• Title/Summary/Keyword: 형광 파라미터

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Photophysical Parameters, Photodecomposition, Fluorescence Quenching and Convolutive Voltammetry of 7-Diethylaminocoumarin (DEAC) Laser Dye (7 Diethylaminocoumarin (DEAC) 레이져 염료의 광물리적 파라미터, 광분해, 형광 소광 및 Convolutive Voltammetry)

  • El-Daly, S.A.;El-Hallag, I.S.
    • Journal of the Korean Chemical Society
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    • v.54 no.1
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    • pp.13-22
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    • 2010
  • The photophysical properties of 7-diethylaminocoumarin (DEAC) laser dye have been measured in different solvents. The emission spectrum of DEAC has also been measured in cationic (CTAC) and anionic (SDS) micelles. The laser parameters have been calculated in different solvents namely acetone, dioxane, ethanol and dimethylforamide(DMF). The photoreactivity of DEAC has been studied in $CCl_4$ solvent using 366 nm light. The values of photochemical yield (${\Phi}_c$) and rate constant (k) are determined. The interaction of organic acceptors such as picric acid (PA), tetracyanoethylene (TCNE) and 7,7,8,8-tetracynoquinonedimethane (TCNQ) with DEAC are also studied using fluorescence measurements in acetonitrile ($CH_3CN$). The electrochemical investigation of (DEAC) has been carried out using cyclic voltammetry and convolutive voltammetry combined with digital simulation technique at a platinum electrode in 0.1 mol $L^{-1}$ tetrabutyl ammonium perchlorate (TBAP) in $CH_3CN$ solvent. The electrochemical parameters of the investigated compound were determined using cyclic and convolutive voltammetry. The extracted electrochemical parameters were verified and confirmed via digital simulation method.

X-Ray Fluorescence Analysis of Iron and Titanium in Iron Ores by Dilution Parameter Method (희석 파라미터법에 의한 철광석 중 철과 티탄의 X-선 형광분석)

  • Young Sang Kim;Lee Chong Wook
    • Journal of the Korean Chemical Society
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    • v.25 no.3
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    • pp.183-189
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    • 1981
  • Iron and titanium, the major constituents in iron ores, were X-ray spectrometrically determined by using the dilution parameter method. A standard and samples possessing a similar composition were diluted with the diluent $ZrO_2$ to their proper respective ratios. After measuring the intensity of the fluorescent X-ray, the dilution parameter was calculated from the following equation. $Pa=\frac{\frac{I_{as}}{(I_{as})_d}}{D-1}{^{-1}}$The dilution parameters were used to correct the difference between the matrix effect of the standard and that of the sample. The content of the major constituents was calculated, without using any standard calibration curves, from the following equation;$W_a=W_a^*{\cdot}{\frac{I_as}{I_{as}^*}{\cdot}\frac{P_a^*}{P_a}$where asterisks indicate the standard. The results agreed with those of the wet analysis within 2% of relative error, and the precision of the experiment was also tolerably good.

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Measurement on the Methotrexate in L-${\alpha}$-Phosphatidylcholine Media by Light Sacttering (L-${\alpha}$-Phosphatidylcholine 매질에서 빔산란에 의한 Methotrexate의 측정)

  • Kim, Ki-Jun;Lee, Joo-Youb
    • Journal of the Korean Applied Science and Technology
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    • v.30 no.2
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    • pp.251-257
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    • 2013
  • The influences of Methotrexate as fluorophor, scatterer, absorber in turbid material by light scattering were interpreted for the scattered fluorescence intensity and wavelength, it has been studied the molecular properties by laser induced fluorescence spectroscopy. It has been found that the effects of optical properties in scattering media by the optical parameters((${\mu}_s$, ${\mu}_a$, ${\mu}_t$). The value of scattering coefficient ${\mu}_s$ is large by means of the increasing particles of L-${\alpha}$-Phosphatidylcholine, it has been found that the slope decays exponentially as a function of depth from laser source to detector. It may also aid in designing the best model for oil chemistry, laser medicine and application of medical engineering.

A Study on the Measurements of Beam Wave Propagation and Fluorescence Spectroscopy in Particles Media (입자매질에서 빔파동전파와 형광분광 측정에 관한 연구)

  • Kim, Ki-Jun;Lee, Jou-Youb;Sung, Wan-Mo
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.2
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    • pp.167-175
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    • 2014
  • The influences of fluorescence, scattering, and flocculation in turbid material were interpreted for the scattered fluorescence intensity and wavelength, it has been studied the molecular properties by the spectroscopy of laser induced fluorescence(LIF). The effects of optical properties in scattering media have been found by the optical parameters(${\mu}_s$, ${\mu}_a$, ${\mu}_t$). Flocculation is an important step in many solid-liquid separation processes and is widely used in Photodynamic therapy. The interactions of several colloid particles can come into play which have major effect on the flocculation and LIF process. We measured scattering and fluorescence spectra of the sample for in vitro as function of concentration from lase source to detector. The value of scattering coefficient ${\mu}_s$ is large by means of the increasing particles of scatterer. Therefore, Phorphyrin A is larger than Phorphyrin C in scattering intensity ${\mu}_s$, but Phorphyrin A is smaller than Phorphyrin C in penetration depth ${\delta}$.

