• Title/Summary/Keyword: 합성 제어

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동시진공증발공정의 단계별 Se 분압의 변화가 CIGS 박막에 미치는 영향

  • Kim, Jong-Geun;Lee, In-Gyu;Yun, Ju-Heon;Yun, Gwan-Hui;Park, Jong-Geuk;Kim, Won-Mok;Baek, Yeong-Jun;Jeong, Jeung-Hyeon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.370-370
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    • 2011
  • I-III-IV2족의 Cu(In,Ga)Se2 (CIGS) 박막 태양전지는 3단계(three-stage) 동시증발공정을 통하여 약 19.9%의 최고의 효율을 보유하고 있다. 3단계 공정에 있어 IV2족 Se의 증발 속도 또는 증착압력은 우선 배향성 제어 및 표면 미세구조 영향 등에 큰 영향을 미치는 것으로 알려져 있다. 본 연구에서는 CIGS 박막 합성을 위한 3단계 공정에서 각 단계별 Se 분압의 변화를 주어, 각 공정 단계에서 Se 분압의 변화가 CIGS 박막의 미세구조 및 셀 효율에 미치는 영향을 분석하였다. 3단계 공정에서 Cu, In, Ga 분압은 고정시키고, Se 분압의 크기 순서대로 1, 2, 3으로 변화시켜 CIGS 박막을 제조하였다. 이 박막의 미세구조, 특히, 우선 배향성, 표면의 기공, 결정성을 제어 하기 위하여 3단계 공정에서 1st stage 이후 Se 분압을 증가시키는 방법($3{\rightarrow}1$, $2{\rightarrow}1$)과 1st stage 이 후 Se 분압을 감소시키는 방법($1{\rightarrow}3$, $1{\rightarrow}2$)을 적용하여 비교하였다. 그 결과 3단계에서 1st stage 이후 Se 분압을 증가시킴으로써 (220)/(204)의 우선 배향성을 촉진시키며, 결정성을 개선하였고, 1st stage 이후 Se 분압을 감소시킴으로써 CIGS 박막 표면의 기공을 제거하고, 결정성을 향상시켰다. 이렇게 1st stage이 후 Se 분압을 증가시킴으로써 (220)/(204)의 우선 배향성의 촉진과 결정성 개선은 단락 전류(Jsc)를 증가시켰으며, 1st stage 이후 Se 분압을 감소시킴으로써 CIGS 박막 표면의 기공을 제거와 결정성 개선은 개방전압(Voc)의 증가효과를 가져왔다.

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Reduction of Radiated Emission of an Infrared Camera Using a Spread Spectrum Clock Generator (확산 스펙트럼 생성기를 이용한 적외선 카메라의 방사노이즈 저감에 관한 연구)

  • Choi, Bongjun;Lee, Yongchun;Yoon, Juhyun;Kim, Eunjun
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.27 no.12
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    • pp.1097-1104
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    • 2016
  • The infrared camera is difficult to satisfy the RE-102 specification of Mil-Std-461. Especially, in the case of UAV electronics, shielded cable is not used, so it is difficult to meet the electromagnetic compatibility standard. In the RE-102 test of the IR camera for UAV, radiated noise exceeding 30 dBuV/m was observed in the range of 50 MHz to 200 MHz. As a result of pcb em scan, peak noise which caused by the harmonic frequency of the digital control signal clock was observed. Radiated noise was reduced by up to 22.9 dBuV/m by applying the spread spectrum clock generator(SSCG) with 3 % down spreading method to the camera control clock.

Improved Harmonic-CELP Speech Coder with Dual Bit-Rates(2.4/4.0 kbps) (이중 전송률(2.4/4.0 kbps)을 갖는 개선된 하모닉-CELP 음성부호화기)

  • 김경민;윤성완;최용수;박영철;윤대희;강태익
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.28 no.3C
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    • pp.239-247
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    • 2003
  • This paper presents a dual-rate (2.4/4.0 kbps) Improved Harmonic-CELP(IHC) speech coder based on the EHC(Efficient Harmonic-CELP) which was presented by the authors. The proposed IHC employs the harmonic coding for voiced and the CELP for unvoiced segments. In the IHC, an initial voiced/unvoiced estimate is obtained by the pitch gain and energy. Then, the final V/UV mode is decided by using the frame energy contour. A new harmonic estimation combining peak picking and delta adjustment provides a more reliable harmonic estimation than that in the EHC. In addition, a noise mixing scheme in conjunction with an improved band voicing measurement provides the naturalness of the synthesized speech. To demonstrate the performance of the proposed IHC coder, the coder has been implemented and compared with the 2.0/4.0 kbps HVXC(Harmonic excitation Vector Coding) standardized by MPEG-4. Results of subjective evaluation showed that the proposed IHC coder and produce better speech quality than the HVXC, with only 40% complexity of the HVXC.

