• Elastomers and Composites
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• v.46 no.3
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• pp.245-250
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• 2011

The self diffusions and hole volumes of amorphous region of poly(acrylonitrile)-poly(vinyl chloride) fibers were investigated by experiments of stress relaxation. The experiments of stress relaxation were carried out using the tensile tester with the solvent chamber. The flow parameters of filament fibers were obtained by applying the experimental stress relaxation curves to the theoretical equation of stress relaxation. From the flow parameters, the hole volumes, self diffusions, viscosities and thermodynamic parameters of solid polymers were calculated. It was observed that the flow parameters of these samples are directly related to the hole volumes, self diffusions and flow activation energies of flow segments.

• Journal of the Korean Chemical Society
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• v.58 no.3
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• pp.251-257
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• 2014

The stress relaxation of poly(methyl acrylate)-poly(acrylonitrile) copolymer samples were carried out in air and distilled water at various temperatures using the tensile tester with the solvent chamber. The rheological parameters were obtained by applying the experimental stress relaxation curves to the theoretical equation of the Eyring-Halsey non-Newtonian model. The self diffusion, hole volume, viscosities, and thermodynamic parameters of copolymer samples were calculated from rheological parameters and crystallite size in order to study of flow segments in amorphous region. It was observed that the rheological parameters of these copolymer samples are directly related to the self diffusion, hole volume, viscosities, and thermodynamic parameters of flow segments.

• Tunnel and Underground Space
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• v.14 no.6 s.53
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• pp.411-422
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• 2004

Sinkhole subsidence occurs over abandoned mine workings and can be detrimental to human lives, damage to properties and other surface structures. In this study, simulation of sinkhole development process is performed using special finite element procedure. Especially, creation of mine voids due to roof falls and generation of goaf from broken rocks are simulated using active-passive-active finite elements. An active or solid element can be made passive or void once the tensile failure criterion is satisfied in the specified sinkhole formation zone. Upon completion of sinkhole development process, these passive elements in again be made active to simulate goal region. Several finite element models are analyzed to evaluate the relationships between sinkhole formation with width of gallery. depth of mine, roof condition and bulking factor of roof rocks. This study demonstrates that the concept of passive elements in numerical analysis can be used effectively for analyzing sinkhole formation or roof fall phenomenon in general.

• Journal of the Korean Applied Science and Technology
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• v.36 no.4
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• pp.1050-1059
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• 2019

The self diffusion, hole volume, and flow thermodynamic parameters of polyamide fibers were calculated from rheological parameters and crystallite size in order to study of flow segments in amorphous region. The stress relaxation of polyamide filament fibers were carried out in air and various solvents at various temperatures using the tensile tester with the solvent chamber. The rheological parameters were obtained by applying the experimental stress relaxation curves to the theoretical equation of the Ree-Eyring and Maxwell non-Newtonian model. It was observed that the rheological parameters of these polyamide filament fibers are directly related to the relaxation spectra, self diffusion, viscosities, and activation energies of flow segments.

• Journal of the Korean Chemical Society
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• v.50 no.3
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• pp.196-202
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• 2006

The self diffusion distributions of viscoelastic molten polyurethanes were determined from the relationship between the relaxation spectra and the distribution of self diffusion. The relaxation spectra of ester, PCL and PCL dyed type molten polyurethanes were obtained by applying the experimental stress relaxation curves to the theoretical equation of the Ree-Eyring and Maxwell non-Newtonian model(REM model) from computer calculation. The experiments were carried out at various temperatures using the physica rheometer with the temperature controller. The self diffusion and hole distance of amorphous region of polyurethane samples were investigated by experiments of stress relaxation. The diffusion coefficients and hole volumes were calculated from rheological parameters and crystallite size in order to study the diffusion of flow segments in amorphous region. It was observed that the relaxation spectra and self diffusions of these polymer samples are directly related to the distribution of molecular weights, viscosities, hole volumes and activation energies of flow segments.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2002.04a
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• pp.70-71
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• 2002

