• Journal of the Korean Crystal Growth and Crystal Technology
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• v.25 no.6
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• pp.252-256
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• 2015

Nitrogen oxides ($NO_X$) was emitted from flue gas of stationary sources and exhaust gas of mobile sources, can leads to various environments problems. Selective Catalysts Reduction (SCR) is the most effective $NO_X$ removal system. Commercial $V_2O_5-WO_3/TiO_2$ catalysts, usually containing $V_2O_5$ 0.5~3 wt%, $WO_3$ 5~10 wt%, and $V_2O_5$ is active in the reduction of $NO_X$ but also in the desired oxidation of $SO_2$ to $SO_3$. To reduce the amount of vanadium, using graphene matrix supported vanadium to synthesize nanocomposite. Then, we fabricated to 1 inch honeycomb type of SCR catalysts adding graphene-vanadium nanocomposite. The chemical-physical characteristics and the catalytic activity were performed by XRD, XRF, BET and Micro-Reactor (MR). As a result, the De-NOX performance was showed, similar to the commercial catalyst activity as 77.8 % and using nanocomposite catalyst as 77.1 % at $350^{\circ}C$.

• Journal of the Mineralogical Society of Korea
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• v.27 no.1
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• pp.31-40
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• 2014

In present study, we geochemically investigated the fresh coal ashes and the saline ash pond of an electric power plant in Korea, which burns imported bituminous coals. The goals are to see the chemical changes of the ash pond by reaction with coal ashes and to investigate the relative leachability of elements from the ashes by reaction with saline waters. For this study, one fresh fly ash, one fresh bottom ash, and 7 water samples were collected. All the ash samples and 2 water samples were analyzed for 55 elements. The results indicated that the fly ashes are enriched with chalcophilic elements such as Cu, Zn, Ga, Ge, Se, Cd, Sb, Au, Pb, and B relative to other elements. On the other hand, concentrations of As, Ba, Co, Ga, Li, Mn, Mo, Sb, U, V, W, and Zr are much higher in the ash pond than those dissolved in the seawater. Ag, Bi, Li, Mo, Rb, Sb, Sc, Se, Sn, Sr, and W show high ratios of elemental concentrations in pond water to those in the fly ash. Our results imply that the leaching of trace elements is regulated by geochemical controls such as solubility and adsorption even though the trace elements are relatively enriched on the ash surfaces after the coal combustion due to their volatilities.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.21 no.2
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• pp.92-97
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• 2011

Landfill is the main treatment method for bottom-ash because it has not only an irregular particle size and ingredients but also not proper recycling treatment. The aim of this study is to raise recycling rate of bottom-ash(nonplasticity pulverulent) and for the purpose of alternatives of clay to investigate the properties of Bottom-ash (B/A)-Hard Clay (H/C) bodies with controlled interfacial chemistry properties. After investigating the sedimentation height of suspensions with controlled pH, it was discovered that there was no hetero-polar aggregation for mixed slips because hard clay and bottom-ash had similar interfacial chemistry properties. Also, bulk density, water absorption, and microstructure properties of each pellet was observed that made by silp casting method and manufactured at $50^{\circ}C$ intervals between $1000{\sim}1250^{\circ}C$. As a result, dispersed slip of clay and bottom ash are possible for slip casting and plastic forming process because they exhibit Bingham plastic behavior. Products that made by slip with dispersed clay and bottom ash are not only suitable for KS L 4201 and KS L 1001 at $1250^{\circ}C$ but it is also possible to apply for ceramic and sanitary ware because specific gravity was about 15 % lighter than general ceramic materials.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.18 no.5
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• pp.211-216
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• 2008

