• Title/Summary/Keyword: 혼합물온도

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Separation of Oxygen/Nitrogen Mixture by Polysulfone Hollow-Fiber Membrane (폴리설폰 중공사막에 의한 산소/질소 혼합물의 분리)

  • 김종수;송근호;이광래
    • Membrane Journal
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    • v.9 no.2
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    • pp.89-96
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    • 1999
  • 국내 K-그룹 연구소에서 제조한 폴리설폰 중공사막의 산소/질소 혼합물에 대한 압력, stage , cut , 공급기체 혼합물의 조성에 따른 분리성능을 조사하였다. 본 실험의 압력범위와 온도 3$0^{\circ}C$에서의 이상분리인자 (O2/N2)는 5.7이었으며, 유입기체 혼합물의 21mole % 산소농도가 약 50 mole%로 농축되었다. 저압측과 고압측의 압력비는 산소농축에 미치는 영향이 적었으며 이상분리인자의 영향은 매우 컸다. 그러나, 이상분리인자가 증가함에 따라 이상분리인자의 영향은 둔화되었다. 따라서, 이상분리인자가 큰 신소재 개발과 더불어 공정변수의 최적화가 필요하다. 수학적 모델링에 의한 예측치와 실험치가 잘 맞았다.

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Measurement of Autoignition Temperature for Toluene + iso-Propanol (IPA) and p-Xylene+n-Butanol Systems (Toluene과 iso-Propanol계 및 p-Xylene과 n-Butanol계의 자연발화온도 측정)

  • Yoon, Yeo-Song;Ha, Dong-Myeong;Yu, Hyun-Sik;Lee, Yong-Soon
    • Fire Science and Engineering
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    • v.24 no.2
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    • pp.172-177
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    • 2010
  • The values of the AIT (autoignition temperature) for fire and explosion protection are normally the lowest reported. The MAITB (Minimum Autoignition Temperature Behavior) of flammable liquid mixture is exhibited when the AITs of mixture is below the AIT of the individual components. The MAITB is an interesting experimental features, which can be significant from the perspective of industrial fire safety. In this study, the AITs of toluene + iso-propanol(IPA) and p-xylene + n-butanol systems were measured using ASTM E659-78 apparatus. The AITs of toluene, iso-propanol (IPA), pxylene and n-butanol which constituted two binary systems were $547^{\circ}C,\;463^{\circ}C,\;557^{\circ}C$ and $340^{\circ}C$ respectively. The toluene + iso-propanol(IPA) system is exhibited MAITB at 0.3 mole fraction of toluene, and its minimum autoignition temperature was $460^{\circ}C$.

Pre-service Chemistry Teachers’ Understanding of the Boiling Process of a Liquid Mixture (액체 혼합물의 끓음에 대한 예비 화학교사의 이해)

  • Park, Kira;Yoon, Heesook
    • Journal of the Korean Chemical Society
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    • v.59 no.5
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    • pp.454-465
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    • 2015
  • The goal of this study is to investigate pre-service chemistry teachers’ understanding of the boiling process of a liquid mixture. We surveyed 65 students in the chemistry program of the College of Education about the boiling point of a 50%(by mole) ethanol aqueous solution and the temperature changes during heating. We then interviewed 9 of these students. According to the survey results, the percent of the pre-service teachers who thought that the boiling point of the ethanol solution would be ‘between the boiling points of ethanol and water (78-100 ℃)’ and ‘the same as that of ethanol’ were 52.3% and 35.4%, respectively. The majority of those who stated the former explained that the boiling point of the ethanol solution increased due to the effects of attraction or blocking by water molecules. Most of those who believed the latter explained that physical properties such as the boiling point would not be changed by the addition of water. With regard to the temperature change during heating, 69.2% of the teachers thought that the temperature would increase gradually while boiling, which some thought resulted from the increasing amount of water in the solution as the ethanol boiled off. Others thought that two temperature plateaus would be observed as each component of the liquid mixture underwent phase transition at its specific boiling point. When asked about the particle model of the gas phase during the boiling and evaporation process, some students drew both ethanol and water during evaporation but only ethanol when boiling. We discussed several alternative concepts of pre-service chemistry teachers about the boiling process of liquid mixtures and ways to improve their understanding.

