• Clean Technology
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• v.29 no.1
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• pp.1-9
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• 2023

Waste explosives such as useless ammunition discharged from the military and coproduced useless explosives during the manufacturers production process have been continuously produced. These are difficult to dispose with normal waste treatment facilities due to the dangers of fire and explosion. An open burning or an open detonation at military designated disposal facilities is a classical treatment method for the dangerous explosives. The classical method raises various environmental problems by the emission of hazardous materials. An air pollution by the emission of hazardous gases such as SO_x and NO_x, soil and water contaminations by the accumulation of non-biodegradable heavy metals, are representative pollution examples. To overcome these problems, various processes for eco-friendly waste treatment methods have been developed, and some processes have already been operated in some countries. In the current report, various eco-friendly disposal processes for waste explosives or harmful materials, and their advantages and disadvantages are documented to suggest future development directions for reducing the hazardous substances by the treatment processes.

• Journal of the Korean Institute of Gas
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• v.4 no.4 s.12
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• pp.20-24
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• 2000

The electrostatic safety consciousness of safety manager were investigated through questionnaires sent to liquid petroleum gas stations in Korea. In addition, hazards of fire and explosion due to electrostatic on synthetic-polymer-wears and cotton-wears were estimated experimentally. The results of questionnaires indicate most workers wear their working clothes indiscreetly owing to lack of knowledge of preventing electrostatic hazards. The amounts of electrostatic charge generated in synthetic-polymer-wears were 1.79, 1.44 and 1.02 $\mu$C in winter, spring and autumn and summer, respectively. All these values exceed the limit of working wears of 0.60$\mu$C requested by Korea Standard(KS K-7807) for preventing electrostatic hazards, which means hazards may occur. While, the charge in cotton-wears were in the range of 0.42 to 0.52$\mu$C, which suggests that the cotton-wears investigated in this study have no problem of hazards. Therefore workers, visual and experiential education are necessary for elevating the standard of on electrostatics. It is also necessary to establish standards of wearing for preventing electrostatic hazards.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.20 no.3
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• pp.35-42
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• 2019

Risk assessment and analysis for a medium-to-small sized chemical plant that manufactures a polyester resin by the process of batch-type condensation reaction was conducted using K-PSR technique which is one of the risk assessment methods used to implement the Process Safety Management System (PSM). K-PSR is a risk assessment technique developed by KOSHA to compensate for difficulties caused by the lack of infrastructure of medium-to-small sized chemical plants in the re-evaluation. To apply the K-PSR technique, the entire process of a selected chemical palnt was classified in two review sections, i.e., the condensation reaction process and the dilution/filtration process, and the potential risks of the process about these review sections were identified and classified based on the four guide-words (release, fire.explosion, process trouble, and injury). As the results of the research, refer to recommend of risk rating has been confirmed that non-destructive testing of old facilities and the preparation of LOTO procedures for the electrical equipments are necessary as specific measures to prevent the risk of release and fire.explosion. It was also shown that pressure gauges and thermometers should be installed on the hot-oil supply piping to minimize the process trouble, and exhausting hood should be installed to prevent potential injury.

• Industry Promotion Research
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• v.8 no.4
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• pp.37-46
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• 2023

Due to the aging, advancement, and complexity of chemical facilities, non-routine work such as facility inspection, repair, or maintenance work is increasing. Of the 1,483 accidents that occurred over the past 10 years at chemical product manufacturing sites subject to PSM, accidents that occurred during non-routine work accounted for 56% (932 Cases) of the total. It can be seen that more accidents occur during non-routine work than during routine work. In particular, in order to improve the economy and efficiency of factory operation, there are cases where some facilities are stopped without stopping the entire factory and then inspection, repair, or maintenance work is performed while isolated from the operating facilities. Therefore, first, a safe isolation method must be selected by establishing an isolation standard (Baseline Isolation Standard) based on the chemicals handled, operating conditions, and risk level of the equipment in the chemical plant. Second, since current domestic laws and standards do not suggest the need for specific quarantine standards, it is necessary to institutionalize the preparation of quarantine standards. Technical and institutional improvements are needed to prevent fires, explosions, and poisoning accidents caused by leaks of chemical substances.

