• Title/Summary/Keyword: 합성율

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Development of IR Reflective Cool Pigment and Paint (차열도료용 Cool Pigment 및 Paint 개발)

  • Kwon, Myon-Joo;Do, Young-Woong;Ha, Jin-Wook
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.13 no.8
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    • pp.3800-3805
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    • 2012
  • Infrared(IR) reflective black cool pigment and paint which is used for interior/exterior materials(IR reflectance >30%) to prevent heat island effect and to increase energy efficiency were studied. Cool pigment was synthesized using mixture of $Fe_2O_3$ and $Cr_2O_3$ with calcination from 900 to $1,200^{\circ}C$. Cool paint was prepared by formulation of cool pigment, acrylic resins, and other additives. Results showed that optimum color fixation of pigment obtained by mole ratio of Fe to Cr was 0.9 with calcination temperature at $1,000^{\circ}C$. The cool paint formulated by 20% pigment and 1.5% dispersive additive with $125{\mu}m$ thickness of coated layer showed optimum IR reflectance. Temperature difference on surface between cool paint and ordinary paint(STD) was $36.5^{\circ}C$ and IR reflectance(TSR) was 39.3% at wavelength from 700 to 2,500nm. And color change was not detected during 500hrs weathering test.

A Study on the Application Medium Expansion Foam Extinguisher by a Fire Performance Analysis used Medium Expention Foam Agent (중발포 소화약제 소화성능 분석을 통한 중발포기 적용에 관한 연구)

  • Lee, Jang Won
    • Journal of the Society of Disaster Information
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    • v.15 no.3
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    • pp.402-408
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    • 2019
  • Purpose: The study want to verify application the medium expantion foam extinguisher of expantion foam rate and fire extinguishing Performance test because the medium expansion system can maintain the discharge distance less affected by air currents, and the foam agent can be used efficiently. Method: For the study, the medium-expansion testing apparatus was manufactured and with synthetic surfactant foam agent of (class B) fire extinguishing model, and Fire Performance was analyzed for foam expansion rate and the fire agent consumption was measured and analyzed. Results: We measured the medium-spray testing apparatus and found that the expansion rate was 26.1 times. The test results of a 20-unit fire extinguishing model show that the extinguishing time is faster than the high and low foam expansion. It has been analyzed that it is possible to apply a hand-operated with a hose reel or medium expansion apparatus. Conclusion: Considering that the foaming agent and the extinguishing performance of the medium foam ratio are excellent, It is necessary to introduce the technical standards of medium foam agent for the introduction of hand-operated equipment, such as hose reel or portable medium foam apparatus.

Arrhythmia Classification using GAN-based Over-Sampling Method and Combination Model of CNN-BLSTM (GAN 오버샘플링 기법과 CNN-BLSTM 결합 모델을 이용한 부정맥 분류)

  • Cho, Ik-Sung;Kwon, Hyeog-Soong
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.26 no.10
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    • pp.1490-1499
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    • 2022
  • Arrhythmia is a condition in which the heart has an irregular rhythm or abnormal heart rate, early diagnosis and management is very important because it can cause stroke, cardiac arrest, or even death. In this paper, we propose arrhythmia classification using hybrid combination model of CNN-BLSTM. For this purpose, the QRS features are detected from noise removed signal through pre-processing and a single bit segment was extracted. In this case, the GAN oversampling technique is applied to solve the data imbalance problem. It consisted of CNN layers to extract the patterns of the arrhythmia precisely, used them as the input of the BLSTM. The weights were learned through deep learning and the learning model was evaluated by the validation data. To evaluate the performance of the proposed method, classification accuracy, precision, recall, and F1-score were compared by using the MIT-BIH arrhythmia database. The achieved scores indicate 99.30%, 98.70%, 97.50%, 98.06% in terms of the accuracy, precision, recall, F1 score, respectively.

Synthesis and characterization of the two-fold interpenetrated Tb(III)-based metal-organic framework (이중 상호 침투 구조를 갖는 신규 터븀(III) 기반 금속-유기 골격체의 합성 및 특성연구)

  • Song, Jeong Hwa
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.32 no.6
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    • pp.225-230
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    • 2022
  • A new two-fold interpenetrating two-dimensional (2D) Tb(III) metal-organic framework (MOF), [Tb(p-XBP4)2.5(H2O)2]·W(CN)8 (1), was prepared using a p-XBP4 (N,N'-p-phenylenedimethylenbis(pyridin-4-one)), Cs3[W(CN)8], and Tb(NO3)3·6H2O. The single crystal X-ray diffraction indicated that Tb-MOF exhibits a unique two-fold interpenetrating 2-D framework. It was also characterized through Fourier transform infrared spectroscopy (FTIR), and single and powder X-ray diffraction. To probe the molecular magnetic behavior, the magnetic properties of Tb-MOF were investigated by direct-current (DC) and alternating-current (AC) magnetic susceptibilities measurements and discussed.

