• Explosives and Blasting
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• v.38 no.1
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• pp.1-13
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• 2020

Gas explosion accidents are steadily being issued due to increased gas consumption in Korea and foreign countries. To analyze the effects of these gas explosions, a TNT equivalent method is used. In this study, the TNT equivalent was calculated in the event of an explosion due to the volume content in the air of CO, CH₄ and C₂H₄, the typical flammable gases emitted by coal. Also, the peak overpressure and impulse variation with the distance from explosion point were compared and analyzed by gas using the calculated equivalent value of TNT. The upper limit of the TNT equivalent for the three mixed gases is up to five times larger than the other gases mixture. In addition, the peak overpressure and impulse, which are factors of the TNT characteristic curve, are also increasing as the number of gases increases.

• Journal of Animal Environmental Science
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• v.13 no.2
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• pp.129-138
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• 2007

A natural deodorizing agent (NDA) was made using pine cone byproduct, and its effects on malodor emission and composting were analyzed in this study. NDA was manufactured by mixing pine cone byproduct with three species of microorganisms and water containing mineral nutrients and molasses, and then by incubating for 48 hours at $30^{\circ}C$. Lab scale experiments were done with three treatment groups, T1 (control, sawdust treatment), T2 (microorganisms and sawdust treatment group), and T3 (NDA and sawdust treatment group). During composting, temperatures reached over $55^{\circ}C$, a minimum temperature for the inactivation of pathogenic microorganisms. No differences were found in physicochemical composition of compost among treatments. However, it was observed that over usage of NDA could obstruct temperature increase, since the biodegradation rate of organic matter of NDA was relatively low, Nitrogen loss due to ammonia gas emission, which normally happens during composting, was reduced by using NDA, and hence the nitrogen level of final compost was higher in T3 than in others. During experiment, it was found that ammonia gas emission was entirely lasted through compositing duration, but the $CH_3SH$ and $H_2S$ gases were produced only at early stage of composting. The ammonia concentration trapped in $H_2SO_4$ solution during 31 days of composting in T1, T2 and T3 was 12,660mg/L, 11,598mg/L and 7,367mg/L, respectively, showing distinguishable reduction of ammonia gas emission in T3. The emissions of $CH_3SH$ and $H_2S$ gases were also remarkably reduced in T3. Based on these obtained results, usage of the deodorizing agent made with pine cone byproduct could reduce the emission of malodor during composting, without any deterioration of compost quality.

• Journal of Energy Engineering
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• v.8 no.2
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• pp.309-316
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• 1999

A numerical study for the turbulent reacting flow in an orimulsion gasifier has been carried out to analyze the characteristics of chemical reaction by orimulsion droplets. In this study, our interest has been focused on the effect of oxidizer to orimulsion ratio, which is one of the key parameters of gasification operation, as well as on the distribution of chemical species. In addition, we have conducted numerical calculations to understand the effect of droplet size, spray angle and injection velocity of fuel so as to acquire the basic information on the operating range of orimulsion gasifier. The result of numerical calculations showed that the gas composition of CO and H$_2$concentrations was the highest when the oxidizer to orimulsion ratio was about 0.88 and the reactivity of orimulsion increased as the droplet size reduced with proper spray angle. Also, we have carried out the analysis on the orimulsion gasification in the 100 ton/day-scale gasifier based upon the prior study in order to obtain the basic data for the proper operating condition using orimulsion feed.

• Journal of Advanced Marine Engineering and Technology
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• v.40 no.3
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• pp.174-179
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• 2016

To protect the ocean environment, the use of liquefied natural gas (LNG) carriers, bunkering ships, and fueled ships is increasing. Recently, Korean shipbuilders have developed and supplied a partial reliquefaction facility for boil-off-gas (BOG). Despite reasonable insulation, heat leakage in vessel storage tanks causes LNG to be continuously evaporated as BOG. This research analyzed the maximum liquid yield rate for various partial reliquefaction systems (PRS) and considered related factors affecting yields. The results showed a liquid yield of 48.7% from an indirect PRS system (heat exchanges between cold flash gas and compressed natural gas), and 41% from a direct PRS system (BOG is mixed with flash gas and discharged from a liquid-vapor separator). The primary factor affecting liquid yield was heat exchanger effectiveness; the exchanger's efficiency and insulation characteristics directly affect the performance of BOG reliquefaction systems.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.36 no.2
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• pp.225-232
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• 2012

A chemical reactor network (CRN) was developed for a lean premixed gas turbine combustor to predict the emission of pollutants such as NOx and CO. In this study, the predictions of NOx and CO emissions from lean premixed methane-air combustion in the gas turbine were carried out using CHEMKIN and a GRI 3.0 methane-air combustion mechanism, which includes the four NO formation mechanisms for various load conditions. The calculated results were compared with experimental data obtained from a modified test combustor to validate the model. The contributions of the four NO pathways were investigated for various load conditions. The effects of nonuniformity of the mass flux and of the equivalence ratio of the injector on the NOx formation were investigated, and a method of reducing the pollutant formation was suggested for the development of a sub-10 ppm gas turbine combustor.

