• Title/Summary/Keyword: 합성 작용

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Cholecalciferol Metabolism Metabolic Conversion and Mode of Action (Cholecalciferol 대사연구(代謝硏究)에 관(關)한 일정리(一整理))

  • Yoon, Jin-Sook
    • Journal of Nutrition and Health
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    • v.12 no.1
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    • pp.9-16
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    • 1979
  • Cholecalciferol은 피하에서 자외선과 체온의 작용을 받아 7-dehydrocholesterol로부터 Previtamin D를 거쳐 합성이 되며 이어서 간에 빨리 축적, 25 hydroxylation을 거치게 되고 신장에서 가장 활성을 띤 형태인 $1.25-(OH)_{2}CC$로 변하게 된다. 한편 신장에서는 체내의 Ca, P이 정상으로 존재하게 되면 1-hydroxylation이 억제되는 대신 24-hydroxylation이 일어나 또 다른 active form인 $24,\;25-(OH)_{2}CC$가 되는데 24-hydroxylation의 역활이 무엇인가에 대해서는 아직 구체적으로 밝혀지지 않았다. $24,\;25-(OH)_{2}CC$$1.25-(OH)_{2}CC$는 모두 공통적으로 또 다른 active form인 $1.24,\;25-(OH)_{3}CC$를 형성할 수도 있다. 그중 $1.25-(OH)_{2}CC$는 Steroid H.으로 일컬어지기도 하는 Vit. D metabolite중에서 가장 활성을 가진 형태이며 표적기관으로 크게 소장, 뼈, 신장을 들 수 있다. 소장에서의 역활은 무엇보다도 Ca흡수에 관련되는 것으로 소장에서의 Ca흡수와 Ca BP합성에 관여한다. 골격 형성과 뼈의 mineralization에 관여하는 Vit. D metabolite를의 효과에 관해서는 아직까지 일관성있는 보고가 없다. 한편 $1.25-(OH)_{2}CC$는 side chain oxidation을 거쳐 $CO_{2}$와 미지의 물질을 생성하는데 이 mechanism이 어떤 의미를 갖는지는 분명치 않다. 그밖에 또 다른 표적기관으로서 최근 타액선의 존재가 알려졌으며 Vit. D가 배설되는 경로에 대해서는 새로운 바가 없다. Vit. D가 담즙을 통해서 우선적으로 배설되고 소량이 뇨를 통해 배설되는데 metabolite들의 배설경로는 더욱 규명되어야 할 과제이다.

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다차원 구조의 그래핀-산화구리 나노선 복합 필러의 열전도도 특성

  • Ha, In-Ho;Lee, Han-Seong;An, Yu-Jin;Park, Ji-Seon;Seo, Mun-Seok;Jo, Jin-U;Lee, Cheol-Seung
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.433.2-433.2
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    • 2014
  • 그래핀(graphene)은 탄소나노튜브(CNTs)에 비해 가격 경쟁력이 있고 우수한 광투과성과 전기 및 열 전도성을 갖고 있어 반도체 소재, 방열 소재, 접점 소재 등에 적용 가능성이 높은 재료로 주목받고 있다. 특히 모바일 디바이스의 소형화, 고집적화 등의 이슈로 인해 그래핀 소재의 방열 소재 적용을 위해 다양한 연구가 진행되고 있다. 한편 산화 구리 나노선(CuO Nanowire)은 전기 및 열전도도가 우수하고 1차원 나노 구조는 부피대비 큰 표면적, 종횡비가 커서 뛰어난 열전도 구조로서 방열 소재로 응용되기 좋은 조건을 갖고 있다. 본 연구에서는 2차원 구조의 그래핀 나노플레이트(Graphene Nanoplatelet)와 1차원 구조의 CuO NW를 하이브리드화를 통해 열전도도 향상를 개선시키고자 하였다. 소재 합성은 GNP에 Cu 무전해 도금을 진행한 후 열산화 방식을 적용하여 CuO NW를 직접 성장시키는 방식으로 진행하였다. 합성된 GNP-CuONWs 다차원 나노구조체의 열전도도 측정은 에폭시에 분산시켜 레이져 플레쉬법을 이용하였다. 미세 구조 관찰 결과, CuO NW 성장 거동은 열처리 온도 및 시간 그리고 O2 가스의 순환 환경이 주요인자로 작용하는 것을 확인하였다. 열전도도 향상은 다차원 구조의 특성으로 인해 면접촉과 선접촉이 동시에 이루어졌기 때문인 것으로 분석되었으며, 이러한 CuO NWs morphology와 열전도도 향상과의 상관 관계에 대해 논의할 것이다.