Analysis of the Effect of Maximum Aggregate, Porosity, and Temperature on Durability of Porous Asphalt Mixtures (최대입경, 공극률, 그리고 온도가 다공성 아스팔트 혼합물의 내구성에 미치는 영향분석)

  • Yoo, In-Kyoon;Lee, Su-Hyung;Park, Ki-Soo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.12
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    • pp.227-233
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    • 2020
  • The demand for porous asphalt mixtures is increasing because it has a range of functions, such as reducing traffic accidents and traffic noise. On the other hand, its application is delayed due to concerns about durability. This study examined the effects of the maximum aggregate size, temperature, and porosity of an asphalt mixture on the durability. To this end, the durability measure was set to the Cantabro loss rate. Mixtures having the same porosity of 20% and the maximum aggregate diameters of 13 mm, 10 mm, and 8 mm were tested at 20℃ and -20℃. Mixtures containing 20% and 22% voids with the same material having the same diameter were tested. With 20% porosity, there was no significant difference in durability when there was a change in the maximum aggregate size. There was a significant difference between 20℃ and -20℃, but no significant difference in durability when there was a 2% difference between 20% and 22%. The significance of this study is that the durability was presented quantitatively by tests and statistical analysis. This research will help improve the durability of porous asphalt mixtures by evaluating the factors affecting the durability quantitatively.

Evaluation of Laboratory Performance Characteristics of Fiber-Reinforced Asphalt Concrete (섬유활용 아스팔트 콘크리트의 실험적 공용특성평가)

  • Kim, Nak-Seok
    • Journal of the Korean Society of Hazard Mitigation
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    • v.2 no.2 s.5
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    • pp.61-72
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    • 2002
  • The optimum fiber and asphalt binder contents were decided on the base of the Mashall mix design method. To compare the mechanical characteristics between the conventional(dense-graded 20) and the fiber-reinforced mixtures, indirect tension tests were conducted under three temperatures(5, 20, 60$^{\circ}C$). In particular, the wheel tracking tests were performed to evaluate the rutting resistances of the mixtures. Test results showed that the indirect tensile strength of fiber-reinforced asphalt concrete was higher than that of conventional one. The toughness of fiber-reinforced mixture was 1.27 to 1.97 times higher than that of conventional one, depending upon the temperature. In addition, the results of wheel tracking tests and the retained indirect splitting tension tests conducted at $60^{\circ}C$ revealed that the resistance to permanent deformation of fiber-reinforced mixture was stronger than that of the conventional one.

Analysis of the Phase Change Temperatures and the Latent Heat Characteristics of $H_2O$-NaCl Mixtures for the Cold thermal Energy Storage (냉축열을 위한 $H_2O$-NaCl 혼합물의 상변화 온도와 잠열 특성분석)

  • Song, H.K.;Ro, J.G.
    • Solar Energy
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    • v.19 no.2
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    • pp.57-65
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    • 1999
  • In this study $H_2O$-NaCl mixture was selected as a cold thermal storage material and its phase change temperature($liquid{\Leftrightarrow}solid$) was controlled with the molar concentration of NaCl. Ion dipole interaction mechanism and the fusion and crystallization structure of $H_2O$-NaCl were visualized with the low and high concentration of NaCl in the heating and cooling processes. In this study, the original cause of the appearance of two steps phase change period in heating and cooing processes were found by the visualization of the ion dipole interaction mechanism of $H_2O$-NaCl, and the theoretical equation of the phase change temperature variation in the NaCl high molar concentration was rearranged.

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An Evaluation of Epoxy Asphalt Mixtures for Long-Span Steel Bridge Deck (장경간 강바닥판 교량용 에폭시 아스팔트 혼합물의 적용성 평가)

  • Baek, Yu Jin;Park, Chang Woo;Kim, Nakseok
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.32 no.6D
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    • pp.579-586
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    • 2012
  • The main objective of the research is to evaluate the laboratory performances of epoxy asphalt mixtures for long-span steel bridge decks. The aggregate gradations were recommended for field applications. The laboratory performance test results showed that the durability of epoxy asphalt mixtures was more noticeable than that of conventional ones. The structural analysis was conducted using resilient modulus and bond-shear test results. The analysis results revealed that just 9% out of total bond-shear stress was enough for the entire required bond-shear stress in the pavement system. The tensile stresses in the bridge decks were within limits compared to the laboratory test results from the Nanjing Grand Bridge in China. As a result, the laboratory performances of the epoxy asphalt mixtures for long-span steel bridge decks were better than those of conventional asphalt mixtures. However, the laboratory performance tests of epoxy asphalt mixtures for long-span steel bridge decks should be conducted precisely since the strengths of the mixtures are sensitive to the temperatures and curing times.

