• Journal of Radiation Protection and Research
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• v.21 no.2
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• pp.117-124
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• 1996

Source intensities in terms of the exposure rates at 1m from the fresh and spent DUPIC fuels, made from standard and extended turnup PWR fuels, were analyzed. Two cases were studied based on the degree of elimination of removable elements. Homogeneous mixture model was applied to get the exposure rate. The exposure rate turned out to be very high and sensitive to Cs elimination during the dry process. About 90% of exposure can be reduced in the case of fresh DUPIC fuel made from 10-year cooled spent PWR fuels if Cs is fully removed during the dry process. The main radiation source in spent fuels is Cs-137. The dry storage of spent DUPIC fuel may need a longer wet storage period and require a further review.

• KSBB Journal
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• v.11 no.2
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• pp.159-164
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• 1996

Transesterification of used frying oil was investigated to produce the bio-diesel oil. Experimental conditions included molar ratio of used frying oil to alcohol (1:3, 1:5 and 1:7), concentration of catalyst (0.5, 1.0 and 1.5 wt.%), ippe of catalyst(sodium melhoxide, NaOH and KOH), reaction temperature (30, 45 and $60^{\circ}C$), and types of alcohol(methanol, ethanol and butanol). The conversion of used frying oil increased with the alcohol mixing ratio and with the reaction temperature. The effect of the type of catalysts on conversion was not significant. The highest conversion was obtained when methanol was used as alcohol. Viscosity was a little higher with the ester product over grade #2 diesel oil. But the physical properties improved significantly with transesterification, resulting in similar fuel properties with those obtained for grade #2 diesel fuel.

• Transactions of the Korean Society of Mechanical Engineers
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• v.15 no.2
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• pp.618-629
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• 1991

The purpose of this experiment is to understand the distribution of coal particles inside CWM droplet which is believed to be a very important factor controlling the flame stability. CWM slurry is atomized by an air assisted twin fluid nozzle. An experimental rig is designed and fabricated. The mean size of coal particle distribution in CWM slurry, atomizing air pressure, coal particle loading in slurry and sampling position inside spray are main experimental variables. The atomized CWM droplets are sampled on the thin white layer of magnesium oxide by the emergency sampling shutter. The sampled coal particles on magnesium oxide layers are collected into test tubes and dispersed completely by Ultra-Sonicator. The size distribution of coal particles inside droplets are measured by Coulter Counter. The presence of coal particle inside the impressions of droplets on magnesium oxide layer are investigated by photo technique. There are quite many droplets which do not have any coal particles. Those are just water droplets, not CWM droplets. The population ratio of droplets without coal particles to toal number of droplets is strongly affected by the mean size of coal particle distribution in slurry and this ration becomes bigger number as the mean size of coal particles be larger. The size distribution of coal particles inside CWM droplets is not even and depends on the size of droplet. Experimental results show that the larger CWM droplets has droplets has bigger mean value of particle size distribution. This trend becomes more evident as the atomizing air pressure is raised and the mean size of coal particles in CWM slurry is bigger. That is, the distribution of coal particles inside CWM dropolets is very much affected by the atomizing air pressure and the mean size of pulverized coal particles in CWM slurry.

• Journal of Energy Engineering
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• v.11 no.1
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• pp.10-17
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• 2002

The objective of performing this study is to develop low emission condensing gas boiler. To reduce NOx and CO, three reasonable distances between burner and heat exchanger were decided through the experiments of model plane burner. Three burners with different diameter were made and then emission characteristics were examined. The optimum burner geometry was determined from flame stability, pollutant emission characteristics and applicability to the practical boiler system. In the domain of equivalence ratio 0.68~0.85, turn-down ratio of the burner designed by this research was extended to a wider range of 5 : 1. Thermal efficiency of the boiler developed by this study reached to 97% (LHV basis) of heating water efficiency at heating load of 20,000 kcal/hr when fueled by both of LNG or LPG. Emission ($O_2$=0%, wet basis) of NOx and CO concentration was 26 ppm and 85 ppm when fueled by LNG, 41 ppm and 113 ppm when fueled by LPG respectively.

• Journal of Energy Engineering
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• v.11 no.2
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• pp.90-98
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• 2002

The effects of swirl and combustion parameters on the performance and emission in a turbo-charged D.I. diesel engine of the displacement 9.4L were studied experimentally in this paper. Generally the swirl in the combustion process of diesel engine promotes mixing of the injection fuel and the intake air. It is a major factor to improve the engine performance because the fuel consumption and NO$_{x}$ is trade-off according to the high temperature and high pressure of combustion gas in a turbocharged D.I. diesel engine, it's necessary to thinking over the intake and exhaust system, the design of combustion bowl and so on. In order to choose a turbocharger of appropriate capacity. As a result of steady flow test, when the swirl ratio is increased, the mean flow coefficient is decreased, whereas the gulf factor is increased. Also, through engine test its can be expected to meet performance and emissions by optimizing the main parameter's; the swirl ratio is 2.43, injection timing is BTDC 13$^{\circ}$ CA, compression ratio is 16, combustion bowl is re-entrant 5$^{\circ}$, nozzle hole diameter is $\Phi$0.28*6, turbocharger is GT40 model which are compressor A/R 0.58 and turbine A/R 1.19.

