• Title/Summary/Keyword: 혼입시기

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Influence of Addition Timing and Dosage of ERCO on Autogenous Shrinkage and Fundamental Properties of HPFRCC (ERCO 혼입시기 및 혼입율 변화가 HPFRCC의 자기수축저감 및 기초적 특성에 미치는 영향)

  • Han, Cheon-Goo;Lee, Je-Hyun
    • Journal of the Korea Institute of Building Construction
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    • v.18 no.4
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    • pp.313-319
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    • 2018
  • For the entire world, due to the increased risks of explosion and terrorisms, damages on human life and properties have been increased. Regarding this issue, research on high performance fiber reinforced cementitious composite (HPFRCC) with the protecting performance for the building structures or military facilities against explosion or bombing has been increased (important). Among a series of the research, using emulsified refined cooking oil(ERCO) to reduce the autogenous shrinkage may cause some adverse effect on performance of the mixture such as increased viscosity, decreased fluidity, air content, and strength. Hence, in this research, based on the optimum design of HPFRCC induced by previous research, the influence of ERCO adding timing and dosage on autogenous shrinkage and fundamental properties were analyzed. As a result, it was revealed that 0.5% of ERCO should be added right after the mixing is most effective for the quality of HPFRCC such as fluidity, strength development and autogenous shrinkage reducing.

Synthesis and Characterization of Iron Incorporated MCM-41 (철 혼입 MCM-41 촉매의 제조 및 특성 연구)

  • Cho, Deug-Hee;Jin, Hangkyo
    • Applied Chemistry for Engineering
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    • v.19 no.2
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    • pp.242-248
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    • 2008
  • The iron incorporation method according to addition steps during the synthesis of iron incorporated MCM-41 was examined systematically. Iron addition during pH adjustment was more effective than the other addition steps which were addition to template agent solution or addition after mixing of template agent and sodium silicate solution. In case of iron addition after extraction of template agent from as-synthesized silica MCM-41, most of the iron was on the surface of pores not the frame work structure. Although the amount of iron addition was increased, there was a limit to the amount of iron incorporated into framework structure of MCM-41. The synthesized FeMCM-41 catalyst showed catalytic activities for propylene oxidation. Otherwise, there might be no attractive differences of catalytic activity among the addition steps of iron.

Effect of Incorporation Times of Green Barley and Hairy Vetch on Rice Yield in Paddy Soil with Liquid Pig Manure (돈분액비를 시용한 녹비보리 및 헤어리베치의 혼입시기가 벼 수량에 미치는 영향)

  • Kang, Se-Won;Seo, Dong-Cheol;Lee, Sang-Gyu;Seo, Young-Jin;Park, Ju-Wang;Ryu, Jin-Hee;Kim, Min-Tae;Kang, Hang-Won;Heo, Jong-Soo;Cho, Ju-Sik
    • Korean Journal of Environmental Agriculture
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    • v.32 no.4
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    • pp.287-293
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    • 2013
  • BACKGROUND: Soil incorporation of green manure crop(GMC) and liquid pig manure(LPM) is one of the methods for reduction of chemical fertilizer and the increase of crop yield. The objective of this study was to select optimal incorporation time of GMCs on growth and nutrient property in paddy soil treated LPM. METHODS AND RESULTS: The kinds of GMCs were Hordeum vulgare L.(green barley, GB) and Vicia villosa roth(hairy vetch, HV). The effects of GMCs on rice yield were investigated under different incorporation times of GMCs(LPM1: at 25 days before rice transplantation, LPM2: at 18 days before rice transplantation, LPM3: at 11 days before rice transplantation). In GB treatments, the biomass was greater in the order of $$LPM3{\geq_-}LPM2{\geq_-}LPM1$$. Contents of N, P and K ranged 1.21~1.28, 0.36~0.38 and 1.41~1.45%, respectively, regardless of incorporation times. The amounts of nutrient supply in GB treatments were higher in LPM1 than those in other treatment conditions. In GB treatments, rice yields in LPM1, LPM2 and LPM3 were 523, 525 and 526(increasing yield 3% than control) kg/10a, respectively. In HV treatments, the amounts of nutrient supply were higher in the order of $$LPM3{\geq_-}LPM2{\geq_-}LPM1$$. Rice yields were 530 kg/10a for LPM1, 531 kg/10a for LPM2, 535 (increasing yield 5% than control) kg/10a for LPM3 in HV treatments, respectively. CONCLUSION(s): The optimum incorporation time of green barley and hairy vetch was at 11 days before rice transplantation(LPM3) in paddy soil with liquid pig manure.