A Simulation Study on SCR(Steam Carbon Dioxide Reforming) Process Optimization for Fischer-Tropsch Synthesis (Fischer-Tropsch 합성용 SCR(Steam Carbon Dioxide Reforming) 공정 최적화 연구)

  • Kim, Yong Heon;Koo, Kee Young;Song, In Kyu
    • Korean Chemical Engineering Research
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    • v.47 no.6
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    • pp.700-704
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    • 2009
  • A simulation study on SCR(steam carbon dioxide reforming) in gas-to-liquid(natural gas to Fischer-Tropsch synthetic fuel) process was carried out in order to find optimum reaction conditions for SCR experiment. Optimum operating conditions for SCR process were determined by changing reaction variables such as temperature and $CH_4/steam/CO_2$ feed ratio. Simulation was carried out by Aspen Plus. During the simulation, overall process was assumed to proceed under steady-state conditions. It was also assumed that physical properties of reaction medium were governed by RKS(Redlich-Kwong-Soave) equation. Optimum simulation variables such as temperature and feed ratio were determined by considering $H_2/CO$ ratio for FTS(Fischer-Tropsch synthesis), $CH_4$ conversion, and $CO_2$ conversion. Simulation results showed that optimum reaction temperature and $CH_4/steam/CO_2$ feed ratio in SCR process were $850^{\circ}C$ and 1.0/1.6/0.7, respectively. Under optimum temperature of $850^{\circ}C$, $CH_4$ conversion and $CO_2$ conversion were found to be 99% and 49%, respectively.

Development of Vibration and Impact Noise Damping Wood-Based Composites -Synthesis of the Polymer Showing a Broad Damping Peak (진동·충격음 흡수성 목질계 복합재료의 개발 -폭 넓은 감쇠곡선을 나타내는 고분자의 합성-)

  • Lee, Hyun-Jong
    • Journal of the Korean Wood Science and Technology
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    • v.27 no.2
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    • pp.15-22
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    • 1999
  • Polymeric meterials that are used for noise and vibration damper in wood/polymer/wood sandwich composites, must have a high loss factor(tan ${\delta}$), and at the same time the storage modulus(E) of $5{\times}10^7$ to $10^9$ dyne/$cm^2$ must withstand over a wide temperature and frequency ranges. In this study, the series of epoxy resinlpolyacrylate interpenetrating polymer networks(IPNs) were synthesized by simultaneous polymerization. Their dynamic tensile properties were measured at 110Hz using Rheovibron instrument. Composite damping factor(tan ${\delta}_c$) and dynamic bending modulus($E_c,\;E_^{\prime\prime}c$) of wood/polymer/wood sandwich composites were measured at 110Hz using a Rheovibron in bending mode of vibration. These dynamic tensile studies indicated that cured epoxy resin/polyacrylates IPNs were semicompatible in the sense that both the shifting of T($E^{\prime\prime}_{max}$) or T(tan ${\delta}_{max}$) and the broadening of glass transition temperature range were observed. Especially, the cured Epikote871/P(n-BMA) IPNs of composition 70/30 to 50/50 showed a relatively high tan a and appropriate E' value over a wide temperature range; consequently the tan a e curves of wood/IPNs/wood sandwich composites was broadened over a wide temperature range.

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Removal Efficiency of Pesticide Residues on Apples by Ultrasonic Cleaner (초음파 세척기를 이용한 사과의 잔류농약 제거 효과)

  • Yoon, Chae-Hyuk;Park, Woo-Churl;Kim, Jang-Eok;Kim, Chung-Hyo
    • Korean Journal of Environmental Agriculture
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    • v.16 no.3
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    • pp.255-258
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    • 1997
  • In order to determine the removal efficiency of pesticide residues on apples by ultrasonic cleaner, apples(Fuji var.) were artificially treated by dipping in water solution of fenitrothion EC, chlorpyrifos EC and phenthoate EC. The treated apples were washed by the ultrasonic cleaner with water, 30% ethanol solution or 0.2% detergent solution, respectively. The removal efficiency of fenitrothion, chlorpyrifos and phent-hoate by ultrasonicated washing in water for 0.5min. was 39.2%, 32.0% and 50.4%, respectively, but there was a tendency to decrease the removal efficiency of the pesticide residues as the duration of ultrasonicated washing period is increased. The maximum removal efficiency of the pesticide residues washed in the detergent solution was observed by ultrasonicated washing the samples for 5min. and it was recorded as 33.5% ; fenitrothion, 30.1% ; chlorpyrifos and 48.3% ; phenthoate, respectively. However it's appeared that the longer the ultrasonicated washing period in 30% ethanol solution the more pesticides from the apples were removed and the maximum removal efficiency of the pesticides was recorded as 66.2%(fenitrothion ; washed for 15min.), 41.7%(chlorpyrifos ; washed for 10min.), 74.2%(phenthoate ; washed for 10min.).

