• Title/Summary/Keyword: 합성 작용

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An Experimental Study on the Bending Capacities of Steel-Concrete Column under the Axial Load (축력을 받는 SC 기둥의 휨 성능에 관한 실험 연구)

  • Lee, Hwan Soo;Oh, Myoung Ho;Kim, Sang Dae
    • Journal of Korean Society of Steel Construction
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    • v.15 no.1
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    • pp.87-96
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    • 2003
  • The Ssteel-Cconcrete (SC) Ccomposite Ccolumn is a new Ccomposite Ccolunin system, where hoops are welded between flanges of H-shapesd steel and concrete is filled in spaces between flanges are filled with con crete. Tests of SC composite columns were performed previously to determine their compression, bending and shear strength, and it showed good structural behavior. But sSince a column is usually subjected to an axial compression force, and bending it ihas needed to be bent forevaluate its structural behavior to be evaluated when its axial load and bending isaresimultaneously applied to the SC composite column. In this paper, tests were conducted to investigate the bending strength of SC composite columns subjected to axial compression force and bending moment. The parameters of the tests were concrete, a stud bolt, a hoop and a magnitude of axial compression. The test results showed that the maximum bending strength and ductility of an SC composite column were increased by 33-42% and 33-63%, respectively, comparinged to those of a bare steel column. Also, the results obtained bywith the Korean Limit State Design Code (LSD) presents a considerably safe side value compared to those of the Eurocode-4 and the Japan Code. However, wWhen the axial compression force is was increased, however, there awere considerable differences between the maximum strength obtained by the test and the LSD analysis. For this reason, it is recommended tothe use of the Eurocode-4 is recommended when calculates the strength of an SC composite column is being calculated, since the Eurocode-4 gives us a better estimation.

The Inhibitory Effects of Alnus Japonica Steud. Extract on Melanogenesis (적양 추출물의 멜라닌 합성 저해효과)

  • Lee, Jun Young;Im, Kyung Ran;Jung, Taek Kyu;Yoon, Kyung-Sup
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.39 no.2
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    • pp.159-166
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    • 2013
  • In order to develop new skin whitening agents, we prepared the EtOAc layer (AJE) after enzyme treatment of 75% EtOH extract of the Alnus Japonica Steud. We measured their tyrosinase inhibitory activity in vitro and melanin synthesis inhibitory activity in B16-F1 melanoma cells. They did not show inhibitory activity against mushroom tyrosinase but showed melanin synthesis inhibitory activity in a dose-dependent manner. In a melanin synthesis inhibition assay, AJE suppressed melanin production up to 52% at a concentration of $40{\mu}g/mL$. To elucidate the mechanism of the inhibitory effects of AJE on melanogenesis, we measured expression of melanogenesis-related proteins by the western blot assay. As a result, AJE suppressed the expression of tyrosinase related protein 1 (TRP-1) and microphthalmia associated transcription factor (MITF). Moreover, AJE increased the expression of phosphorylated extracellular signal-regulated kinase (p-ERK). These results conclude that ERK activation by AJE reduces melanin synthesis via MITF downregulation and is subsequent to the inhibition of TRP-1 expression. Therefore, we suggest that AJE could be used as active ingredients for skin whitening.

Synthesis of Several Osmium Redox Complexes and Their Electrochemical Characteristics in Biosensor (오스뮴 착물들의 합성 및 전기화학적인 특성에 관한 연구)

  • Kim, Hyug-Han;Choi, Young-Bong;Tae, Gun-Sik
    • Journal of the Korean Electrochemical Society
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    • v.11 no.3
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    • pp.176-183
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    • 2008
  • Redox complexes to transport electrodes from bioreactors to electrodes are very important part in electrochemical biosensor industry. A novel osmium redox complexes were synthesized by the coordinating pyridine group having different functional group at 4-position with osmium metal. Newly synthesized osmium complexes are described as ${[Os(dme-bpy)}_2{(ap-im)Cl]}^{+/2+}$, ${[Os(dme-bpy)}_2{(ap-im)Cl]}^{+/2+}$, ${[Os(dmo-bpy)}_2{(ap-im)Cl]}^{+/2+}$, ${[Os(dcl-bpy)}_2{(ap-im)Cl]}^{+/2+}$. We have been studied the electrochemical characteristics of these osmium complex with electrochemical techniques such as cyclic voltammetry and chronoamperommetry. Osmium redox complexes were immobilized on the screen printed carbon electrode(SPE) with deposited gold nanoparticles. The electrical signal converts the osmium redox films into an electrocatalyst for glucose oxidation. Each catalytic currents were related with the potentials of osmium complexes.