A Study on Wave Propagation and Scattering in Purple Membrane and β-carotene (Purple Membrane과 β-carotene에서 산란과 파동전파에 관한 연구)

  • Kim, Ki-Jun;Park, Tae-Sul;Sung, Wan-Mo
    • Journal of the Korean Applied Science and Technology
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    • v.33 no.1
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    • pp.136-142
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    • 2016
  • The influences of fluorescence, scattering, and flocculation in random media were interpreted for the scattered fluorescence intensity and wavelength, it has been studied the molecular properties by the spectroscopy of laser induced fluorescence(LIF). The effects of optical properties in scattering media have been found by the optical parameters(${\mu}_s$, ${\mu}_a$, ${\mu}_t$). Flocculation is an important step in many solid-liquid separation processes and is widely used in Photodynamic therapy. The interactions of several colloid particles can come into play which have major effect on the flocculation and LIF process. We measured scattering and fluorescence spectra of the sample in vitro as function of distance from lase source to detector. The value of scattering coefficient ${\mu}_s$ is and ${\beta}$-carotene were measured as larger values(I, ${\delta}$) by means of closer distance from source to detector.

The Design of an Electronic Ballast for Fluorescent Lamp Using Class E Zero-Voltage-Switching Type (E급 영전압 스위칭 방식의 형광램프용 전자식 안정기 설계)

  • No, Jae-Yup;Park, Jae-Kweon;Kim, Soon-Gi;Yi, Chin-Woo
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 2005.05a
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    • pp.170-173
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    • 2005
  • 본 논문에서는 E급 영전압 스위칭(zero-voltage-switching) 인버터 방식의 타려식 형광램프용 전자식 안정기를 설계하였다. 이론을 통하여 각 파라미터 값을 산출하고, PSpice를 이용한 시뮬레이션을 통하여 램프 출력을 예측하였으며, 실제 안정기를 제작하여 전기적 특성을 살펴보았다.

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A Study on X-Ray Fluorescence Analysis of Ta$_2O_5,\;Nb_2O_5,\;SnO_2$ and ZrO$_2$ in Tin-slag Samples (희석 파라미터법에 의한 주석슬랙중 Ta$_2O_5,\;Nb_2O_5,\;SnO_2$ 및 ZrO$_2$의 X-선형광분석에 관한 연구)

  • Young Sang Kim
    • Journal of the Korean Chemical Society
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    • v.29 no.3
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    • pp.265-270
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    • 1985
  • Ta$_2$O$_5$, Nb$_2$O$_5$, SnO$_2$ and ZrO$_2$ in tin-slag samples were determined by X-ray fluorescence spectrometry using the dilution parameter method and the analytical results were compared with the data obtained by standard calibration curve method. Tin-slag samples and one standard sample having very similar composition to the tin-slags were diluted with a proper diluent (La$_2$O$_3$) to the ratio of 1: 1, 1 : 2, 1 : 3 and 1 : 4. After measuring the X-ray intensities of original and diluted samples, the values of dilution parameters were calculated by using the dilution parameter equation. Without any calibration curve, the analytical results were calculated from the equation including the dilution parameter term. The results were in good agreement with the reference data by the standard calibration curve method.

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Design of Fluorescence Multi-cancer Diagnostic Sensor Platform based on Microfluidics (미세 유체 기반의 형광 다중 암 진단 센서 플랫폼 설계)

  • Lee, B.K.;Khaliq, A.;Jeong, M.Y.
    • Journal of the Microelectronics and Packaging Society
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    • v.29 no.4
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    • pp.55-61
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    • 2022
  • There is a major interest in diagnostic technology for multiple cancers worldwide. In order to reduce the difficulty of cancer diagnosis, a liquid biopsy technology based on a microfluidic device using trace amounts of biofluids such as blood is being studied. And optical biosensing, which measures the concentration of analytes through fluorescence imaging using biofluids, requires various strategies to improve sensitivity, and specialists and equipment are needed to carry out these strategies. This leads to an increase in diagnostic and production costs, and it is necessary to develop a technology to solve this problem. In this paper, we design and propose a fluorescent multi-cancer diagnostic sensing platform structure that implements passive self-separation technology and molecular recognition activation functions by fluid mixing, only with the geometry and microfluidic phenomena of microchannels based on self-driven flow by capillary force. In order to check the parameters affecting the performance of the plasma separation part of the designed sensor, the hydrodynamic diameter of the channel and the viscosity of the fluid were set as variables to confirm the formation of plasma separation flow through simulation. And finally, we propose an optimal sensor platform structure.

광량과 온도 변화에 따른 고추(Capsicum annuum L.) 잎 광계 II의 광억제

  • 홍영남
    • Journal of Plant Biology
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    • v.38 no.4
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    • pp.373-380
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    • 1995
  • Photoinhibition of photosystem (PS) n was induced in primary leaves of 25 day-old peppers grown $100\;{\mu}mol{\cdot}m^{-2}{\cdot}s^{-1},\;at\;25^{\circ}C$. The modulation of PSII functionality in vivo was induced by varying both irradiance ($0-3000\;{\mu}molm^{-2}{\cdot}s^{-1}$) and duration (0-70 min) of light treatment. The functionality of PSII was investigated in terms of photochemical efficiency of PSII (Fv/Fm) and quantum yield of $O_2$ evolution, and expressed as a function of photon exposure [$mol\;photons{\cdot}m^{-2}$, the product of irradiance and duration of light treatment (Bell and Rose, 1981)]. Contrary to the linear decline of Fv/Fm ratio showing 50% decreases by absorption of $10\;mol\;photons{\cdot}m^{-2$, quantum yield of $O_2$ evolution decreased biphasically with increasing photon exposure, showing 50% decreases by absorption of $5.5\;mol\;photons{\cdot}m^{-2}$. Treatment of low temperature at $15^{\circ}C$ for 30 min alone did not affect the functionality of PSII, but high temperature ($45^{\circ}C$) significantly inactivated PSII activity. However, when Jeaves of pepper were subjected to low or high temperature in the presence of light, PSII was substantially photoinactivated. These results suggest the presence of different photoinhibitory mechanisms at low and high temperature.rature.

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