Ore Minerals, Fluid Inclusion and Stable Isotope Studies of the Bongsang Gold-silver Deposit, Republic of Korea (봉상 금-은광상의 광석광물, 유체포유물 및 안정동위원소 연구)

  • Yoo, Bong-Chul;Lee, Jong-Kil;Lee, Gil-Jae;Lee, Hyun-Koo
    • Economic and Environmental Geology
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    • v.41 no.1
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    • pp.1-14
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    • 2008
  • The Bongsang gold-silver deposit consists of quartz veins that fill along the fault Bone within Cretaceous andesitic lapilli tuff. Mineralization is occurred within fault-breccia zones and can be divided into two stages. Stage I which can be subdivided into early and late depositional stages is main ore mineralization and stage II is barren. Stage I began with deposition of wall-rock alteration minerals and base-metal sulfides, and was deposited by later native silver, Ag-bearing tetrahedrite, polybasite and base-metal sulfides such like pyrite, sphalerite, chalcopyrite and galena. Fluid inclusion data indicate that homogenization temperatures and salinities of stage I range from 137 to $336^{\circ}C$ and from 0.0 to 10.6 wt.% NaCl, respectively. It suggests that ore forming fluids were cooled and diluted with the mixing of meteoric water. Also, temperature and sulfur fugacity deduced mineral assemblages of late stage I are $<210^{\circ}C\;and\;<10^{-15.4}$ atm, respectively. Sulfur(3.4%o) isotope composition indicates that ore sulfur was mainly derived from a magmatic source as well as the host rocks. The calculated oxygen{2.9%o, 10.3%o(quartz: 7.9%o, 8.9%o, calcite: 2.9%o, 10.3%o)}, hydrogen(-75%o) and carbon(-7.0%o, -5.9%o) isotope compositions indicate that hydrothermal fluids may be meteoric origin with some degree of mixing of another meteoric water for paragenetic time.

A Study on Reducing the Corrosion of Steel Rebar Embedded in Concrete using Various Materials of Coating (다양한 코팅재를 이용한 콘크리트 중 철근의 부식 억제에 관한 연구)

  • Song, Il-Hyun;Lee, Yong-Soo;Ryou, Jae-Suk
    • Proceedings of the Korea Concrete Institute Conference
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    • 2010.05a
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    • pp.179-180
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    • 2010
  • The literature of present study was performed with content of chloride by total 6 level. After casting, and then, to measure the results of corrosion in a quick time used accelerated method of corrosion during 20 weeks. Both Galvanic and Half-cell for 20 weeks was used to model the initial time to corrosion, and then current of corrosion was measured by using Linear polarization at the end of cycling. The processing of steel used in concrete is same way as the case of mortar and also the initial time of corrosion was measured.

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Analysis of Autogenous Shrinkage Properties of High Strength Mortar in Relation to the Time and Rate of Mixing ERBO (ERBO 혼입율 및 혼입시기 변화에 따른 고강도 모르타르의 자기수축 특성분석)

  • Kim, Tae-Woo;Beak, Cheol;Hyun, Seong-Yong;Lee, Jea-Hyun;Han, Min-Cheol;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.05a
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    • pp.180-181
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    • 2017
  • This study aims to analyze the high strength mortar's fundamental properties and autogenous shrinkage properties by taking into consideration the result of the previous study in which it was found that ERBO(Biodiesel) exercises greatest effect on the expansion effect of mortar, and changing the time and rate of mixing the ERBO. A total of five levels were set as experimental variables: the three levels of the rate of ERBO, 0, 0.5, 1.0%, and the two levels of the time of mixing the ERBO: first, adding the ERBO with the mixing water and mixing it before, and second, mixing it after the mortar is completely mixed. It was found that the rate of length change decreased as the rate of ERBO increased, and the rate of length change was lower when the ERBO was mixed sooner.