Design Thermal Loads In Composite Box Girder Bridges (합성형교량의 설계온도하중)

  • Chang, Sung Pil;Im, Chang Kyun
    • Journal of Korean Society of Steel Construction
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    • v.10 no.3 s.36
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    • pp.537-551
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    • 1998
  • The intention of this paper is to provide realistic values of design thermal loads applicable to composite box girder bridges on the basis of the statistical analysis of long-term measured temperature data. For this purpose, temperatures were recorded at a newly constructed composite box girder bridge during about 20 months. Before analyzing the extreme values, major thermal loading parameters that characterize the temperature profile are defined, and a seasonal behavior of those is examined in detail. The limit distributions of the thermal loading parameters are then determined by the tail-equivalence method, and the thermal loading parameters corresponding to selected return period are calculated. Finally, the results are compared to the specifications suggested in a current design code for thermal loads, and it is concluded that the current design code is unsuitable for representing the self-equilibrated thermal stresses in composite bridges, and the horizontal temperature difference which is not suggested in current design code should be taken Into account in particular cases.

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Characteristic Polynomial of 90 UCA and Synthesis of CA using Transition Rule Blocks (90 UCA의 특성다항식과 전이규칙 블록을 이용한 CA 합성법)

  • Choi, Un-Sook;Cho, Sung-Jin
    • The Journal of the Korea institute of electronic communication sciences
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    • v.13 no.3
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    • pp.593-600
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    • 2018
  • Cellular automata (CA) have been applied to effective cryptographic system design. CA is superior in randomness to LFSR due to the fact that its state is updated simultaneously by local interaction. To apply these CAs to the cryptosystem, a study has been performed how to synthesize CA corresponding to given polynomials. In this paper, we analyze the recurrence relations of the characteristic polynomial of the 90 UCA and the characteristic polynomial of the 90/150 CA whose transition rule is <$00{\cdots}001$>. And we synthesize the 90/150 CA corresponding to the trinomials $x^{2^n}+x+1(n{\geq}2)$ satisfying f(x)=f(x+1) using the 90 UCA transition rule blocks and the special transition rule block. We also analyze the properties of the irreducible factors of trinomials $x^{2^n}+x+1$ and propose a 90/150 CA synthesis algorithm corresponding to $x^{2^n}+x^{2^m}+1(n{\geq}2,n-m{\geq}2)$.

Review: Magnetite Synthesis using NanoFermentation (Review: NanoFermentation을 이용한 자철석 합성연구)

  • Moon, Ji-Won;Roh, Yul;Phelps, Tommy J.
    • Economic and Environmental Geology
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    • v.45 no.2
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    • pp.195-204
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    • 2012
  • Biomineralization has been explored for geochemical cycles and microbial tolerance mechanisms to metal toxicity. Here, we are introducing NanoFermentation which enables economic, environmentally friendly, requiring low input energy, and scalable manufacturing of nano-dimensioned magnetite. We are also focusing on controlling factors of crystallite size which can determine superparamagnetism and ferrimagnetism. Controlling factors are such as microbial species, temperature, incubation time, medium composition, substituted elements and their concentration, precursor type, reaction volume, precursor concentration density and their combinations. Crystallite size distribution of biomagnetite depends on the balance between nuclei generation and crystal growth. Biomineralization will elucidate elemental cycles on earth crust and microbial ecology as well as it will be applied to material sciences and devices via massive production of nanomaterials.

