• Elastomers and Composites
• /
• v.34 no.1
• /
• pp.45-52
• /
• 1999

This paper describes how the gold particles self assemble on the specific phase on the microphase separated block copolymer thin film and form a well ordered patterns. For this study, polystyrene-polybutadiene-polystyrene (PS-PB-PS) triblock copolymer (30wt % PS) thin films (${\sim}100nm$) having a cylindrical morphology were cast from 0.1wt% toluene solution to be used as polymer thin film templates. The films having either vertical PS cylinders or in-plane PS cylinders in PB matrix from each different solvent evaporation condition were obtained. Cross-sectional transmission electron microscopy(TEM) was used to study the surface and bulk morphologies of block copolymer thin films. Small amount of gold particles was evaporated on a block copolymer thin film template to obtain a nano-scale pattern. When an as-cast thin film template was used, gold particles preferentially self assemble on the low surface tension PB phase and a relatively well ordered pattern in nano-scale was produced. However, after the formation of a low surface energy PB rich layer upon annealing, a gold self-assembled pattern was not observed.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.10 no.8
• /
• pp.2005-2014
• /
• 2009

There are several methods to fabricate Polymer Dispersed Liquid Crystal(PDLC) films. One of them, so-called Nematic Curvilinear Aligned Phase(NCAP) film, is based on emulsion technology. To produce NCAP systems various water soluble polymers, such as partially hydrolyzed polyvinylalcohol(PVA) and polyvinyl pyrrolidone(PVP), which can form stable emulsion of liquid crystal(LC) without any stabilizers were used. In this work, we studied the dependence of emulsion stability on nature and composition of copolymers composed of water-soluble and water-insoluble moiety. We found that interfacial surface tension depends on the composition of comonomer, the copolymer concentration in the water, and the nature of hydrophobic chain. The Acrylamide -styrene(AA-ST) copolymer showed the lowest interfacial surface tension among the tested copolymers at the same concentration. Since the interfacial surface tension decreases with increasing the compatibility of copolymer with LC phase the AA-ST copolymer has the best compatibility with LC molecules. It is believed that molecules adsorbing easily on the surface of LC droplets allows the LC emulsion system to be more stable.

• Polymer(Korea)
• /
• v.28 no.5
• /
• pp.367-373
• /
• 2004

Novel non-conjugated blue light-emitting copolymers containing perylene and triazine moieties as light emitting and electron transporting units, respectively in the polymer side chain were synthesized. The resulting copolymers were soluble in most organic solvents such as chlorobenzene, THF, chloroform and benzene. The single-layered electroluminescence (EL) device consisting of indium tin oxide (ITO) /copolymer/aluminium (Al) exhibited a maximum external quantum efficiency ($0.003\%$) and a good carrier balance when the triazine content was $30\%$. In particular, the device emitted blue light (479 nm) corresponding to the emission of perylene moiety. The drive voltage was observed at 5 V and the CIE coordinate was x=0.16, y=0.17.

• Journal of the Microelectronics and Packaging Society
• /
• v.25 no.4
• /
• pp.35-40
• /
• 2018

Simple and useful synthetic process to control the morphology of block copolymers (BCPs) is required for implementation in various device applications. However, the conventional method to use colloidal templates is not enough to realize the production of pure and massive core-shell nanoparticles due to the cost-intensive complex process. Here, we introduce a novel and facile synthesis method to realize the formation of core-shell $SiO_x$ nanoparticle power by employing an immersion annealing of a sphere-forming poly(styrene-b-dimethylsiloxane) (PS-b-PDMS) BCP. We successfully obtained a PS-encapsulated $SiO_x$ nanoparticle with a diameter of ~20 nm. In addition, we analyzed how the mixing ratio of heptane/ethanol affects the BCP morphology of self-assembled PS-b-PDMS nanoparticles, showing a worm-like structure under the optimum immersion conditions. This useful approach is expected to be extendable to other solvent-based BCP synthesis, providing a new guideline for unique BCP production.

• Polymer(Korea)
• /
• v.24 no.4
• /
• pp.469-476
• /
• 2000

The miscibility between acrylic copolymers and tackifier resins influenced on adhesion properties of PSA. PSA with high molecular weight and narrow molecular weight distribution of acrylic copolymers showed systemical modification of adhesion properties of PSA by tackifier resins only in case of miscible system. It is concluded that the investigation of the miscibility between two Components is very important to adhesion properties of PSA.

