• Title/Summary/Keyword: 형상선별

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Development of Lecithin Organogel to Improve Solubility of Genistein (레시틴 오가노겔을 이용한 난용성 제니스테인의 용해도 향상)

  • Lee, Su Jin;Kim, Jung A;Kang, Nae Gyu;Park, Sun Gyoo;Lee, Cheon Koo
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.41 no.3
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    • pp.201-208
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    • 2015
  • Organogels are semi-solid systems that consist of an apolar solvent as the liquid phase within a three-dimensional networked structure. In this study, we developed a stable and skin penetration-enhanced Lecithin Organogel (LO) containing genistein, which is one of the poorly soluble active ingredients in both polar and apolar phase. After screening of various components (type of gelators, organic and aqueous phase), hydrogenated lecithin (HL), sunflower oil (SO), dipropylene glycol (DPG), and polyethylene glycol (PEG) were mainly used in this formulation. Phase ternary diagram was employed for optimization of the composition in the LO. The formulated LO were evaluated for its organoleptic characteristics, stability, pH, rheology, phase transition temperatures, microscopic analysis and skin penetration. The optimized stable LO system can be utilized as an effective and stable cosmetic formulation that can carry poorly soluble active ingredients at high concentration for topical dermal delivery.

Characterization of Thermo-Plastic Vulcanized (TPV) Composite Prepared by the Waste Tire and Plastic Powder (폐타이어 분말과 재생PP로 제조한 열가소성 고무 플라스틱(TPV)의 물성평가)

  • An, Ju-Young;Park, Jong-Moon;Bang, DaeSuk;Kim, Bong-Suk;Oh, Myung-Hoon
    • Resources Recycling
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    • v.23 no.4
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    • pp.30-36
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    • 2014
  • 300,000 tons of waste tires are annually being produced with development of the automotive industry in Korea. Landfill and incineration treatment system are causing the economic problem through secondary environmental pollution and waste. Therefore, as one of the ways to take advantage of this, Thermo-Plastic Vulcanized (TPV) composite was prepared by the ground waste tire and plastic powders. The waste tire powder was gained by mechanical fracturing through crushers. The waste tire powder was ground by a shear crushing method and a 2-stage disk mill method instead of cutting crushing one. The waste tire powder of 50 mesh was mixed with Polypropylene(PP) in various proportions. TPVs were prepared by an extrusion, and tensile and impact tests were performed. In addition, the same experiments were repeated in 40, 80, 140 mesh conditions in order to observe size effect of waste tire powders.

Predicting Longitudinal Dispersion Coefficient of Two-dimensional Model for Analysis of Mixing in Natural Streams (하천 혼합 해석을 위한 2차원 이송-분산 모형의 종분산계수 예측)