Design of an 8051 Microcontroller With Application-Specific Instructions and I/O Ports for Data Transmission (데이터 전송을 위한 전용 명령어 및 I/O 포트를 탑재한 8051 마이크로콘트롤러의 설계)

  • Kim, Jihye;Lee, Seongsoo
    • Journal of IKEEE
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    • v.19 no.4
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    • pp.625-631
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    • 2015
  • In this paper, an 8051 microcontroller with application-specific instructions and I/O ports for data transmission is designed. The designed microcontoller includes two UART ports and one SMBus port to control external devices and to transmit data with them. Application-specific instruction is developed and added to the instruction set to exploit these I/O ports. So the designed microcontroller can perform multi-device control and multi-byte transmission. Also, it can reduce the code size of the application program. Especially, the designed microcontroller does not stall and can execute other programs during data transmission, which significantly increases its efficiency. Synthesized in 0.18 um technology, the area overhead due to application-specific instructions was negligible. Operations of all instructions and I/O ports were verified to run correctly on a FPGA board.

Single crystal growth of synthetic emerald by flux method of Vandadium - Molybdenum - Lithium oxide system (산화 바나디움, 몰리브데늄, 리티움계 융제법에 의한 합성 Emerald 단결정 육성)

  • 최의석;김무경;이종민;안영필;서청교;안찬준
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.6 no.1
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    • pp.44-55
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    • 1996
  • Emerald (3BeO{\cdot}Al$_{2}$O_{3}{\cdot}6SiO_2 : Cr^{3+}$) single crystals were grown by flux method of $Li_2O-MoO_3 - V_2O_5$ system. The composition of starting materials were 1, 3, 5 mole ratio of $MoO_3 - V_2O_5/$Li_2O$, 20 - 15% of emerald content to flux composition and 1% of $Cr_2O_3$ colordopant to emerald composition. After mixing those were melted at $1100^{\circ}C$ in Pt crucible of electric furnace. Single crystal growth was cooled down slowly rate of $3^{\circ}C$/hr from $1100^{\circ}C$ to $650^{\circ}C$, for the cooling period it was controlled and prevented the nucleation of microcrystallite from variation of each thermal fluctuation range. Specially it has been obtained plenty of large emerald single crystal when thermal fluctuation was treated for cooling period at $1050 ~ 950^{\circ}C$, in 3 mole ratio of $V_2O_5 - MoO_3/Li_2O$ flux. Emerald single crystal growing effect and $Cr_{+3}$ ion of substitutional solid solution effect for $Al_{+3}$ ion was good than mole ratio of 5. Emerald single crystals were c (0001) hexagonal rystal face of preferencial direction and m (1010) post side. Emerald was hexagonal columnar greenish transparent and 2.65 ~ 2.66 of specific gravity.

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A Study on Implementation of a VC-Merge Capable High-Speed Switch on MPLS over ATM (ATM기반 MPLS망에서 VC-Merge 가능한 고속 스위치 구현에 관한 연구)

  • Kim, Young-Chul;Lee, Tae-Won;Lee, Dong-Won
    • The KIPS Transactions:PartC
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    • v.9C no.1
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    • pp.65-72
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    • 2002
  • In this paper, we implement a high-speed swatch tilth the function for label integration to enhance the expansion of networks using the label space of routers efficiently on MPLS over ATM networks. We propose an appropriate hardware structure to support the VC-merge function and differentiated services simultaneously. In this paper, we use the adaptive congestion control method such as EPD algorithm in carte that there is a possibility of network congestion in output buffers of each core LSR. In addition, we justify the validity of the proposed VC-merge method through simulation and comparison to conventional Non VC-merge methods. The proposed VC-merge capable switch is modeled in VHDL. synthesized, and fabricated using the SAMSUNG 0.5um SOG process.

A Study on the Dust Control Effect of PM10 Dust Inhibitor by Polysaccharides and its Effect on Water Quality and Soil Environment (Polysaccharides를 이용한 PM10 먼지억제제의 먼지제어 효과와 수질 및 토양 환경에 미치는 영향에 대한 연구)

  • Lee, Han Seob;Choi, Sung Boo;Hwang, Su Jin;Hwang, Hyun Seok
    • Journal of Korean Society of Environmental Engineers
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    • v.39 no.2
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    • pp.59-65
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    • 2017
  • In this study, A dust inhibitor for $PM_{10}$ was prepared by using molecular structure, molecular weight, viscosity, hydrophilicity, swelling and wetting / moisturizing properties of natural polysaccharide which is widely used as food and cosmetic materials. Various dust control effects were confirmed and superior results were obtained than simple water spraying and synthetic PVA as a control. In addition, the comparison of water evaporation, pot test of cabbage seed germination, effects on fish and aquatic plants, and effects on herb plant growth were studied and the safety of soil and water quality was studied. The availability of the dust inhibitor was confirmed.