• Journal of Energy Engineering
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• v.12 no.4
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• pp.302-308
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• 2003

The peformence tests of zinc-based desulfurization sorbents using the yellow earth as support for the hot gas clean up were carried out. The zinc-based sorbent with 25 wt％ yellow earth was prepared, and their properties such as the reaction rate, the sulfur capacity and the attrition resistance, were investigated. The reactivity tests for hot gas desulfurization was performed at middle temperatures (sulfidation/regeneration：480$^{\circ}C$/580$^{\circ}C$). During multi-cyclic desulfurization, the deactivation of zinc-based sorbent was decreased by the addition of yellow earth, and their efficiency was enhanced. The ZnO/yellow earth sorbent had high reactivity, good regenerability, long-term durability (about 19 gS/100 g sorbent for 10-cycles) and high attrition resistance (AI=19.1％). It was concluded that the peroperties of zinc-based sorbent were improved by metal oxides (Fe$_2$O$_3$, Na$_2$O, MnO$_2$, etc) in the yellow earth. From these results, it was confirmed that the desulfurization properties of zinc-based sorbents at middle temperatures could be improved by the yellow earth using as support.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 2008.04a
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• pp.161-166
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• 2008

This paper searched through mixture ratio response test whether exert effect that is some in part load performance of engine according to inlet valve angle in gasoline engine. Engines that inlet valve angle is narrow decreased quantity of NOx among exhaust gas than engine that inlet valve angle is wide, and ignition timing was retard, and fuel consumption improved a little. That quantity of NOx among exhaust gas decreases and ignition timing was retard can judge that fast burning occurred. Fast burning can decrease output decline and misfire that can happen at lean burning. Can be judged by thing which engine's combustion performance improves if inlet valve angle is narrow if examine test result.

• Applied Chemistry for Engineering
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• v.9 no.1
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• pp.89-93
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• 1998

To increase performance of electrodes used in PAFC the new fabrication method was introduced and its characteristics were investigated. In the case of traditional method, electrodes show low performance because of dead catalysts. So new process was investigated to increase the utilization of Pt catalyst. After preparing PTFE/C slurry and Pt/C powder respectively, they were mixed at the ratio of 4:6, 5:5, 6:4, 7:3, 8:2, 9:1 and electrodes were fabricated. In this case of [PTFE/C(6/4):Pt/C(1/9)=5:5], the performance of electrode, $310mA/cm^2$ at 0.7V, was most excellent.

• Applied Chemistry for Engineering
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• v.7 no.5
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• pp.992-998
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• 1996

The $La_{0.8}Ca_{0.2}CoO_3$ prepared by a citrate process was shown to have higher oxygen reduction current density and specific activity than $LaCoO_3$, $La_{0.6}Ca_{0.4}CoO_3$. In the cyclic voltammogram, an oxygen desorption peak of a $La_{0.8}Ca_{0.2}CoO_3$+carbon electrode was larger than that of a only carbon electrode. $La_{0.8}Ca_{0.2}CoO_3$ sintered at $900^{\circ}C$ for 5 hours was shown high oxygen reduction current density because of the particle size distribution and sintering effect.

• 한국신재생에너지학회:학술대회논문집
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• 2008.05a
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• pp.602-605
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• 2008

$CO_2$ 분리는 크게 연소전 탈탄소화(pre-combustion capture)와 연소후 포획(post-combustion capture)으로 나누어지는데, post-combustion capture는 연료가 연소하면 $N_2$와 $CO_2$가 남게 되고 흡수나, 흡착, 막분리 등을 이용해서 $CO_2$를 분리하는 것이고, Pre-combustion capture(연소전 회수)는 연소 전에 이산화탄소가 발생되지 않도록 하는 기술로써, 부분 산화나 개질 및 수성가스 변위반응 등이 포함되며 생성된 수소와 이산화탄소를 분리하여 수소를 생산하는 기술($CO_2/H_2$ 분리가 핵심)이다. 우리나라는 대부분 연소 후 포획 위주로 많은 연구가 진행되어 왔지만, 최근 고유가 시장이 형성되면서 석탄화력발전 및 복합가스발전(IGCC)에 필요한 연소전 탈탄소화($H_2/CO_2$ 가스로부터 $CO_2$ 회수) 연구에 산업적 관심이 급상승 되고 있다. 특히, Pre-combustion 과정에서는 높은 자체압력(약 2.5 - 5.0MPa)과 비교적 높은 농도의 $CO_2$(약 40%의)가 발생되기 때문에, 연소전 탈탄소화는 가스하이드레이트 형성/분해 원리가 가장 잘 적용될 수 있는 기술이라 할 수 있다. 본 연구에서는 비교적 저압 조건에서도 하이드레이트를 보다 쉽게 형성시키는 촉진제를 이용하여 $CO_2/H_2$ 혼합 가스 중 $CO_2$를 분리하는 실험을 수행하였다.