  • Seo, Il Won;Choi, Hwang Jeong
    • Proceedings of the Korea Water Resources Association Conference
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    • 2015.05a
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    • pp.75-75
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    • 2015
  • 오염원과 취수장이 동일 구간 내에 공존하는 국내하천의 특성상, 하천 평면 내에서 오염물의 거동 및 혼합 특성을 보다 정확하게 해석하기 위해서는 2차원 이송-분산 모형의 적용이 필요하다. 이를 위해서는 2차원 모형의 주요 매개변수인 종분산계수와 횡분산계수의 적절한 입력이 매우 중요하다. 하지만 국내외적으로 횡분산계수에 대한 연구는 많이 진행된 반면, 현재까지 종분산계수에 대한 연구는 충분히 이루어지지 않은 실정이다. 분산계수를 결정하는 방법에는 실측된 농도 자료의 유무에 따라 크게 두 가지로 분류된다. 실측된 농도 자료가 없는 경우, 이론식이나 경험식을 이용하는 방법이 있다. 반면에 추적자 실험 등을 수행하여 실측된 농도 자료가 있는 경우, 모멘트법 또는 추적법을 적용하여 농도-시간 분포 곡선으로부터 분산계수를 계산하는 것이다. 모멘트법은 임의 지점에서 농도의 횡분포를 통해 얻을 수 있는 2차 모멘트의 종방향 변화율이 횡분산계수와 비례한다는 원리를 이용한 것이며, 추적법은 상류부의 관측된 농도를 입력자료로 하여 하류부의 농도를 계산한 후 계산된 농도와 실측된 하류부 농도의 비교를 통해 분산계수를 산정하는 방법이다. 본 연구에서는 불규칙한 단면 형상을 가지는 자연하천에서의 2차원 종 횡분산계수를 산정하기 위해서 Baek & Seo(2010)가 제안한 2차원 유관추적법(2D Stream-tube Routing Procedure)을 적용하였다. 본 연구에서는 국내 자연하천 중 다양한 사행형태를 갖으며 수질오염 사고의 위험이 높은 구간을 선정하고, 추적자로서 Rhodamine WT를 이용하여 현장실험을 수행하였다. 실험에서 수집된 수리량 및 농도자료로부터 추적자의 2차원적 거동을 분석하였으며, 2차원 유관추적법을 적용하여 종분산계수를 산정하였다. 그 결과 하폭 대 수심비(W/H)와 마찰손실관련 무차원변수(U/U*)의 증가에 따라 종분산계수가 증가됨을 확인 할 수 있었다. 본 연구에서 산출된 종분산계수와 선행 연구에서 수집된 자료를 이용하여 추정식을 개발하였다. 차원해석을 통해 무차원 종분산계수에 영향을 미치는 무차원 인자를 선별하고 회귀분석을 이용하여 종분산계수 추정식을 유도하였다. 추정식을 이용하여 산정한 종분산계수의 범위는 Elder (1959)가 제안한 이론값보다 약 10배 정도로 크게 나타났다. 혼합 특성이 밝혀지지 않은 자연하천에 2차원 확산모형을 적용하고자 할 때 본 연구에서 개발된 추정식으로부터 계산된 종분산계수를 사용할 수 있을 것이다.

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Deterioration Degree and Material Research of Metal Archival Objects (금속류 행정박물의 손상도 및 재질 연구)

  • Park, Hyung-Ho;Cho, Nam-Chul;Na, Mi-Sun
    • Journal of Conservation Science
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    • v.26 no.1
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    • pp.33-41
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    • 2010
  • The archival objects are tangible evidence reflecting public work as forming archives which are administrative, historic, symbolic, cultural and artistic value. They are produced from the various countries so that they have different material and manufacture techniques. However there are difficulties in conservation and management because the material investigation and conservation management system are not established. Therefore this research presents fundamental data for the efficient conservation management by material investigation and condition check metal archival objects. Among the public official presents made of metal, 12 pieces which are discoloration, oxidation, loss or crack are chosen for this research. In order to examine extensive condition of metal archival objects, the condition check card used from the domestic museum and the national museum in Japan are collected and then the new check card is produced. X-ray is used to know the making technique, binding means between different material. Portable-XRF is also used for the chemical composition analysis of metal archival objects, and then classifying respectively according to their material. As a result of condition check, it is possible to investgate the appearance character, deteriorated parts and weak parts of structure. Also P-XRF could find out the composition of metal archival objects which is different from existing condition check card. Therefore the research results can be used as fundamental data for further conservation and management as well as long-term conservation.

Study on Characteristics of Corrosion Products Generated in Iron Artifacts after Conservation Treatments (보존처리 후 철제유물에 생성된 부식물 특성 연구)

  • Jeong, Ji-Hae;Yang, Hee-Jae;Ha, Jin-Uk
    • Journal of Conservation Science
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    • v.29 no.4
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    • pp.297-309
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    • 2013
  • Iron objects become corroded at fast speed from the moment when they are excavated, so it is needed to control corrosion through processes of conservation treatment. However, re-corrosion mostly takes place in excavate iron objects, although they have already gone through the process of conservation treatment, and it is more difficult to carry out the second conservation treatment of re-corroded excavated iron objects than the first conservation treatment, and it requires a longer period of time to treat them as well. In this study, aims to discover factors of re-corrosion by scientifically analyzing corrosion products generated during the process of storage after the process of conservation treatment. The finished on conservation treatment of the iron artifacts, which were unearthed from three ancient site in Gyeongju by using the same conservation method between 2002 and 2009, re-corrosion condition observed on the packaging-iron artifacts. Focused on 9 target forged iron artifacts among them, this study analyzed the physical changes by mass measurement, naked-eye and microscopic observations and the chemical changes by SEM-EDS, XRD, IC and ICP analysis. The results show that the yellowish brown corrosion products formed on the facing surface of part dropped from the artifacts had different associated forms but acicular shape. In addition, the acicular shape became clearer as the color changed from red to yellowish brown. According to the process when the conservation treatment was completed, the mass of the artifacts increased in proportion to the corrosion products and the chloride ion ($Cl^-$) concentration had a tendency to increase relatively. ${\beta}$-FeOOH (akaganeite) was confirmed in the XRD analysis for the corrosion products of all the collected samples. As a result of ICP analysis, $Na^+$ and $Ca^{2+}$ components were confirmed.