Impact of Xanthan-locust Bean Gum Mixtures on Pasting/Paste Characteristics and Freeze-thaw Stabilities of Waxy Rice Starch (찹쌀 전분의 페이스팅/페이스트 특성 및 냉해동 안정성에 대한 잔탄검-로커스트콩검 혼합물의 영향)

  • Kim, Hyun-Seok
    • Korean Journal of Food Science and Technology
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    • v.46 no.5
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    • pp.593-600
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    • 2014
  • Normal rice starch (NRS) possesses high gelling and retrogradation tendencies, with poor freeze-thaw stability. This study investigated the effects of partial replacement of waxy rice starch (WRS) with gums on the pasting and viscoelastic properties as well as the freeze-thaw stability of the WRS paste. Xanthan gum (XAT), locust bean gum (LBG), and their mixtures were individually mixed with WRS at a ratio of 1:19 (w/w). WRS-gum mixtures were pasted using a rapid visco-analyzer at 5% total solid content, and analyzed with respect to the pasting and viscoelastic characteristics, and freeze-thaw stability. Pasting properties of WRS were retarded in pasting temperature and enhanced in pasting viscosity (although peak viscosity was varied) by partial replacement with gum and gum mixtures. Storage moduli of WRS-XAT:LBG pastes became similar to those of NRS paste with increasing angular frequency from 1 to 10 rad/s. Finally, WRS-XAT and WRS-XAT:LBG possessed more enhanced freeze-thaw stability than NRS.

Measurement and Prediction of Autoignition Temperature(AIT) of n-Decane+Ethylbenzene System (노말데칸과 에틸벤젠 계의 최소자연발화온도 측정 및 예측)

  • Lee, Jae-Hwa;Kim, Gui-Ju;Hong, Soon-Kang;Ha, Dong-Myeong
    • Journal of the Korean Institute of Gas
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    • v.19 no.5
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    • pp.54-60
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    • 2015
  • The autoignition temperature (AIT) of a material is the lowest temperature at which the material will spontaneously ignite. The AIT is important index for the safe handling of flammable liquids which constitute the solvent mixtures. This study measured the AITs of n-decane+ethylbenzene system by using ASTM E659 apparatus. The AITs of n-decane and ethylbenzene which constituted binary system were $210^{\circ}C$ and $430^{\circ}C$, respectively. The experimental AITs of n-decane+ethylbenzene mixture were a good agreement with the calculated AITs by the proposed equations with about $11^{\circ}C$ A.A.D.(average absolute deviation).

An Experimental Study on the Compressive Strength of Impervious Waterproof Asphalt Mixture (불투수성 방수아스팔트 혼합물의 압축강도 특성에 관한 실험적 연구)

  • Kim, In-Joong;Kim, Kyeong-Jin;Lee, Seung-Yong;Jeong, Yong-Hwi
    • Proceedings of the Korean Society of Disaster Information Conference
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    • 2016.11a
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    • pp.349-352
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    • 2016
  • 기존의 가열식 일반아스팔트 공법은 동결 등에 원인으로 포장재의 수명이 짧아져 잦은 유지보수가 필요한 문제점을 갖고 있으며, 이로 인해 내구성이 뛰어난 포장공법의 필요성이 대두되고 있다. 불투수성 방수아스팔트는 이러한 문제를 해결하기 위한 방안의 하나로 아스팔트 혼합물이 골재와 골재 사이를 강력하게 부착하며, 골재간의 공간을 메우고, 골재표면을 두껍게 코팅하여 골재 상호간의 강한 접착을 유지시켜주는 열가소성 폴리머를 사용한 포장공법이다. 본 연구는 불투수성 방수아스팔트 혼합물 개발을 위한 연구의 일환으로 석회석함유량, 유제함유량, 다짐강도, 실험온도 차이에 따른 불투수성 방수아스팔트 혼합물의 압축강도 특성을 실험을 통해 비교 검토하였다. 결과 분석을 통해 각각의 변수에 따른 압축강도 특성을 파악하였으며, 불투수성 방수아스팔트 혼합물 배합설계에 기초자료로 활용하고자 한다.

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