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http://dx.doi.org/10.6111/JKCGCT.2022.32.6.225

Synthesis and characterization of the two-fold interpenetrated Tb(III)-based metal-organic framework  

Song, Jeong Hwa (Dept. of Advanced Materials & Chemical Engineering, Halla University)
Publication Information
Journal of the Korean Crystal Growth and Crystal Technology / v.32, no.6, 2022 , pp. 225-230 More about this Journal
Abstract
A new two-fold interpenetrating two-dimensional (2D) Tb(III) metal-organic framework (MOF), [Tb(p-XBP4)2.5(H2O)2]·W(CN)8 (1), was prepared using a p-XBP4 (N,N'-p-phenylenedimethylenbis(pyridin-4-one)), Cs3[W(CN)8], and Tb(NO3)3·6H2O. The single crystal X-ray diffraction indicated that Tb-MOF exhibits a unique two-fold interpenetrating 2-D framework. It was also characterized through Fourier transform infrared spectroscopy (FTIR), and single and powder X-ray diffraction. To probe the molecular magnetic behavior, the magnetic properties of Tb-MOF were investigated by direct-current (DC) and alternating-current (AC) magnetic susceptibilities measurements and discussed.
Keywords
Lanthanide; Tb-MOF; Metal-organic framework; Interpenetration; Magnetism;
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