The artificial lightweight aggregate (ALA) was manufactured in a rotary kiln at $1125^{\circ}C$ using green body formed by pelletizing the batch powder composing of coal bottom ash (CBA) produced from power plant, clay and dredged soil (DS). The TCLP (Toxicity characteristic leaching procedure) results showed that the dissolution concentration of heavy metal ions of ALA fabricated in this study was below the limitation defined by the enforcement regulations of wastes management law in Korea. The ALA containing 60$\sim$70 wt% CBA had a bulk density of 1.45$\sim$1.49 and a water absorption of 17.2$\sim$18.5 %. The impact values for oven-dry state and saturated-surface dry state of ALA were 27.4$\pm$1.3 and 23.4$\pm$2.6 % respectively. The 28-days compressive strength of concrete made with various ALA was $22.7\sim27.8 N/mm^2$. The slump of concrete with ALA containing CBA 60 and 70 wt% were 7.9 and 14.3 cm respectively. The unit weight of concrete made with any ALA fabricated in this study was satisfied with the standard specifications of lightweight concrete for the civil engineering and construction presented by Korea as below $1.84 ton/m^3$.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.25 no.6
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• pp.257-262
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• 2015

Recently the world wide efforts reduce occurrence of $CO_2$; global warming main reason. The aim of this study is to improve recycling rate of the fly ash (FA) and fused waste slag (FWS) from the power plant and to carbonate under supercritical condition ($40^{\circ}C$, $80kgf/cm^2$ pressure, 60 min) for $CO_2$ fixation. Specimens of mortar with various mixing ratios of FA, FWS (from 100:0 to 20:80 in 5 steps of 20 % reduction each time), distilled water and 3 M NaOH alkali activators were prepared. As a result, the proportion of weight change ratio increases with CaO content, to 12 % after carbonation under the supercritical condition. There is difference of compressive strength between the carbonated and the alkali activator mortar specimens. The stabilization of $CO_2$ fixation through carbonation which could confirm the applicability of the eco-friendly materials without loss of compressive strength.

• Journal of the Korea Institute of Building Construction
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• v.9 no.5
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• pp.63-70
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• 2009

This study is part of an ongoing research project on the development of a sound-absorbing lightweight foamed concrete manufactured by a hydro-thermal reaction between silica and calcium. As the silica source, pulverized bottom ash was used, and as several cementitious powders of ordinary portland cement, alumina cement and calcium hydroxide were used. Manufacture of foamed concrete was accomplished using the pre-foaming method to make a continuous pore system, which is the method of making the foam by using a foaming agent, then making the slurry by mixing the foam, water, and powders. The experiment factors are W/B, foam agent dilution ratio, and foam ratio, and test items are compressive strength, dry density, void ratio, and absorption rate, as evaluated by NRC. The experiment results showed that the sound absorption of lightweight foamed concrete satisfied NRC requirements for the absorbing materials in most of the experiments. It is thus concluded that foam ratio was the most dominant factor, and significantly affected all properties of lightweight foamed concrete in this study. W/B rarely affected total void ratio and continuous void ratio as well as compressive strength, and dry density and foam agent dilution ratio also had little effect onalmost all properties. The analysis of the correlation between NRC, absorption time, continuous void ratio, and absorption time showed that the interrelationship of the continuous void ratio was high.

• KOREAN JOURNAL OF CROP SCIENCE
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• v.47 no.6
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• pp.459-464
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• 2002

This experiment was conducted to know the changes of bioactive component content in four-year-old peony (Paeonia lactiflora Pall.) root with various drying methods such as room temperature drying, $50^{\circ}C$ heat-air drying, room temperature drying after $80^{\circ}C$ boiling water treatment and freeze drying, and to establish the optimum drying method for high quality production of Paeoniae Radix. For this purpose, the contents of paeoniflorin, albiflorin and five phenolic compounds (gallic acid, benzoic acid, (+)-catechin, (-)-epicatechin and (+)-taxifolin 3-O-$\beta$-D-glucopyranoside) in peony root with different drying methods were analyzed by RP-HPLC. The contents of paeoniflorin, albiflorin and (+)-taxifolin 3-O-$\beta$-D-glucopyranoside at room temperature drying were higher than in the other drying methods and that of gallic acid at 8$0^{\circ}C$ boiling water treatment was the highest among that of all drying methods. In the case of freeze drying, the contents of (+)-catechin, benzoic acid and (-)-epicatechin were the highest among those of all drying methods. As increase of drying and treatment temperature, the contents of paeoniflorin, albiflorin, (+)-taxifolin 3-O-$\beta$-D-glucopyrano-side, (+)-catechin and benzoic acid were decreased.