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Analysis of Phytosterols and Tocopherols, and Production of Structured Lipids from the Extracted Plant Oils (선택된 식물자원에서 추출조건에 따른 Phytosterol과 Tocopherol의 함량분석 및 추출유로부터 재구성지질의 합성)

  • 조은진;이기택
    • Food Science and Preservation
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    • v.10 no.3
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    • pp.370-375
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    • 2003
  • To obtain the oil sesame, walnut, whole wheat, and rice bran were extracted for 1, 3, or 6 hr by a shanking water bath(35$^{\circ}C$ and 100 rpm), and by soxhlet extractor(80$^{\circ}C$) for 1, 3 or 6 hr, respectively. The highest yield of extracted oil was obtained from the walnut(63.07% weight) and the whole wheat showed the lowest extraction yield of oil(1.13% weight). Major fatty acids from the extracted oils were linoleic, oleic, and palmitic acid. The maximum contents of total phytosterol in sesame, walnut, whole wheat, and rice bran were 0.44, 1.57, 2.25, and 2.03(% weight), respectively. Besides, total tocopherol contents in sesame, walnut, whole wheat, and rice bran were maxima 3.42, 0.16, 2.92, and 0.07(% weight), respectively. From the extracted oils, structured lipids(SL) were synthesized by the interesterification reaction with conjugated linoleic acid(CLA) in a shanking water bath at 55$^{\circ}C$. When the reactions(1:3 substrate molar ratio, extracted oil:CLA) were conducted for 24 hr, maxima 23.75 mol% of CLA incorporation was obtained from walnut oil and, in other cases, 16.28 - 19.15 mol% of CLA was found in the produced SL triacylglycerol molecules.

Hydrothermal Preparation and Sintering of Fine PSZT Powder (미세 PSZT분말의 수열합성 및 소결)

  • Oh, Jung Kang;Seo, Kyung Won
    • Applied Chemistry for Engineering
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    • v.9 no.5
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    • pp.654-660
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    • 1998
  • In preparing PSZT powder by hydrothermal synthesis, effects of reaction temperature, concentration of raw materials and mineralizer on crystallinity, particle size distribution, and dielectric constant were investigated. By varying the concentration of mineralizer and the ratio of Pb to Sr or Zr to Ti, crystalline PSZT powder, having the mean particle size of $0.3{\sim}15{\mu}m$, was prepared by hydrothermal synthesis in the temperature range of $120{\sim}200^{\circ}C$ for a 2h reaction. PSZT ceramics, having dielectric constant of 1000~3000, were prepared at $1150^{\circ}C$ for a 2h sintering reaction of the PSZT powders. Experimental results showed that the weight mean particle size of $0.5{\mu}m$ was obtained when the concentration of KOH in the solution was 10 wt % and the ratio of Pb to Sr was 0.95/0.05, that of Zr to Ti was 0.52/0.48. It also showed that the ceramics of dielectric constant of 2900 were prepared through sintering of this PSZT powder. Size of PSZT particles became smaller with its narrow distribution as the concentration of KOH increased up to 10 wt %. However, it came to be larger at this concentration and above. By adding small amount of Sr that would not affect that crystallinity of particles we can improve dielectric property of sintered materials. Addition of Zr may shift the major crystal phase of synthetic PSZT powder from tetragonal to rhombohedral phase.

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Lithium ion Transport Characteristics of Gel-Type Polymer Electrolytes Containing Lithium p-[Methoxyoligo(ethyleneoxy)] benzenesulfonates (리튬 p-[메톡시 올리고(에틸렌옥시)]벤젠설폰산염으로 제조된 젤형 고분자 전해질의 리튬 이온 운반 특성)

  • 허윤정;강영구;한규승;이창진
    • Polymer(Korea)
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    • v.27 no.4
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    • pp.385-391
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    • 2003
  • Lithium p-[Methoxyoligo(ethyleneoxy)] benzenesulfonates (LiEOnBS) with different repeating unit of ethylene oxide were synthesized and were used for preparing gel-polymer electrolytes. The conductivities and lithium ion transference number were measured as a function of Li-salt concentration and repeating unit of ethylene oxide of the LiEOnBS. The maximum conductivity of the resulting gel-polymer electrolyte was found to be 4.89${\times}$10$\^$-4/ S/cm (LiEO7.3BS, 0.5 M) at 30$^{\circ}C$. The lithium ion transference number (t$\sub$Li$\sub$+//) measurement were performed by means of the combination do polarization and ac impedance methods in gel-polymer electrolytes. Lithium ion transference number was measured to be in the range of 0.75∼0.92 for the LiEOnBS containing gel-polymer electrolytes. The maximum t$\sub$Li$\sub$+// was obtained to be 0.92 for the 0.1 M LiEOnBS containing polymer electrolytes. The synthesized LiEOnBS showed single ion transport like characteristics when n was large than 3.