연소실의 세장비(aspect ratio)가 작으면서 추진제의 고 충전을 이용한 단시간 연소 모타는 유도탄의 사출 모타 용으로 사용될 수 있다. 사출 모타는 일반적으로 모타 무게에 대한 제약 조건이 까다롭지 않기 때문에 무게 경량화에 대한 부담은 줄어들지만, 모타의 부피가 커지면 유도탄 발사 장치의 부피가 커지기 때문에 공간적인 측면에서 가능한 작게 하는 것이 시스템 전체의 효율을 증대시킬 수 있다. 또한 사출 모타의 연소 시간이 짧기 때문에(1초 이내) 추진제의 웹 두께가 작으므로 연소실의 주어진 공간에서 추진제를 많이 채우기 위한 방법으로 원통 튜브형 그레인을 여러 개의 다발로 사용하는 방법이 효과적이다. 이러한 관점에서 사출 모타용으로 다발 원통 튜브형 그레인을 설계/제작/연소시험을 하였더니 작은 저주파(약 10Hz)의 연소 불안정 현상이 발생하였다. (그림1). 이러한 주파수 대역은 일반적으로 잘 알려진 연소 불안정 모드 (longitudinal, tangential, and radial mode)와는 다른 아주 특이한 현상이다. 이러한 현상의 주 원인은 연소실 내 압력의 비평형에 의한 현상이라 판단되어 다음과 같은 연구를 수행하였다. 1) 그레인 튜브간의 압력 평형을 원활하게 하기 위하여 그레인에 구멍(홀)을 뚫어서 연소 안정화에 미치는 영향에 대한 연구(그림2), 2) 그레인에 홀을 뚫지 않고 격자와 격자간의 공간을 이용하여 그레인 간에 발생된 저주파의 압력 진동을 산란/소멸 시키는 연소 안정화 연구(그림3).

• Proceedings of the KIPE Conference
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• 2016.11a
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• pp.99-100
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• 2016

본 논문에서는 위치 센서 없이 단상 모터를 운전하는 방법을 제안한다. 제안하는 센서리스 방식은 PM flux 추정기와 PLL 옵저버를 이용하여 구현된다. 이를 통해 홀 센서로 인한 조립상의 문제와 부피 증가 문제를 해결 할 수 있다. 또한 효율적인 운전을 위하여 0 속도가 아닌 파워가 다시 들어올 때 모터를 다시 구동하는 재 시작 전략 또한 제안한다. 이 방식은 위치 센서가 존재 하지 않기 때문에 재 시작시의 각도를 구하기 위한 0 전류 제어와 함께 전압의 zero crossing을 이용한다.

• Korean Chemical Engineering Research
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• v.51 no.6
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• pp.760-765
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• 2013

Lysozyme crystallization was performed by using flow-focusing chip in droplet-based microfluidic system. Water-in-oil droplets were formed in the system and collected on petri-dish and cross type mold. Liquid-liquid reaction of lysozyme and sodium chloride occurred in the droplet and crystals were observed through microscope. Solution pH was varied as 4.8 and 7.2. Crystals of polyhedron and plate-like shape were obtained at pH 4.8, while needle structure crystals formed at pH 7.2. Lysozyme in single droplet for two pHs were crystallized with constant or decreased droplet size. However, crystals at pH 4.8 were only obtained in the droplet of which size was increased by the interaction between droplets. Droplet volume did not change at pH 7.2 and crystals formed in both droplets.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.47 no.9
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• pp.617-628
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• 2019

The currently considered pyrotechnic separation nut is separated through the complicated process, because it has many internal moving parts and two variable-volume chambers connected by the vent hole. Therefore, it has many design parameters. Some of these are the contact angles between internal moving parts, the masses of the internal moving parts, the inner diameter of the push rod protrusion, the initial volumes of the chambers, the mass of the explosive charge, and the diameter of the vent hole. To improve the pyrotechnic separation nut, it is necessary to understand how the behavior of the separation nut is changed according to design parameters. In this point of view, parametric studies are carried out using the previously proposed prediction model for pyrotechnic separation nut behaviors. In each case, the parameter of the interest is changed while the others are kept unchanged. From the results, it is investigated how each design parameter influences the separation behavior.

• Elastomers and Composites
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• v.45 no.4
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• pp.250-255
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• 2010

From the three element non-Newtonian model of one non-Newtonian viscoelastic Maxwell elements and a elastic spring, the stress relaxation equation was derived. The various model parameters of this equation were evaluated by appling the experimental results of stress relaxation to the stress relaxation equation. The theoretical curves calculated from this model parameters agreed with the experimental stress relaxation curves. From the parameters of nonlinear viscoelastic model, the hole volume, fine structure, viscoelastic properties and mechanical properties of polymer fibers were studied. The experiments of stress relaxation were carried out using the tensile tester with the solvent chamber. The stress relaxation curves of the two types polyacrylonitrile-polyvinylchloride copolymer and another two types PVC monofilament fibers were obtained in air and water of various temperatures.