Embedding Built-in Tests in Hot Spots of an Object-Oriented Framework (객체지향 프레임웍의 Hot Spot에 Built-in Tests를 내장하는 방법)

  • Shin, Dong-Ik;Jeon, Tae-Woong;Lee, Syung-Young
    • Journal of KIISE:Software and Applications
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    • v.29 no.1_2
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    • pp.65-79
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    • 2002
  • Object-oriented frameworks need to be systematically tested because they are reused in developing many applications software. They also need additional testing whenever they are extended for reuse. Frameworks, however, have properties that make it difficult to control and observe the testing of the parts that were modified and extended. In this paper, we describe the method of embedding test components as BIT(Built-In Test) into the framework's hot spots in order to efficiently detect the faults through testing that occurred while implementing application programs by modifying and extending the framework. The test components embedded into a framework make it easy to control and observe testing the framework, and thereby improve the testability of frameworks. Test components designed by the method proposed in this paper can be dynamically attached and detached to/from hot spots of a framework without changes or intervention to the framework code.

Design of $TiO_2$ electrode for DSSC

  • Lee, Wan-In
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.22-22
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    • 2010
  • 최근 염료감응형 태양전지(DSSC)는 광변환효율 측면에서 향상 가능성이 높으며, 전기화학적 반응을 바탕으로 하므로 생산단가가 낮아 차세대 태양전지로 관심을 모우고 있다. 염료감응형 태양전지에 있어서 주요 구성성분 중의 하나는 다공성 산화물 광전극 재료이다. 다양한 반도체 물질과 비교할 때 $TiO_2$는 전도대의 위치와 전자이동성 면에서 비교적 적합하며, 유기물과의 흡착성 및 안정성 측면에서 대단히 우수하다. 염료감응형 태양전지의 $TiO_2$ 광전극이 갖추어야 할 요건은 표면적이 넓어서 염료 흡착량이 많아야 하며, 전자전달 및 전해질 이동을 위한 효율적 구조이어야 한다. $TiO_2$ 광전극 제작을 위한 재료로서는 나노입자가 널리 이용되며, 입자의 크기는 20 nm 부근이 적합한 것으로 알려져 있다. 본 발표에서는 나노입자 외에 나노막대, 나노섬유, 나노튜브, inverse-opal 구조 등과 같이 지금까지 연구되고 있는 $TiO_2$ 나노구조 관련연구를 소개 한다. 한편으로 효율적 전극구조를 제작하려면 $TiO_2$ 나노구조 제어 외에도, 투명전극과 $TiO_2$ 전극과의 계면층(interfacial layer) 제어, 빛의 효율적 이용을 위한 산란층(scattering layer) 및 $TiO_2$ 전극에서 전해질로의 전자손실 억제를 위한 blocking layer 도입 등이 필요하다. 이에 대한 기본개념을 설명하고 다른 연구자의 연구결과를 소개한다. 본 연구실의 연구 결과인, 메조 포러스 구조, 다공성 속빈구 구조와 구형구조체를 합성하고 이를 염료감응형 태양전지에 응용한 내용을 소개한다. 다공성 속빈구의 경우, 산란층으로 대단히 우수한 결과를 나타내었고, 다공성 구형구조체는 광전극 주재료로 적합한 특성을 나타내었다. 즉, 다공성 구형구조체를 적용한 광전극은 표면적이 대단히 넓고 또한 효율적 동공구조가 형성되어 전해질 이동에도 매우 효율적이다.

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Anisotropic Acorn-like Particle Fabrication Via a Dynamic Phase Separation Method (동적 상분리법을 이용한 이방성 도토리형상 입자 제조)

  • Park, Chul Ho;Baek, Il-hyun
    • Membrane Journal
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    • v.29 no.1
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    • pp.61-65
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    • 2019
  • Anisotropic particles have been issued in various fields due to their unique physical properties. Herein, a novel dynamic phase separation method (DPS) is introduced to fabricate anisotropic acorn-like nanoparticles. DPS consists of two dynamic conditions; solvent evaporation and nonsolvent induced precipitation. The bottom layer is controlled by feeding the water as a non-solvent diluent, and the phase separation of the upper layer relies on the diffusion and evaporation of a volatile good solvent. At this condition, the acorn-like particles were fabricated. Under a closed box filled with water (spontaneous phase separation), monodisperse polystyrene (PS) particles were synthesized. At the coexistence between DPS and spontaneous phase separation, the sizes of cap and particle were changed. Also, the volume of PS solutions influences on the particle shape. Since the unique structures could be utilized into various applications, if advanced techniques such as membrane-based controlled water feeding is developed, monodisperse acorn-like particles could be tuned.