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Genetic Environment of the Samsung Gold-Silver Deposit, Republic of Korea: Ore Minerals, Fluid Inclusion and Stable Isotope Studies (삼성 금-은광상의 생성환경: 광석광물, 유체포유물 및 안정동위원소 연구)

  • Yoo, Bong-Chul;Lee, Gill-Jae;Koh, Sang-Mo;You, Byoung-Woon
    • Economic and Environmental Geology
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    • v.43 no.5
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    • pp.443-453
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    • 2010
  • The Samsung gold-silver deposit consists of quartz veins that fill along the fault zone within Cretaceous shale and sandstone. Mineralization is occurred within fault-breccia zones and can be divided into two stages. Stage I is main ore mineralization and stage II is barren. Stage I is associated with wall-rock alteration minerals(sericite, pyrite, chlorite, quartz), rutile, base-metal sulfides(pyrrhotite, pyrite, sphalerite, chalcopyrite, galena), and electrum. Stage II occur quartz, calcite and pyrite. Fluid inclusion data indicate that homogenization temperatures and salinities of stage I range from 145 to $309^{\circ}C$ and from 0.4 to 12.4 wt.% NaCl, respectively. It suggests that hydrothermal fluids were cooled and diluted with the mixing of meteoric water. The main deposition of base-metal sulfides and electrum occurred as a result of cooling and dilution at temperature between $200^{\circ}C$ and $300^{\circ}C$. Sulfur(9.3~10.8‰) isotope composition indicates that ore sulfur was mainly derived from a magmatic source as well as the host rocks. The calculated oxygen[-2.3~0.9‰(quartz: 0.3‰, 0.9‰, calcite: -2.3‰)] and hydrogen[-86~-76‰(quartz: -86‰, -82‰, calcite: -76‰)] isotope compositions indicate that hydrothermal fluids may be meteoric origin with some degree of mixing of another meteoric water for paragenetic time.

Stable Isotope and Fluid Inclusion Studies of the Daebong Gold-silver Deposit, Republic of Korea (대봉 금-은광상에 대한 유체포유물 및 안정동위원소 연구)

  • 유봉철;이현구;김상중
    • Economic and Environmental Geology
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    • v.36 no.6
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    • pp.391-405
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    • 2003
  • The Daebong gold-silver deposit consists of mesothermal massive quartz veins thar are filling the fractures along fault shear (NE, NW) Bones within banded or granitic gneiss of Precambrian Gyeonggi massif. Based on vein mineralogy, ore textures and paragenesis, ore mineralization of this deposits is composed of massive white quartz vein(stage I) which was formed in the same stage by multiple episodes of fracturing and healing, and transparent quartz vein(stage II) which is separated by a major faulting event. Stage I is divided into the 3 substages. Ore minerals of each substages are as follows: 1) early stage I=magnetite, pyrrhotite, arsenopyrite, pyrite, sphalerite, chalcopyrite, 2) middle stage I=pyrrhotite, arsenopyrite, pyrite, marcasite, sphalerite, chalcopyrite, galena, electrum and 3) late stage I=pyrite, sphalerite, chalcopyrite, galena, electrum, argentite, respectively. Ore minerals of the stage II are composed of pyrite, sphalerite, chalcopyrite, galena and electrum. Systematic studies (petrography and microthermometry) of fluid inclusions in stage I and II quartz veins show fluids from contrasting physical-chemical conditions: 1) $H_2O-CO_2-CH_4-NaCl{\pm}N-2$ fluid(early stage I=homogenization temperature: 203∼3$88^{\circ}C$, pressure: 1082∼2092 bar, salinity: 0.6∼13.4 wt.%, middle stage I=homogenization temperature: 215∼28$0^{\circ}C$, salinity: 0.2∼2.8 wt.%) related to the stage I sulfide deposition, 2) $H_2O-NaCl{\pm}CO_2$ fluid (late stage I=homogenization temperature: 205∼2$88^{\circ}C$, pressure: 670 bar, salinity: 4.5∼6.7 wt.%, stage II=homogenization temperature: 201-3$58^{\circ}C$, salinity: 0.4-4.2 wt.%) related to the late stage I and II sulfide deposition. $H_2O-CO_2-CH_4-NaCl{\pm}N_2$ fluid of early stage I is evolved to $H_2O-NaCl{\pm}CO_2$ fluid represented by the $CO_2$ unmixing due to decrease in fluid pressure and is diluted and cooled by the mixing of deep circulated meteoric waters ($H_2O$-NaCl fluid) possibly related to uplift and unloading of the mineralizing suites. $H_2O-NaCl{\pm}CO_2$ fluid of stage II was hotter than that of late stage I and occurred partly unmixing, mainly dilution and cooling for sulfide deposition. Calculated sulfur isotope compositions ({\gamma}^{34}S_{H2S}$) of hydrothermal fluids (3.5∼7.9%o) indicate that ore sulfur was derived from mainly an igneous source and partly sulfur of host rock. Measured and calculated oxygen and hydrogen isotope compositions ({\gamma}^{18}O_{H_2O}$, {\gamma}$D) of ore fluids (stage I: 1.1∼9.0$\textperthousand$, -92∼-86{\textperthansand}$, stage II: 0.3{\textperthansand}$, -93{\textperthansand}$) and ribbon-banded structure (graphitic lamination) indicate that mesothermal auriferous fluids of Daebong deposit were two different origin and their evolution. 1) Fluids of this deposit were likely mixtures of $H_2O$-rich, isotopically less evolved meteoric water and magmatic fluids and 2) were likely mixtures of $H_2O$-rich. isotopically heavier $\delta$D meteoric water and magmaticmetamorphic fluids.

