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Synthesis and Characterization of Iron Incorporated MCM-41  

Cho, Deug-Hee (Avanced Chemical Technology Division, KRICT)
Jin, Hangkyo (Avanced Chemical Technology Division, KRICT)
Publication Information
Applied Chemistry for Engineering / v.19, no.2, 2008 , pp. 242-248 More about this Journal
Abstract
The iron incorporation method according to addition steps during the synthesis of iron incorporated MCM-41 was examined systematically. Iron addition during pH adjustment was more effective than the other addition steps which were addition to template agent solution or addition after mixing of template agent and sodium silicate solution. In case of iron addition after extraction of template agent from as-synthesized silica MCM-41, most of the iron was on the surface of pores not the frame work structure. Although the amount of iron addition was increased, there was a limit to the amount of iron incorporated into framework structure of MCM-41. The synthesized FeMCM-41 catalyst showed catalytic activities for propylene oxidation. Otherwise, there might be no attractive differences of catalytic activity among the addition steps of iron.
Keywords
FeMCM-41; propylene oxidation; synthesis; characterization;
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