• Title/Summary/Keyword: 해수용 역삼투

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역삼투법 해수담수화 시스템의 최적설계 (먹는물을 생산하기 위한 시설을 중심으로)

  • 김충환
    • Proceedings of the Membrane Society of Korea Conference
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    • 1997.04a
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    • pp.131-153
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    • 1997
  • 먹는물 생산용 역삼투법 해수담수화 시설의 도입에서 시설은 원수의 수질에 대하여 먹는물 수질기준을 충분히 달성할 수 있는 능력을 가져야 하고, 또한 시설의 배치, 유지관리 및 경제성을 고려한 최적공정이 선정되어야 한다. 역삼투법에 의한 먹는물 생산용 담수화시스템의 설비는 기본적으로 막의 성능을 안정적으로 유지하기 위한 전처리설비, 역삼투막모듈로 원수를 공급하기 위한 고압펌프 및 용존염의 제거하기 위한 역삼투막모듈 등의 세부분으로 구성되지만, 실용화 장치에서는 원수를 공급하기 위한 취수설비, 막으로 처리된 생산수를 먹는물로 급수하기 위한 후처리설비, 기타 세정설비 및 세정배수처리설비 등으로 구성된다.

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The Performance Evaluation of Blended Fertilizers as Draw Solution in Forward Osmosis Desalination (유도용액으로 혼합비료를 사용한 정삼투식 해수담수화에서 혼합비료의 성능평가)

  • Kim, Seung-Geon;Lee, Ho-Won
    • Membrane Journal
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    • v.28 no.1
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    • pp.45-54
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    • 2018
  • This study is to find the optimum draw solution in fertilizer-drawn forward osmosis desalination. Considering osmotic pressure, solubility, and pH, 20 blended fertilizers were screened. Their performance were evaluated in terms of pure water permeate flux, reverse solute flux, and specific reverse solute flux for nitrogen, phosphorus, and potassium. The pure water permeate flux of blended fertilizers including KCl were relatively higher. The reverse solute flux and specific reverse solute flux for nitrogen of blended fertilizers containing ${NO_3}^-$ ion were relatively higher than those of the nitrate ion-free draw solution. Those for phosphorus, and potassium of blended fertilizers including $NH_4H_2PO_4$, and $KNO_3$ were relatively higher than those of the phosphorus-free, and potassium-free draw solution, respectively. The blended fertilizer of $NH_4H_2PO_4$ and KCl contains all of nitrogen, phosphorus and potassium which are essential elements of fertilizer, and has the relatively high water permeation flux and the low reverse solute flux for nitrogen, phosphorus, and potassium. Therefore, it is the most effective draw solution for fertilizer-drawn forward osmosis desalination.

Secondary Concentration Technology of Brine from Membrane Seawater Desalination Process with Electrodialysis (전기투석을 이용한 분리막 담수화 공정 배출 농축수의 이차 농축기술)

  • Moon, Jeong-Ki;Park, Kwang-Seok;Yoo, Yoon-Ki;Yun, Young-Ki
    • Transactions of the KSME C: Technology and Education
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    • v.1 no.1
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    • pp.69-73
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    • 2013
  • This study is about the secondary concentration technology using electrodialysis process for minimum discharge and maximize recovery ratio from seawater desalination by reverse osmosis process. The experimental method adopted the constant voltage driving method and, concentrated/desalination volume capacity ratio changes, voltage changes and electrolyte types. Multi-ion membrane is used, aiming to derive conditions to minimize the TDS concentration of desalination water, to minimize the volumes of secnodary concentraion water and minimizing the power efficiency. The results of this study are as follows. The optimal ratio of concentraion/desalination volume is 1:5, the final TDS concentration of desalinated water is 5.32g/l, the final secnodary concentrated water salinity is 17.07% and electric energy demands of desalinated water is $16.74kWh/m^3$.

