composed of A, B, and A' set, which had to be answered sequentially. The A set consisted of questions asking the change of reaction rate when chemical equilibrium was shifted, the B set was to testify the basic concepts of the reaction rate, and the A' set was the same as the A set. The results showed that the students' understanding of the reverse reaction rate change was lower than that of the forward reaction rate change during the equilibrium shift. Also it was found that students' understanding of the reaction rate change caused by adding the reactant was fairly good while their understanding of the reaction rate change caused by temperature increment was very poor. Since the students marked very high scores in the B set questions, their poor understanding for the reaction rate changes during the equilibrium shifts was not seemed to be due to the lacks of the basic knowledge of reaction rate. Instead, it was due to the failure of applying the basic knowledge of reaction rate to the changes of reaction conditions. It was also found that the average scores of A' set were statistically higher than those of A set. It means the B set items were helpful for the students to solve the A' set items. These results evidenced the possibility of set questionnaires could help the students to connect the related concepts in solving the problems.

• Journal of the Korean Vacuum Society
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• v.18 no.1
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• pp.49-53
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• 2009

The chemical properties of SiOC film was studied for inter-layer insulator. SiOC film was formed with non polarity due to the appropriate union by the alkyl and hydroxyl group. An amorphous structure of non polarity can induce the low dielectric constant materials. The chemical properties of thin film can define the bonding structure owing to the ionic variation, and the analysis of chemical properties was researched by the carbon content using the FTIR spectra, and induced the film with non polarity. The electrical properties is the electron flow, and is always not the same as the chemical properties. The electrical properties of SiOC film with various flow rate ratios was analyzed and researched the correlation between the chemical properties. SiOC film showed the increasing of the leakage current after annealing process, and abruptly increased the carbon content at some samples. But the sample with increasing the carbon content decreased the leakage current. It means that the chemical properties is not the same as the electrical properties, and the carbon is related with the variation of the bonding structure, and does not contribute the current flow.

• Journal of the Korean Electrochemical Society
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• v.17 no.4
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• pp.209-215
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• 2014

We report on the electrocatalytic activities at Pt nanostructure surfaces electrodeposited with different deposition charges on indium tin oxide electrodes for oxygen reduction and methanol oxidation reactions. The surface properties of Pt nanostructures depending on deposition charges were characterized by scanning electron microscopy, electrochemical surface area measurement, X-ray diffraction, and CO stripping analysis, which were correlated to the electrocatalytic activities. Pt nanostructures with deposition charge of 0.03 C exhibited the highest electrocatalytic activity for oxygen reduction and methanol oxidation. The sharp sites of Pt nanostructure and the presence of highly active facet play a key role, whereas the electrochemical surface area does not significantly affect the electrocatalytic activity. The results obtained in this work with regard to the dependence of electrocatalytic activity on the variation of the Pt nanostructures will give insights into the development of advanced electrocatalytic systems.

• The Korean Journal of Quaternary Research
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• v.23 no.1
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• pp.42-53
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• 2009

In response to the abrupt climate change in recent years, atmosphere, ocean and cryosphere are reported to be altered. In addition to these changes, the land surface is also gradually changing and its impact on the global climate may not be negligible. The land surface change impacts the global climate via two ways, the biogeochemical and biophysical feedbacks. The biogeochemcial change in the land surface modifies the atmospheric trace-gas concentrations through a change in photo synthesis, while biophycal changes of the land surface alters the surface albedo, which influences the amount of the short wave radiative heat fluxes. There are many examples in the past that the change in land surface greatly influences the global climate change. The recent IPCC report has suggested that the climate change will occur rather abrubtly in the near future. In order to predict the future climate accurately, the impact of the land surface change is fully considered.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.02a
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• pp.329-329
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• 2013

본 연구에서는 PEDOT:PSS와 crystalline-ITO (c-ITO) 박막 계면에서의 화학적 반응을(박리 및 용해 특성)을 관찰하기위해 spin-coating 및 droplet dropping을 통하여 PEDOT:PSS 용액을 코팅하고 이후 화학적 거동에 따른 전기적, 광학적 및 구조적 특성 변화를 관찰하였다. 강산성을 띄는 PEDOT:PSS (Al 4083) 박막의 코팅 전, 0.4T sodalime glass 위에 열처리를 통하여 성막된 c-ITO 투명전극을 15분 동안 상압 오존 공정을 통하여 계면처리함으로써 다른 변수의 영향을 배제하였으며, 표면 처리 후 spin-coating 및 droplet dropping method를 통하여 PEDOT:PSS를 코팅하여 c-ITO와 PEDOT:PSS 계면사이의 화학적 반응의 영향을 시간 경과에 따라 분석하였다. PEDOT:PSS 코팅 후 솔밴트 제거를 위해 hot plate를 이용하여 $110^{\circ}C$로 열처리되었다. Spin-coating 방법과는 달리 droplet dropping 방법을 통해 형성된 c-ITO 투명전극/PEDOT:PSS 계면에서는 spin coating에서 적용된 동일한 공정변수적용에도 불구하고 PEDOT:PSS의 산성으로 인한 ITO 투명전극 표면에서의 화학적 조성변화가(In, Sn, O의 조성의 변화) 발생됨을 x-ray photoelectron spectroscopy 결과를 통해 확인하였다. 뿐만 아니라 계면 조성반응 변화에 따른 전기적 특성 및 광학적 투과율의 열화가 발생됨을 Hall measurement 측정과 UV/Vis spectrometer 결과를 통하여 도출하였다. 본 결과를 통해 c-ITO/PEDOT:PSS 사이에서 발생되는 내산특성/계면 화학변화가 유기태양전지에서의 산화물 투명전극과 유기물 계면 열화현상에 영향을 받을 수 있음을 나타낸다.