• Korean journal of applied entomology
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• v.56 no.3
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• pp.253-259
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• 2017

Fumigation using chlorine dioxide ($ClO_2$) has been regarded as a potential control technique against stored grain insect pests. The control efficacy can be enhanced with increase of opening rates of spiracles by facilitating the toxic gas delivery to internal body. To test this hypothesis, this study used the Indianmeal moth, Plodia interpunctella, which was known to be susceptible to $ClO_2$, and analyzed the opening rate of spiracles. A total of 9 pairs of spiracles were observed in P. interpunctella larvae, in which one pair was located on the prothorax and eight pairs were on the abdomen. Within the body, the spiracles were connected to longitudinal and transverse tracheal trunks. The open spiracles were determined by the dye-infiltration method. Based on this method, the opening rate of spiracles increased up to about 60% with increase of ambient temperatures. Furthermore, exposure to carbon dioxide stimulated the opening rate of spiracles up to about 95%. In contrast, exposure to $ClO_2$ prevented the spiracle opening and resulted in only 25% of spiracles in an opening state. The addition of carbon dioxide to $ClO_2$ treatment rescued the opening rate of spiracles as much as the carbon dioxide single treatment. Based on this modulatory activity of carbon dioxide against spiracles, the combined treatment of $ClO_2$ with carbon dioxide resulted in significant increase of its toxicity against P. interpunctella compared to a single $ClO_2$ treatment.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 1999.05a
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• pp.127-132
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• 1999

우리나라의 도시폐기물 소각로는 화격자 위에 폐기물을 공급하고 화격자 밑에서 공기를 공급하는 스토커식 소각로를 대부분 채택하고 있다. 이러한 스토커 소각로 연소실내에서는 매우 복잡한 연소현상이 발생하는데, 연소실로 투입된 쓰레기는 먼저 건조부에서 수분의 건조가 일어나고, 화격자의 구동에 의해 쓰레기가 혼합 및 이송되면서 열분해, 가스화, 가연성분의 탈휘발화 및 연소, 일부 고정탄소의 표면연소 등의 반응이 일어난다. 그리고 1,2차 연소실에서는 휘발분 및 비산된 고체의 연소가 일어나는데, 이때 대류 및 복사열전달 등의 복잡한 현상을 수반하는 유동장이 형성된다. 더욱이 불균질한 특성을 갖는 쓰레기층 내에서의 복잡한 현상으로 인하여 발생하는 경계조건 설정의 불확실성으로 연소실내의 연소 현상을 전산해석하는 데에는 상당한 어려움이 있다.(중략)

• Applied Chemistry for Engineering
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• v.19 no.2
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• pp.209-213
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• 2008

The fixed bed gasification reactor with 1 m hight and 10.2 cm diameter was utilized for the hydrogen production from biomass wastes. Lauan sawdust was used for non-catalytic and catalytic gasification reaction as a sample in the fixed bed reactor. The fixed bed temperature and catalyst are the major variables affecting the process operation. Thus, the effect of fixed bed temperature and the catalysts on gas composition were studied at the temperature range from $400^{\circ}C$ to $700^{\circ}C$. The yield of hydrogen was increased at higher temperature in the fixed bed reaction. Fractions of hydrogen, carbon monoxide and methane gas in the product gas increased when sodium carbonate ($Na_2CO_3$) and potassium carbonate ($K_2CO_3$) catalysts were used. Furthermore, sodium carbonate catalyst was more effective to obtain higher hydrogen yield compared to potassium carbonate catalyst.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2011.05a
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• pp.127-127
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• 2011

수소가 아닌 헬륨을 희석 가스로 사용하여 나노결정질 실리콘박막을 증착하였고 압력과 RF power에 따른 특성을 살펴보았다. 특히, 4 Torr이상의 공정압력과 낮은 $SiH_4$ 유량을 사용하여 high pressure depletion(HPD)조건을 구현하였다. 그 결과, 6 Torr의 압력과 100W의 RF power를 사용하여 67%의 결정화도와 0.28nm/s의 증착속도를 얻었다.

• Journal of Energy Engineering
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• v.19 no.4
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• pp.221-227
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• 2010

In this study, we consider gas generation characteristics on pyrolysis of eco-fuel which were made by mixing of Pitch Pine and Lauan sawdust as biomass and polyethylene, polypropylene, polystyrene as municipal plastic wastes with catalyst in fixed bed reactor. From the result of higher heating value(HHV) measurement and of ultimate analysis, the heating value of plastic wastes and a hydrogen content in plastic sample are higher than biomass. An activation energy was reduced by a catalyst addition. However the catalyst content influence over 5 wt% was insignificant. The yield of hydrogen from gasification of biomass containing plastic wastes such as polyethylene, polypropylene and polystyrene were obtained higher than that of sole biomass. The high temperature and mixture ratio of catalyst conditions induced to high hydrogen yield in most of the samples. As the influence of catalyst, the hydrogen yield by catalytic reaction was higher than non-catalytic reaction. We confirmed that Ni-$ZrO_2$ catalyst is more active in increasing the hydrogen yield in comparison with that of carbonate catalyst. The maximum hydrogen yield was 65.9 vol.%(Pitch Pine / polypropylene / 20 wt.% Ni-$ZrO_2$(1:9) at $900^{\circ}C$).