Occurrence and Genetic Environments of Quartz Veins from the Jukwangri area, Hwawon-myeon, Jeollanamdo, Republic of Korea (전남 화원면 주광리일대 석영맥의 산상 및 생성환경)

  • Yoo, Bong-Chul;Lee, Hyun-Koo;Choi, Dong-Ho
    • Economic and Environmental Geology
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    • v.39 no.6 s.181
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    • pp.653-662
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    • 2006
  • Quartz veins from the Jukwangri area of Hwawon-myeon are epithermal quartz veins that are filling the NW or NE-trending faults within Precambrian metasedimentary rocks. Based on their prolongation and ore grades, No. 1 quartz vein can be traced for about 200 m and varies 0.1 to 3 m in thickness. Mineralization of No. 1 quartz vein can be divided into hypogene and supergene stages. Hypogene stage is associated with hydrothermal alteration minerals(phyllic and argillic zones) such as illite, sericite and sulfides such as pyrite, arsenopyrite, sphalerite. chalcopyrite, galena, argentian tetrahedrite. Supergene stage is composed of Fe-Mn oxide, Zn-Fe oxide and Pb oxide. Fluid inclusion data indicate that homogenization temperature and salinity of hypogene stage range from 187 to $306^{\circ}C$ and ken 0.0 to 6.2 wt.% eq. NaCl, respectively. They suggest that ore forming fluids were progressively cooled and diluted from mixing with meteoric water. Oxygen($-4.1{\sim}4.1%o$) and hydrogen($-107{\sim}-88%o$) isotope com-positions indicated that hydrothermal fluids were derived from meteoric and evolved by progressive mixing with meteoric water during mineralization.

Ore Minerals, Fluid Inclusion and Stable Isotope Studies of the Buyeong Gold-silver Deposit, Republic of Korea (부영 금-은광상의 광석광물, 유체포유물 및 안정동위원소 연구)

  • Lee, Gill-Jae;Yoo, Bong-Chul;Lee, Jong-Kil;Chi, Se-Jung;Lee, Hyun-Koo
    • Economic and Environmental Geology
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    • v.42 no.6
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    • pp.513-525
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    • 2009
  • The Buyeong gold-silver deposit consists of quartz veins that fill along the NS fault zone within Cretaceous Goseong formation. Mineralization can be divided into hypogene and supergene stages. Hypogene stage is associated with hydrothermal alteration minerals such as sericite, pyrite, chlorite, epidote and sulfides such as pyrite, pyrrhotite, marcasite, sphalerite, chalcopyrite, galena and galenobismutite. Supergene stage is composed of malachite, goethite, chalcocite, and sphalerite oxide. Fluid inclusion data indicate that homogenization temperatures and salinities range from 112 to $340^{\circ}C$ and from 0.2 to 7.9 wt.% NaCl, respectively. Sulfur(3.2~3.9‰) isotope composition indicates that ore sulfur was derived from mainly magmatic source as well as partly host rocks. The calculated oxygen(4.3~6.0‰) and hydrogen(-60~-64‰) isotope compositions indicate that hydrothermal fluids may be meteoric origin with some degree of mixing of another meteoric water for paragenetic time.