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Bed Load Transport by Waves and Current (파와 해류에 의한 소류사 이동)

  • 유동훈
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.7 no.3
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    • pp.257-264
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    • 1995
  • Various factors are investigated on the bed load transport driven by waves and current, and proper forms of bed load transport formulas mainly used in river hydraulics are chosen for the estimation of combined flow bed load transport after considering the additional factors. The BYO Model is employed for the computation of maximum bed shear stress and mean bed shear stress of the combined flow. The friction factor of uni-directional flow is estimated by using modified Keulegan equation, and equivalent roughness height is determined by obtaining correct answer for the bed shear stress of uni-directional flow. Empirical constant in each bed load formula is determined by applying it to Bijker's laboratory data of bed load transport by waves and current and the formulas obtained are discussed on their final forms with the values of empirical constants.

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Depth Extraction of Convergent-Looking Stereo Images Based on the Human Visual System (인간시각체계에 기초한 교차시각 스테레오 영상의 깊이 추출)

  • 이적식
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.27 no.4A
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    • pp.371-382
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    • 2002
  • A camera model with optical axes parallel has been widely used for stereo vision applications. A pair of input ages are obtained from a convergent-looking stereo camera model based on the human visual system in this per, and each image is divided into quadrant regions with respect to the fixation point. The reasoning of quadrant partitions is based on the human visual system and is proven by a geometrical method. Image patches : constructed from the right and left stereo images. A modified cepstrum filter is applied to the patches and disparity vectors are determined by peak detection algorithm. The three-dimensional information for synthetic ages is obtained from the measured disparity and the convergent stereo camera model. It is shown that the experimental results of the proposed method for various stereo images are accurate around the fixation point like the human visual system.

The Synthesis of 2-Furyltriisopropoxytitanium and its Reactivity to Carbonyl Compounds (2-Furytriisopropoxytitanium의 합성 및 카르보닐 화합물에 대한 반응성)

  • Koo, Doo-Hyo;Kyung, Suk-Hun
    • Applied Biological Chemistry
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    • v.39 no.4
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    • pp.309-314
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    • 1996
  • 2-Furyltriisopropoxytitanium was synthesized in situ through transmetallation of 2-furyllithium with chlorotitaniumtriisopropoxide. The compound could be isolated at room temperature and preserved at $-10^{\circ}C$ for several weeks. The reactivity 2-furyltriisopropoxytitanium to carbonyl compounds proved to be high. A complete aldehyde selectivity was observed in competition reactions of 2-furyltriisopropoxytitanium with a 1:1 mixture of aldehyde and ketone. In competition reactions of 2-furyltriisopropoxytitanium with a 1 : 1 mixture of ketone and ketone, the degree of ketone / ketone discrimination was substantial. In the reaction of 2-furyltriisopropoxytitanium to ketone-ester function, the reagent was solely reacted with the ketone function.

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Preparation of $TiO_2$ Particles using Binary Ionic Liquids for Photocatalysis (이성분계 이온성액체를 이용한 광촉매용 이산화 티타늄 입자 제조)

  • Lee, Seulbi;Yoo, Kye Sang
    • Applied Chemistry for Engineering
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    • v.23 no.4
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    • pp.405-408
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    • 2012
  • $TiO_2$ particles with various shapes were synthesized by using a modified sol-gel method with binary ionic liquids. The structural properties of the particles were significantly affected by the composition of ionic liquids. This is mainly attributed to the interaction between the organic solvent and ionic liquid at the interface leading to the formation of particle structure. The photocatalytic activity of the prepared samples was also examined for the degradation of 4-chlorophenol. Among the particles, $TiO_2$ prepared with 1-octyl-3-methylimidazolium tetrafluoroborate and 1-octyl-3-methylimidazolium tetrafluoroborate showed the best photocatalytic performance.