• Fire Science and Engineering
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• v.31 no.3
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• pp.1-10
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• 2017

This study examined the risk of accidents when handling hazardous materials in hazardous materials storage facilities without safety facilities. In the case of illegal dangerous cargo containers, the burning rate is very fast in the case of fire, which leads to explosions, that are damaging and difficult to control. In addition, accidents that occur in flammable liquid hazardous materials are caused mostly by accidents that occur in the space due to leakage. Therefore, the variables that affect these accidents were derived and the influence of these variables was investigated. Numerical and computational fluid dynamics programs were used to obtain the following final results. First, when a flammable liquid leaks into a specific space, it is influenced by temperature and relative humidity until a certain concentration (lower limit of combustion) is reached. In the case of temperature, it was found that the reaching time was shorter than the flash point In addition, the effect of variables on pool fire accidents of leakage tanks is somewhat different, but the variables that have the largest influence are the wind speed. Therefore, it is expected that the results of this study will be used as basic data for similar numerical analysis and it will provide useful numerical information about the accidental leakage of hazardous materials under various research conditions.

• Fire Science and Engineering
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• v.33 no.4
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• pp.59-69
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• 2019

The present article relates to an experimental study on fire risks due to overcharge and external heat of ESS lithium battery. According to the experimental results of overcharge, ignition occurred as combustible gas and smoke was slowly increased after occurrence of venting, and an explosive combustion form accompanied by flame eruption and sparks was displayed as charged energy is rapidly discharged in an instant. On the other hand, according to the experimental results of external heat, as a tremendous amount of combustible gas and smoke was ignited following being discharged after occurrence of vent, the charged energy itself was rapidly reduced due to the discharged energy so that a passive combustion form was observed when compared with overcharge after occurrence of flames. According the analysis results of fire damage characteristics, differences between external heat (External flame) could be found through visual and X-ray inspections. Namely, while inside electrode plate was completely destroyed and perforation of the electrode plate was observed in the case of overcharge, fire damage of the electrode plate was not severe maintaining the form in the case of external heat.

• Journal of Navigation and Port Research
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• v.36 no.10
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• pp.857-864
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• 2012

Reviewing the statistics of harbor shipment of hazardous and noxious substance and the past spill accidents of HNS enabled us to assess the potential risks of transportation of HNS through the major harbors in Korea. Ulsan, Yeosu, Daesan port are relatively evaluated high risk in fire, health and environment disaster. Through the analysis of domestic preparedness to HNS accidents, the supplement of expertise resource to respond the vulnerability of the explosion, the fire and the physiological hazard, is required. Based on this risk assessment and review of the advanced case of Japan in building up HNS response system, a resource model at a national level was proposed which differentiates the sea areas for the proper allocation of resources to respond effectively to HNS accidents in the future.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.11a
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• pp.537-540
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• 2008

Tunnel structures are constructed even longer and more extensive these days than they were in the past. Because of this reason, breaking out a large scale of fire in tunnel structures is frequently. Recently, a noticeable event is reported that the temperature of inside of tunnel rises significantly when an oil car detonated in the tunnel and it reached 1,350$^{\circ}$C. It did damage to people who used the tunnel at that time and caused many demaged parts of tunnel to recover. To improve a fire resistance of tunnel, many methods are studied focused refractory concrete and mortar. This study deals with refractory mortar and is a part of initial basic step. In this study mechanical properties are considered before fire resistance test. As result of test for examination of mechanical properties, it is considered that a consistency and strength of refractory mortar in this study are suitable to construct.

• Congress of the korean instutite of fire investigation
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• 2010.12a
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• pp.63-79
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• 2010

It is found to the arc trace on the junction termination of 345kV cable. According to the analysis of the cable material is judged to be good. Manufacturing and design problems are not considered. In construction defects, it was estimated to the low level of insulation oil. In the majority of the arc trace appeared XLPE is found. However, there is no Soots mark, yellow band has not been confirmed, not associated with a radial arc of the spider leg is not evidence. In other opinions, void, contamination or jut are not found on the inside of XLPE. Thus, by the attachment of the impurities in surface of XLPE insulation is judged to the breakdown.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 2008.04a
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• pp.131-134
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• 2008

In this study, the lower detonation limits(LDL) and the upper detonation limits(UDL) of the flammable substances predicted with the appropriate use of the heat of combustion and the stoichiometric coefficient. The values calculated by the proposed equations were a good agreement with literature data within a few percent. From a given results, It is to be hoped that this methodology will contribute to the estimation of the detonation limits of for other flammable substances.