Evaluation on Chemical Cleaning Efficiency of Fouled in $1,000,000m^3/day$ Sea Water Reverse Osmosis Membrane Plant (해수용 역삼투막을 이용한 $1,000,000m^3/day$ 규모의 플랜트에서 오염된 막의 화학세정 효율 평가)

  • Park, Jun-Young;Kim, Ji-Hoon;Jeong, Woo-Won;Nam, Jong-Woo;Kim, Young-Hoon;Lee, Eui-Jong;Lee, Yong-Soo;Jeon, Min-Jung;Kim, Hyung-Soo
    • Journal of Korean Society of Water and Wastewater
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    • v.25 no.3
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    • pp.285-291
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    • 2011
  • Membrane fouling is an unavoidable phenomenon and major obstacle in the economic and efficient operation under sea water reverse osmosis (SWRO). When fouling occurs on the membrane surface, the permeate quantity and quality decrease, the trans-membrane pressure (TMP) and operation costs increase, and the membrane may be damaged. Therefore, chemical cleaning process is important to prevent permeate flow from decreasing in RO membrane filtration process. This study focused on proper chemical cleaning condition for Shuaibah RO plant in Saudi Arabia. Several chemical agents were used for chemical cleaning at different contact time and concentrations of chemicals. Also autopsy analysis was performed using LOI, FT-IR, FEEM, SEM and EDX for assessment of fouling. Specially, FEEM analysis method was thought as analyzing and evaluating tool available for selection of the first applied chemical cleaning dose to predict potential organic fouling. Also, cleaning time should be considered by the condition of RO membrane process since the cleaning time depends on the membrane fouling rate. If the fouling exceeds chemical cleaning guideline, to perfectly remove the fouling, certainly, the chemical cleaning is increased with membrane fouling rate influenced by raw water properties, pre-treatment condition and the point of the chemical cleaning operation time. Also choice of cleaning chemicals applied firstly is important.

Preparation and Properties of Cellulose Triacetate Membranes for Reverse Osmosis (역삼투용 Cellulose Triacetate 막의 제조와 특성)

  • Nam, Sang-Yong;Hwang, Hae-Young;Koh, Hyung-Chul
    • Membrane Journal
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    • v.17 no.4
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    • pp.277-286
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    • 2007
  • The technology of seawater desalination has been received much attentions to solve the problem of water shortage through all over the world. In this study, it attempts to confirm the use-possibility of cellulose triacetate (CTA) for preparation of reverse osmosis membranes which have been highlighted as high efficiency and low energy consumption process for seawater desalination. The effects of casting dope parameters like an acetyl content, solvent, additives on the membrane performance were investigated. It was possible to produce the membranes which have high water flow rate and salt rejection with the increase of acetyl content and dioxane content among various dioxane/acetone ratios. Acetic acid and maleic acid were preferred for additives to produce high performance membranes. It was verified that $HOLLOSEP^{(R)}$ module which is commercialized CTA membrane by TOYOBO Co. can produce stable water production and high-quality water for long-term operation in the practice plants without any chemical treatments.

Computational Chemistry Study on Gas Hydrate Formation Using HFC & HCFC Refrigerants (R-134a, R-227ea, R-236fa, R-141b) (수소불화탄소 및 수소염화불화탄소 냉매(R-134a, R-227ea, R-236fa, R-141b)를 이용한 가스 하이드레이트 형성에 관한 계산화학적 해석)

  • Kim, Kyung Min;An, Hye Young;Lim, Jun-Heok;Lee, Jea-Keun;Won, Yong Sun
    • Korean Chemical Engineering Research
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    • v.55 no.5
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    • pp.704-710
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    • 2017
  • Although the desalination technique using gas hydrate formation is at a development stage compared to the commercially well-established reverse osmosis (RO), it still draws attention because of its simplicity and moderate operational conditions especially when using refrigerants for guest gases. In this study, DFT (density functional theory)-based molecular modeling was employed to explain the energetics of the gas hydrate formation using HFC (hydrofluorocarbon) and HCFC (hydrochlorofluorocarbon) refrigerants. For guest gases, R-134a, R-227ea, R-236fa, and R-141b were selected and three cavity structures ($5^{12}$, $5^{12}6^2$, and $5^{12}6^4$) composed of water molecules were constructed. The geometries of guest gas, cavity, and cavity encapsulating guest gas were optimized by molecular modeling respectively and their located energies were then used for the calculation of binding energy between the guest gas and cavity. Finally, the comparison of binding energies was used to propose which refrigerant is more favorable for the gas hydrate formation energetically. In conclusion, R-236fa was the best choice in terms of thermodynamic spontaneity, less toxicity, and low solubility in water.