Polymorphism of Calcium Carbonate Crystal by Silk Digested Amino Acid (실크 분해 아미노산에 의한 탄산칼슘 결정의 polymorphism)

  • Kim, Jin-Ho;Kim, Jong Min;Kim, Woo Sik;Kim, In Ho
    • Korean Chemical Engineering Research
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    • v.46 no.6
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    • pp.1107-1112
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    • 2008
  • Crystallization of calcium carbonate was performed by using aqueous calcium chloride and sodium carbonate for operational simplicity. Reaction time, solute concentrations, pH, and organic additive were varied to get calcium carbonate crystals. Silk fibroin was used as the additive to understand the change of morphology of calcium carbonate crystal. The crystals were analyzed by FE-SEM, XRD, and FT-IR. Reaction time, and pH mainly affected the morphology of crystals. Besides, it was found that silk fibroin inhibited the formation of vaterite and promoted the calcite forms.

The Smartware using Concept of Ubiquitous (유비쿼터스 개념을 도입한 스마트웨어)

  • Lee, Jeong-Ick
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.10 no.5
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    • pp.923-928
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    • 2009
  • The advance of scientific technology is enhanced the effect of reaction. The trend of customer for high function product is enlarged. Thus, the composition of each industry, technology and product is actually happened. Therefore, the fusion of different fields in industrial design is widely accomplished. The example of this fusion effect is that 'ubiquitous or wearable computer' which is combined the function of cloth and computing, which is including any type, any purpose, any telecommunication and any multimedia of cloth inside. The ubiquitous or wearable computer will be a final thing of post pc or next step to pc and internet. This paper is studied for the research of smartware by assistance energy. In this paper, the development of multipurpose smartware(wearable computer) powered by solar energy is introduced.

The Inhibitory Effect of Dopamine on Myoblast Fusion in vitro (Dopamine의 배양근원세포 융합억제 작용)

  • Kang, Man-Sik;Song, Woo-Keun;Song, Yung-Kook
    • The Korean Journal of Zoology
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    • v.29 no.4
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    • pp.235-244
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    • 1986
  • In order to elucidate the effect of neurotransmitter on the differention of myoblasts in vitro, dopamine was administered to the myoblasts at varying stages of myogenesis, and the fusion index, the rate of creatine kinase (CK) synthesis, and the sensitivity to dopamine were determined. When dopamine $(3 \\times 10^{-5} M)$ was administered at 34 hr after myoblast seeding, a significant decrease in the fusion index as well as CK synthesis was observed, indicating a good correlation exists between these two parameters. In other experiment, dopamine was administered at varying stages of myogenesis and the inhibitory effect of dopamine as scored by fusion index at 96 hr was found to be cyclic in nature. This finding raised a possibility that arrangement of dopamine receptors occurs according to the cell cycle stages in myogenesis.

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Studies on Slip and Mechanical Properties of Thermoplastic Polyurethane Elastomer with Carboxylic acid and Nano zinc oxide (Carboxylic acid와 nano zinc oxide를 도입한 열가소성 폴리우레탄 탄성체의 슬립특성 및 기계적 물성에 관한 연구)

  • Shin, Hyun Deung;Kim, Dong Ho;Kim, Gu Ni
    • Elastomers and Composites
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    • v.49 no.3
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    • pp.191-198
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    • 2014
  • We synthesized thermoplastic polyurethane elastomer(TPU) with acid group and nano zinc oxide, and characterized their mechanical properties, thermal properties, contact angle and grip property. The effects of the zinc oxide content and size on the physical property of TPU were investigated. When the nano zinc oxide was introduced in TPU with acid group, it had excellent mechanical properties and grip by formation of hydrogen and ionic bonding. The wet slip of TPU with zinc oxide was increased continuously as ionization rate increased due to increase of hydrophilicity and ionic interaction, and mechanical properties were increased with increasing ionization rate up to 50%.