Synthesis of Fréchet-type Dendrimers with Tripodal Core via Staudinger/Aza-Wittig Reactions (Staudinger/Aza-Wittig 반응에 의한 삼발이 핵을 갖는 Fréchet-type 덴드리머의 합성)

  • Han, Seung Choul;Lee, Jae Wook;Jin, Sung-Ho
    • Polymer(Korea)
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    • v.38 no.3
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    • pp.386-390
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    • 2014
  • Efficient stitching methods for the synthesis of tripodal Fr$\acute{e}$chet-type dendrimers containing secondary amine as a connector were elaborated. The synthetic strategy involved Staudinger/aza-Wittig reactions (new click reaction) between tripodal tris(azides) and aldehyde-dendrons in toluene in the presence of triphenylphosphine and followed by the reduction of imine intermediates. The tripodal core (1,3,5-tris-(3-azido-propoxy)-benzene) was chosen to serve as the azide functionalities for dendrimer growth. 1,3,5-Tris-(3-azido-propoxy)-benzene was stitched with the aldehyde-functionalized Fr$\acute{e}$chet-type dendrons via Staudinger/aza-Wittig reactions leading to the formation of the corresponding Fr$\acute{e}$chet-type dendrimers in high yields.

Biomineralization and Biomimetics from the Point of Mineral Processing (광물 합성 공정의 관점에서 본 생광물화과정 및 생체모방공학)

  • Lee, Seung-Woo;Jang, Young-Nam;Park, Seung-Bin
    • The Korean Journal of Malacology
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    • v.26 no.1
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    • pp.1-18
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    • 2010
  • Biological organisms produce organic-inorganic nanocomposite composites that are hierarchically organized in composition and microstructure, containing both inorganic and organic components in complicated mixtures. The process related to the generation and regeneration of organic-inorganic complex in nature is called biomineralization process. Understanding how the process operates in a biological environment is a valuable guide to the synthesis of novel advanced material and developing important industrial processes. Like the mechanism of organisms, mollusks were also synthesized from interaction between organic matrices and minerals and their morphology was designed through biomineralization. In this study, shell formation has been studied as a bio-model and the application of biomimetics based on biomineralization is focused.

Construction of Recombinant DNA for Purification of the Gag-Pro Transframe Protein of Human T-cell Leukemia Virus Type I (HTLV-I) (Human T-cell Leukemia Virus Type I (HTLV-I) 의 Gag-Pro Transframe 단백질 정제를 위한 재조합 DNA 의 제작)

  • 남석현
    • Korean Journal of Microbiology
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    • v.30 no.6
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    • pp.466-471
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    • 1992
  • To determine the site at which -1 ribosomal frameshifting occurs within the gag-pro overlap of HTL V-I. DNA fragment corresponding to a portion of the gene overlap was cloned into a SP6 vector. The resultant plasmid harbors the hybrid gene consisting of a synthetic gene encoding 5 amino acids derived from chick prelysozyme including the initiator methionine plus 141 nucleotides of gag-pro overlapping region followed by Staphylococcus aurcus protein A gene fragment. In vitro transcription by SP6 RNA polymerase with this DNA template made an abundant amount of single species mRNA. Cell-free translation programmed with the RNA transcribed in vitro yielded a polypeptide of 21 kDal in size. which could be purified into homogeneity by IgG-Sepharose affinity chromatography. In vitro system described in this study must be useful for rapid purification and sequencing of the Gag-Pro transframe protein. allowing to determine the exact frameshift site on mRNA and to identify the tRNA involved in frameshifting event for the expression of pro gene.

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Synthesis of Oxyethlyene Modified Silixoane Surfactants for Polyurethane Foam and the Characteristics of Fine Cell Formation (폴리우레탄 폼용 옥시에틸렌 변성 폴리실록산계 계면활성제의 합성 및 미세 셀 발포 특성)

  • Kim, Daeheum;Park, Seungwoo;Yeo, Seungbyung
    • Applied Chemistry for Engineering
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    • v.17 no.3
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    • pp.260-266
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    • 2006
  • For the synthesis of polyurethane memory foam stabilizer with fine cells, hydrosilylation reaction with various polyalkyleneoxides and hydrogen functional group of polymethylhydrogensiloxane (D = 75, D' = 15) was conducted. Polyalkyleneoxides (PAO) used in this research were ethylene oxides or ethylene-co-propylene oxides with terminal groups of hydroxides or methyl groups. To analyze the molecular structures and molecular weights as well as the reaction yields (98%), NMR and GPC analysis were executed. Synthesized siloxane surfactants modified with polyalkylene (EO = 12 units) were applied to producing flexible polyurethane fine memory foams from 0.6 pphp to 2.0 pphp. By controlling the amount of the surfactant, physical characteristics, the polyurethane memory foam with cell size (minimum $0.868{\mu}m$), air flows (-78 KPa), and recovery times (8 sec) were achieved.