• The KSFM Journal of Fluid Machinery
• /
• v.14 no.2
• /
• pp.25-28
• /
• 2011

The control rod assemblies do freely fall into the reactor core by the gravity from the control rod drive mechanism. In order to achieve a rapid shutdown and control the reactor power, it is required to insert control rod assemblies as soon as possible. In this paper, we evaluated the drop time and flow characteristics caused around guide tube for SMART(System-integrated modular advanced reactor) control rod assembly. Numerical analyses are carried out with FLUENT program of computational fluid dynamics. This study results show that the drop time of the control rod assembly in the operating condition of SMART is more 20 percent rapidly than the drop time of the room temperature and ambient atmosphere condition.

• Proceedings of the Korean Society For Composite Materials Conference
• /
• 1999.11a
• /
• pp.172-176
• /
• 1999

에폭시 수지의 강인성 향상을 위하여 양말단에 아민 반응기를 가지는 PES-CTBN-PES triblock copolymer를 합성하여 이를 에폭시 수지의 강인화제로 사용하였으며 경화제로는 p-DDS(p-dichlorodiphenylsulfone)를 사용하였다. 또한 공중합체에 의한 물성 향상효과를 CTBN과 PES-NH$_2$의 블렌드에 의한 경우와 비교하였다. 강인화된 에폭시 수지의 물성은 강인성 및 굴곡특성을 측정하여 분석하였으며, 열특성은 DSC, TGA, 및 DMA에 의해 실시되었다. 그리고 강인화된 에폭시 수지의 강인성 향상 mechanism을 규명하기 위하여 파단면을 SEM으로 분석하여 상분리 거동을 고찰하였다. 높은 유리전이온도와 우수한 기계적 물성을 가지는 고성능 기능성 폴리설폰(PES-NH$_2$)과 상용 액상 고무 첨가제인 CTBN을 이용하여 합성된 공중합체를 강인화제로 사용함으로써 열안정성, 탄성률 및 내식성의 감소없이 에폭시 수지의 쳐대 단점인 강인성을 최적 수준으로 개선시킬 수 있었으며 공중합체의 에폭시 수지에 대한 우수한 용해도에 따른 가공성이 향상되었다.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.5 no.6
• /
• pp.521-525
• /
• 2004

Biodegradation of poly(ethylene carbonate) (PEC) and their terpolymers has been investigated in vitro. PEC has been synthesized with ethylene oxide (EO) and carbon dioxide, which is one of the greenhouse gases using Zinc glutarate has been used as catalyst Carbonate terpolymers have been prepared by the use of EO, cyclohexene oxide(CHO), and carbon dioxide. High biodegradability of PEC and terpolymers with EO. has been observed. Very low biodegradation of poly(propylene carbonate) (PPC) and poly(cyclohexene carbonate) (PCHC) has been shown. The weight loss, FT-IR and SEM have been employed to characterize biodegradability.

• Communications of Mathematical Education
• /
• v.20 no.3 s.27
• /
• pp.361-372
• /
• 2006

This study was extended as one of the properties of isosceles triangles to polygons(n-angles) by conjectures-proofs-reputations-reformations and developed teaching-learning materials which can be used in high-level classes for middle and high school students.

• Proceedings of the Korean Nuclear Society Conference
• /
• 1997.05b
• /
• pp.46-51
• /
• 1997

최근 경수로 핵연료 손상 원인 중의 하나인 연료봉 마모(Fretting Wear)가 지지격자의 스프링력 저하뿐만 아니라 원자로 냉각재 유동에 기인한 집합체 진동(Self-excited Fuel Assembly Vibration)에 의해 유발될 수 있는 것으로 밝혀져 해외 연료공급자들은 새로운 연료개발시 집합체 유동시험을 수행하여 냉각재 유동에 의한 집합체 진동 여부를 확인하고 있다. 본 연구에서는 경수로 핵연료집합체에 대한 모드해석 및 진동시험으로부터 고유진동수 및 진동모드형태를 구하여 모의 집합체 유동시험 결과와 비교 평가하였고 냉각재 유동에 의해 과도한 집합체 진동이 발생됨을 확인하였으며 가연성흡수봉집합체를 삽입한 경우에 대한 유동시험 결과와도 비교하였다. 또한, 이들 집합체의 진동 변위량과 손상 연료의 마모량 분포의 상관성을 비교 평가하였다.