Evaluation of the Inelastic Seismic Response of Curved Bridges by Capacity Spectrum Method using Equivalent Damping (등가감쇠비를 이용한 역량스펙트럼법에 의한 곡선교의 비탄성지진응답 평가)

  • Joe, Yang-Hee;Cho, Sung-Gook;Ma, Jeong-Suck
    • Journal of the Earthquake Engineering Society of Korea
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    • v.13 no.1
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    • pp.17-26
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    • 2009
  • The capacity spectrum method (CSM), which is known to be an approximate technique for assessing the seismic capacity of an existing structure, was originally proposed for simple building structures that could be modeled as single-degree-of-freedom (SDOF) systems. More recently, however, CSM has increasingly been adopted for assessing most bridge structures, as it has many practical advantages. Some studies on this topic are now being performed, and a few results of these have been presented as ground-breaking research. However, studies have until now been limited to symmetrical straight bridges only. This study evaluates the practical applicability of CSM to the evaluation of irregular curved bridges. For this purpose, the seismic capacities of 3-span prestressed concrete bridges with different subtended angles subjected to some recorded earthquakes are compared with a more refined approach based on nonlinear time history analysis. The results of the study show that when used for curved bridges, CSM induces higher inelastic displacement responses than the actual values, and that the gap between the two becomes larger as the subtended angle increases.

Compressive Strength Evaluation of Concrete with Mixed Plastic Waste Aggregates Filled with Blast Furnace Slag Fine Powder (무기충진재를 혼입한 복합 폐플라스틱 골재를 활용한 콘크리트 압축강도 특성)

  • Lee, Jun;Kim, Kyung-Min;Cho, Young-Keun;Kim, Ho-Kyu;Kim, Young-Wook
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.3
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    • pp.253-259
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    • 2021
  • Plastic wastes generated from household waste are separated by mixed discharge with foreign substances, and recycling is relatively low. In this study, the effect of the ratio and content of mixed plastic waste coarse aggregate(MPWCA)s and mixed plastic waste fine aggregate(MPWFA)s filled with blast furnace slag fine powder on the slump and compressive strength of concrete was evaluated experimentally. The MPWCAs were found to have a similar fineness modulus, but have a single particle size distribution with a smaller particle size compared to coarse aggregates. However, the MPWFAs were found to have a single particle size distribution with a larger fineness modulus and particle size compared to fine aggregates. Meanwhile, the effect of improving the density and filling pores by the blast furnace slag fine power was found to be greater in the MPWFA compared to the MPWCA. As the amount of the mixed plastic waste aggregate(MPWA)s increased, the slump and compressive strength of concrete decreased. In particular, the lower the slump and compressive strength of concrete was found to decrease the greater the amount of MPWFA than MPWCA when the amount of MPWA was the same. This is because of the entrapped air and voids formed under the angular- and ROD-shaped aggregates among the MPWFAs. On the other hand, the addition of the admixture and the increase in the unit amount of cement were found to be effective in improving the compressive strength of the concrete with MPWAs.

Recovery of $\alpha$-iron from converter dust in a steelmaking factory (제철소 전노 dust로부터 철분강 회수에 관한 연구)

