• Journal of the Korean GEO-environmental Society
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• v.25 no.5
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• pp.39-47
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• 2024

In this study, the environmental implications of electric arc furnace steel slag, commonly used in road construction and soil reinforcement, were examined. Experiments were conducted to assess the leaching of heavy metals based on particle size and to investigate ion leaching from specimens with varying mixtures of steel slag and clay. The official waste test revealed no detectable heavy metals in the sample items. However, when subjected to leaching experiments and analyzed using ICP-OES, certain heavy metals were found. The reaction of steel slag with water, facilitated by free CaO within the slag, was identified as the cause of leaching. Results showed that aluminum, exhibiting the highest leaching rate, displayed an inverse relationship with particle size. In mixed soil containing steel slag and clay, higher steel slag content resulted in increased aluminum leaching. Nonetheless, the quantity of leached aluminum was notably lower in mixed soil compared to pure steel slag. Furthermore, leaching of other heavy metals remained within acceptable limits. These findings suggest that recycling mixed soil of steel slag and clay for road construction or soil stabilization presents reduced environmental risks compared to using steel slag alone. Utilizing such mixtures could offer an environmentally sustainable and safe alternative.

• Journal of the Korean GEO-environmental Society
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• v.12 no.7
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• pp.31-37
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• 2011

Only a few studies have been conducted using reduced slag as recycled material. The reduced slag in electric furnace is produced as a by-product in making a steel and a few applications of the reduced slag as expensive additives and bonding materials or as the stabilized soils was reported. The purpose of this study is to present the feasibility of the reduced slag as recycled material, especially, in a field of civil engineering. In order to achieve the purpose experiments such as SEM and XRF analysis was conducted for the reduced slag in electric furnace. Based on the results various geotechnical experiments were conducted to know engineering properties of slag-soil mixtures. Weathered soils and clay are mixed with reduced slag for various ratios. As the ratio of reduced slag to weathered soil increases, the maximum dry unit weight of the mixture decreased with increasing optimum moisture content. The results indicates that there is no effect on a reduced slag by compaction efforts. The shear strengths of the weathered soil-slag mixtures are slightly higher or similar to those of weathered soils. The permeability of the weathered soil-slag mixtures is similar to that of silty or sandy soils. Therefore, it is possible to use the mixtures as embankment or backfill materials in the fields. The unconfined strength of the mixtures of reduced slag and clay is higher than that of clay and it tends to increase with the curing time. Therefore it can be used to improve the soft ground.

• Journal of the Korea Concrete Institute
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• v.27 no.1
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• pp.3-9
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• 2015

In this study, hydration properties of ordinary Portland cement were examined, shown from a limestone and blast furnace slag alone or their mixture up to 10% as a minor mineral additives. As of setting time, it was identified that final setting became faster as the amount of limestone mixture increased, which showed limestone accelerated early hydration faster than blast furnace slag. This is because limestone did accelerate the hydration of alite. At the age of 3 days, limestone 5%-blast furnace slag 5% mixture had the highest compressive strength of mortar. It is because hydration acceleration of alite by limestone, and $Ca(OH)_2$ that was additionally formed by hydration acceleration of alite reacted with blast furnace slag, and as a result, additionally created C-S-H hydrate. Regarding the hydration properties by the age of 7 and 28 days, limestone 3%-blast furnace slag 7% of composited mixture showed the largest compressive strength, and in comparison with the 3 days in curing age. This period is when hydration reaction of blast furnace slag is active and the amount of hydrate depends on the amount of blast furnace slag mixture more than that of the limestone mixture. And in order to vitalize hydration reaction of blast furnace slag the amount of $Ca(OH)_2$ created has to increase, and thus, a small amount of limestone is necessary that can accelerate the hydration of alite. Therefore, after the age of 7 days, the fact that there were a large amount of blast furnace slag mixture and small amount of limestone mixture was effective to the strength development of ordinary Portland cement.

• Journal of the Korea institute for structural maintenance and inspection
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• v.23 no.1
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• pp.45-53
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• 2019

Slump flow, compressive strength, flexural strength and drying shrinkage were measured to evaluate workability and mechanical performance of geopolymer. Experimental parameters include the addition of gypsum, blending ratio of blast furnace slag and fly ash and addition of shrinkage reducing agent. Geopolymer using blast furnace slag mixed with gypsum showed larger slump flow than blast furnace slag without gypsum. The slump flow when blending ratio of blast furnace slag and fly ash is 5:5 tended to be larger than the slump flow when blending ratio is 8:2. Geopolymer using blast furnace slag without gypsum showed higher compressive strength and flexural strength than blast furnace slag mixed with gypsum. Compressive strength and flexural strength tended to be higher when blending ratio of blast furnace slag and fly ash was 8:2 than when blending ratio was 5:5. Drying shrinkage decreased with increasing fly ash and blast furnace slag without gypsum, and it was found that shrinkage reducing agent is effective to reduce drying shrinkage of geopolymer.