• Journal of the Korean Society for Marine Environment & Energy
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• v.10 no.2
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• pp.118-124
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• 2007

The oceans could absorb almost all the anthropogenic carbon dioxide the mankind has been producing eventually, but in the nature the air-sea $CO_2$ exchange occurs very slowly and to lower the atmospheric $CO_2$ concentration substantially $CO_2$ must be injected to the interior of the ocean directly. If we inject $CO_2$ collected at the major $CO_2$ sources into the international waters in the Philippine Sea or east of Japan, we could store the $CO_2$ in the oceans effectively for a few hundred years. When $CO_2$ is dissolved into the water, PH drops. The creatures adapted to the deep oceans where environment is very stable could be affected by even a small change in pH significantly. If, therefore, we are to inject $CO_2$ into the oceans, we must assess the effect of $CO_2$ injection in the marine ecosystem beforehand. Only when the damage to the marine ecosystem is smaller than the benefit from the $CO_2$ injection, $CO_2$ injection is effective.

• Journal of the Korean Society for Marine Environment & Energy
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• v.19 no.4
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• pp.286-296
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• 2016

Offshore CCS technology is to transport and inject $CO_2$ which is captured from the power plant into the saline aquifer or depleted oil-gas fields. The more accumulated injected $CO_2$, the higher reservoir pressure increases. The increment of reservoir pressure make a dramatic change of the operating conditions of transport and injection systems. Therefore, it is necessary to carefully analyze the effect of operating condition variations over the injection period in early design phase. The objective of this study is to simulate and analyze the $CO_2$ behavior in the transport and injection systems over the injection period. The storage reservoir is assumed to be gas field in the East Sea continental shelf. The whole systems were consisted of subsea pipeline, riser, topside and wellbore. Modeling and numerical analysis were carried out using OLGA 2014.1. During the 10 years injection period, the change of temperature, pressure and phase of $CO_2$ in subsea pipelines, riser, topside and wellbore were carefully analyzed. Finally, some design guidelines about compressor at inlet of subsea pipeline, heat exchanger on topside and wellhead control were proposed.

• Asian Journal of Turfgrass Science
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• v.24 no.2
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• pp.199-204
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• 2010

Much of the coal ash by thermal power plant has gradually been increased, however researches on the recycling of bottom ash has not been investigated enough so far. In this research, the lysimeter test was conducted to find out the possibilities of bottom ash as soil amendment to improve the physiochemical properties of sandy topsoil of turfgrass in golf course. The turfgrass growth test and leaching test were conducted on the lysimeter. The lysimeter columns were manufactured with various topsoil mixing ratios of 0, 10, 20, 30, and 50% of bottom ash with sand. As a result of leachate analysis through the lysimeter column, the higher ratios of bottom ash mixed affect significantly on water holding capacity of topsoil sand media with decreasing of the percolation rate. The results of leachate analysis in every three days interval, the pH of leachate increased with the bottom ash ratios, but the volume of $NO_3$-N, $NH_4$-N and K decreased significantly. However, the level of EC of leachate had constantly maintained. These results indicate that the application of bottom ash may improve turfgrass growth with water holding capability and fertility of sandy topsoil. However, the negative effects of the bottom ash also evaluated by reducing water permeability and solubility of $PO_4$-P by adsorption into soil particles. The results indicates that the reasonable mixing ratio of the bottom ash as soil amendment should be less than 20% (v/v) with sand which has a low water-holding and fertility in golf course topsoil layers.