  • 김미성;김미성;오재현;김태동
    • Resources Recycling
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    • v.2 no.2
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    • pp.27-38
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    • 1993
  • In this study, we investigated the grinding and sedimentation(elutriation) process of the dusts for the effective separation of high purity iron and iron oxides. For characterization of the dust, particle size distribution and chemical composition, were examined. The results obtained in this study may be summarized as follows : 1. The converter CF(clarifier) dust of the Pohang 1st, 2nd steel making factory and EC(Evaporation Cooler), EP(Eltrostatic precititator) dust of the Kwangyang 2nd steel making factory are composed $\alpha$-Fe(21~50%), FeO(wustite)$Fe_3$$O_4$(magnetite), $Fe_2$$O_3$, CaO, $Al_2$$O_3$, $SiO_2$, and etc. 2. Pure iron has ductile characteristic in nature, particle size of the pure iron increase by increasing the grinding time. On the other hand, it is conformed that bo고 particles of hematite and magnetite become less than 325 mesh after 10 minutes grinding. 3. By applying the elutriation technique for the EC dust of the Kwangyang 2nd steel making factory, the iron powder of high content more than 99.17% of pure Fe was recovered with 37.8% yield at grinding time for 40 minutes. 4. By applying the elutriation technique for the CF dust of the Pohang 2nd steel making factory, the iron powder of high content more than 98.38% of pure Fe was recovered with 44.42% yield at grinding time for 40 minutes. 5. When magnetic separation was performed using plastic bonding magnet of 70 gauss, more than 98% Fe grade of iron powder was recovered in the size range +65 -200 mesh but the recovery of it was low.

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Estrogeicity of Genistein and Bisphenol A (콩류식품의 주성분인 Genistein과 식품포장재 및 용기에 사용되는 Bisphenol A의 에스트로젠 효과에 관한 연구)

  • 강경선;이영순;신광순
    • Journal of Food Hygiene and Safety
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    • v.13 no.2
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    • pp.106-111
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    • 1998
  • This study has been focused on both estrogenic and proliferating activity of genistein (GEN) and bisphenol A (BPA). GEN and BPA enhance the proliferation of estrogen-dependent MCF-7 human breast cancer cells at concentrations as low as 100 nM of GEN and 8 ng/ml of BP A achieving similar effect to that of estradiol at 1 nM. Expression of the estrogen responsive gene, pS2 was also induced in MCF-7 cells by treatment with genistein at dose as low as 1 nM and BPA at dose as low as 4 ng/ml. Using 21 day-old ovariectomized nude mice, we examined end-bud formation and mammary gland development after treatment with bisphenol A or genistein. Compared with untreated control, mammary gland development and end-bud formation were significantly increased in mice fed genistein or bisphenol A (p<0.05). Taken together, it is concluded that GEN and BP A can act as an estrogen agonist resulting in cell proliferation and induction of the estrogen responsive pS2 gene in MCF-7 cells in vitro and in athymic mice in vivo, respectively. Therefore, it is suggested that GEN and BP A might modulate human endocrine system and these compounds might be considered as a endocrine modulator at the low levels of doses.

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Effects of modified atmosphere packaging (MAP) and vaporized ethyl pyruvate (EP) treatment for the shelf life of 'Seolhyang' strawberries (딸기 '설향' 품종의 MAP 및 ethyl pyruvate 처리의 유통기한 연장 효과 연구)

  • Kim, Jinse;Park, Jong Woo;Park, Seok Ho;Choi, Dong Soo;Kim, Yong Hoon;Lee, Soo Jang;Park, Chun Wan;Lee, Jung Soo;Cho, Byoung-Kwan
    • Food Science and Preservation
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    • v.24 no.3
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    • pp.351-360
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    • 2017
  • We have studied the technology to extend the storage period of 'Seolhyang' strawberries using modified atmosphere package (MAP) and ethyl pyruvate (EP) treatment for domestic distribution and export. The selected ripe strawberries harvested on December 28, 2016 at the Sancheong farmhouse were transported to the laboratory for 2 h and tested. After a day's precooling at $4^{\circ}C$, the strawberries were divided into seven experimental groups. These groups were control, active MAP using low density polyethylene (LDPE), active MAP using polyamide (PA), active MAP using PA with EP treatment, passive MAP using LDPE, passive MAP using PA and passive MAP using PA with EP treatment. Quality analysis was carried out every 4 days during the storage period of 16 days. During the storage period of 16 days, MAP decreased from 3.5% to less than 1.1% in weight loss ratio compared with control, and decreased from 36% to less than 7% in fungal incidence. In the case of fungi in the EP treatment group, hyphae did not grow on the outside of the strawberry but grew to the inside. This tendency was similar to that in the low oxygen and high carbon dioxide environment of the MAP, the mycelium of the fungus did not grow outside of the strawberry. Fungi are the biggest problem in the distribution and export of strawberries, and these results suggest that MAP alone could inhibit mold and increase shelf life.