• Journal of the Korean GEO-environmental Society
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• v.13 no.6
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• pp.33-39
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• 2012

With the increase of steel production research interest on the recycling of slag as a by-product also increases steadily. Currently in Korea a lot of researches on blast-furnace slag have been made. However, the researches on the steel slag have been rarely made. Also, a research of steel slag, especially the use of oxidation furnace slag as aggregates for concrete progress, is performing actively, but the research results on the furnace slag are almost nothing. Recently, the research about the furnace slag as backfill material and embankment material confirmed the possibility of the clay soil amendment. Therefore, the object of this study is to review the possibility as civil engineering materials for soil improvement and to find the optimum mixture ratio of furnace slag. This research analyzed the ingredient component of the reduced slag by SEM, XRF, XRD tests and examined the strength increase using unconfined compression tests when the clay and reduced slag are mixed each other. Through this test, the definite strength increase is confirmed according to the mixture of the reduced slag and the possibility of soil improvement is also confirmed based on this result. The object of the study is both utilizing the by-product for civil engineering purpose and effective recycling by the application of the furnace slag for soil improvement.

• Journal of the Korean GEO-environmental Society
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• v.12 no.7
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• pp.23-29
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• 2011

The oxidation slag has been widely used in civil engineering project, whereas the reduced slag from electric furnace has yet to be applied. Consequently in order to find out the recycling method in civil engineering field, the mineral compositions of the reduced slag were analyzed and some tests on water quality were performed to estimate the potential release of toxic compounds. Slag-soil mixtures of 0, 10, 20 and 30%(dry weight) soil were prepared in lysimeter columns and the effluents were collected with the period of one, two and four week options in closed system, respectively. The result from qualitative and quantitative analysis using X-ray Diffraction(XRD) and X-ray Fluorescence(XRF) indicates that the main mineral of the reduced slag is $Ca_2(SiO_4)$, a kind of calcium silicate. Also, the leaching medium analyzed by Inductively Coupled Plasma Optical Emission Spectroscopy(ICP-OES) showed that main heavy metals such as Al, Fe and Mn are included in the reduced slag due to the effect of steel production process. It can be seen that the leachate does not violate the regulation guide line of waste material of heavy metal. Also the pH levels were increased from pH 6.9 for 0% soil to pH 10 for 30% soil. However the influence on leachate circulation period of one through four weeks was negligible.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.677-680
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• 2008

The surface of particles was energetically modified by inter-grinding OPC and BFS in vibration mill for improvement of the early strength and low-heat evolution of concretes. BFS was pre-grinding in ball-mill to 2535(BS2) and 3245 $cm^2/g$(BS3), in blaine surface area. The inter-grinding time in vibration mill was changed from 10 minutes to 30 minutes. And Mixing ration of BFS to OPC was changed in 60, 70, 80%. After inter-grinding, the change of specific surface area, particle size distribution, hydration heat of cement and compressive strength of mortar were measured. As the result of comparison test with LHC, it was found that the mixture and inter-grinding time satisfying the value of over 100% of compressive strength for 7 days and under 170J/g of heat of hydration for 72 hours. and it was confirmed that the possibility of low heat slag cement utilizing blast furnace slag(BS2, BS3) with the low fineness in high volumes.

• Journal of the Korea institute for structural maintenance and inspection
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• v.16 no.3
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• pp.109-116
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• 2012

This study investigated the effects of blast furnace slag mortars activated with sodium hydroxide(NaOH) and gypsum in relation to flow, setting time and compressive strength. The parameters in this studied was the gypsum ratio 0 to 50%, 3M and 6M of activator concentration and $20{\pm}2^{\circ}C$ and $35{\pm}2^{\circ}C$ of curing temperatures. The results of flow was increase, setting time was increase as the amount of gypsum increases. But the results of compressive strength was dependent on the gypsum ratio, indicating that the compressive strength increased with the increase of the amount of gypsum until a certain limit, beyond which the strength decreased quickly.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2021.05a
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• pp.78-79
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• 2021

This study compared and analyzed the fluidity and compressive strength characteristics of mortar using ferronikel slag powder and mixed slag fine aggregate as part of the study to reduce environmental load and increase recycling rate of industrial by-products.

• Magazine of the Korea Concrete Institute
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• v.10 no.2
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• pp.155-165
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• 1998

굳지 않은 콘크리트의 슬럼프손실을 저감시키기 위한 목적으로 고로슬래그 미분말 및 플라이애쉬의 혼합비율과 혼화제의 첨가방법을 변화시킨 콘크리트의 믹싱후 경과시간에 따른 슬럼프 변화에 대하여 고찰하였다. 연구결과 보통포틀랜드시멘트에 고로슬래그 비분말 또는 플라이애쉬를 혼합한 콘크리트가 혼화재를 혼합하지 않은 콘크리트보다 슬럼프손실을 줄일 수 있었으며, 고로슬래그 미분말과 플라이애쉬를 각각 50 및 5%를 혼합한 3성분계 콘크리트의 경우 슬럼프손실을 저감시키는데 유효하였다. 또한 혼화제의 일부를 15분후 분할하여 후첨가하는 혼합방법이 굳지않은 콘크리트의 슬럼프손실을 저감시키는데 가장 큰 효과가 있다. 한편 혼화재를 혼합한 3성분계 보통강도용 및 고강도용 콘크리트의 재령 28일까지의 압축강도는 혼화재를 혼합하지 않은 콘크리트보다 작았으나 재령 91일 압축강도는 31% 및 15%정도 크게 증가하였다.