• Journal of the Korean Ceramic Society
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• v.43 no.10 s.293
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• pp.607-612
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• 2006

In VARTM (Vacuum Assisted Resin Transfer Molding) process, the permeability generally controls the filling time of the resin and it also affects the void characteristics of the fiber composite. In this study, carbon and glass fiber inter-layered hybrid composites (carbon fiber centered stack) with an epoxy matrix were fabricated by VARTM process and evaluated the resin flow and macro void characteristics. The permeability of glass fiber was higher than that of carbon fiber used in this study. Using Darcy's equation, the permeability of hybrid composites could be predicted and experimentally confirmed. After curing, the macro void content of hybrid composites was investigated using image analyzer. The calculated filling time was well agreed with experimental result and the void content was significantly changed in hybrid composites.

• Proceedings of the Korea Electromagnetic Engineering Society Conference
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• 2002.11a
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• pp.29-33
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• 2002

본 논문은 자기 바이어스(self bias)를 이용한 PCS 대역용 하이브리드 전력 저잡음 증폭기(power LNA) 모듈에 관한 것으로 GaAs p-HEMT 칩을 세라믹 기판에 실장하여 와이어 본딩과 주변 매칭을 통해 고주파 손실을 줄이고 온도 변화에 대한 안정성과 1.2㏈의 저잡음, 21~23㏈m의 P$_1$㏈를 실현하였다. 10mm$\times$10mm 크기로 표면 실장이 되도록 단자를 cut-line 형태로 모듈화 하여 안정성과 신뢰성을 향상시켰고 또한 저가격화를 실현하였다.

• Journal of the Korea Safety Management & Science
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• v.7 no.1
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• pp.211-222
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• 2005

The ceramic forming materials are getting more important recently since they are used widely in repairing metal structures, welded metal structures and mechanical components etc. The determination of elastic constants for ceramic coating materials takes much time and efforts in experiment due to the brittleness of ceramic material itself. The aim of this research is to determine the Young's Modulus for ceramic metal coating material. In order to achieve the goal, the hybrid method which uses impulse hammer technique for experimental method and modal analysis of finite element method for computational method was used. The results show good agreement with existing experimental data on Young's Modulus.

• Ceramist
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• v.22 no.2
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• pp.189-197
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• 2019

Direct methanol fuel cells (DMFCs) have found a wide variety of commercial applications such as portable computer and mobile phone. In a fuel cell, the catalysts have an important role and durability and efficiency are determined by the ability of the catalyst. The activity of the catalyst is determined by the structure and shape control of the nanoparticles and the dispersion of the nanoparticles and application system. The surface energy of nanoparticles determines the activity by shape control and the nanostructure is determined by the ratio of bi- and tri-metals in the alloy and core-shell. The dispersion of nanoparticles depends on the type of support such as carbon, graphen and metal oxide. In addition, a hybrid system using both optical and electrochemical device has been developed recently.

• Applied Chemistry for Engineering
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• v.33 no.6
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• pp.600-605
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• 2022

In this study, nitrogen oxide (NO_x) removal experiments were performed using a graphene based ceramic filter coated with a V₂O₅-WO₃-TiO₂ catalyst. Graphene oxide (GO) was prepared by Hummer's method using graphite, and the reduced graphene oxide was produced by reducing with hydrazine (N₂H₄). Vanadium (V), Tungsten (W), and Titanium (Ti) were coated by the sol-gel method, and then a metal oxide-supported filter was prepared through a calcination process at 350 ℃. A NO_x removal efficiency test was performed for the catalytic ceramic filters with UV light in a humid condition. When graphene oxide (GO) and reduced graphene oxide (rGO) were present on the filter, the NOx removal efficiency was superior to that of the conventional ceramic filter. Most likely, this is due to an improvement in the adsorption properties of NOx molecules on graphene coated surfaces. As the concentration of graphene increased, higher NO_x removal efficiency was confirmed.

• Journal of the Korean Ceramic Society
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• v.40 no.12
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• pp.1202-1207
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• 2003

Using a recently developed Hybric Plasma-Particle Accelerating Impact Deposition (HP-PAID) process, synthesis of nanostructured silicon coatings has been investigated by injecting vapor-phase TEOS (tetraethosysilane, (C$_2$H$\_$5/O)$_4$Si) into an Ar hybrid plasma. The plasma jet with reactants was expanded through nozzle into a deposition chamber, with the pressure dropping from 700 to 10 torr. Ultrafine particles accelerated in the free jet downstream of the nozzle, deposited by an inertial impaction onto a temperature controlled substrate. By using this process, nanostructured amorphous silicon coatings with grain size smaller than 10 nm could be synthesized. These samples were annealed in an Ar and crystallized at 900$^{\circ}C$ for 30 min. TEM analysis showed that the annealed coatings were also composed of nanoparticles smaller than 10 nm, which showed a good consistency that the average grain size of 7 nm was also estimated from a peak shift of 2.39 cm$\^$-1/ and Full Width at Half Maximum (FWHM) 5.92 cm$\^$-1/ of Raman analysis. The noteworthy is that a strong PL peak at 398 nm was also obtained for this sample, which indicates that the deposited coatings also contained 3∼4 nm nanostructured grains.

• Korean Journal of Metals and Materials
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• v.50 no.3
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• pp.201-205
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• 2012

The effects of various manganese precursors for the low-temperature selective catalytic reduction (SCR) of $NO_x$ were investigated in terms of structural, morphological, and physico-chemical analyses. $MnO_x/TiO_2$ catalysts were prepared from three different precursors, manganese nitrate, manganese acetate(II), and manganese acetate(III), by the sol-gel method. The manganese acetate(III)-$MnO_x/TiO_2$ catalyst tended to suppress the phase transition from the anatase structure to the rutile or the brookite after calcination at $500^{\circ}C$ for 2 h. It also had a high specific surface area, which was caused by a smaller particle size and more uniform distribution than the others. The change of catalytic acid sites was confirmed by Raman and FT-IR spectroscopy and the manganese acetate(III)-$MnO_x/TiO_2$ had the strongest Lewis acid sites among them. The highest de-NOx efficiency and structural stability were achieved by using the manganese cetate(III) as a precursor, because of its high specific surface area, a large amount of anatase $TiO_2$, and the strong catalytic acidity.

• Membrane Journal
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• v.27 no.4
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• pp.328-335
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• 2017

Fabricating photocatalytic composite membrane with a mesoporous and tailored morphological structure would have significant implication for environmental remediation. In this study, we reported hybrid $TiO_2$ immobilized photocatalytic membrane and its application for the treatment of dye solution. Photocatalytic film with high porosity and homogeneity was fabricated by graft copolymer as polymer template. Hybridization of membrane filtration with photocatalysis was successfully achieved by photocatalytic membrane reactor developed. Result showed that membrane permeability was significantly reduced after immobilizing the $TiO_2$ film on bare $Al_2O_3$ support. The membrane characterization indicated that well organized $TiO_2$ film was successfully formed on $Al_2O_3$ support. Benefiting from the controlled morphology of $TiO_2$ film, the composite membrane exhibited almost complete degradation of organic dye within 5 h of filtration under UV illumination. Langmuir-Hinshelwood model explained degradation of organic dye. First-order rate constant was approximately six times with $TiO_2$ immobilized composite ceramic membrane, higher than the one with the bare $Al_2O_3$ support (0.0081 vs. $0.0013min^{-1}$).

• Journal of the Korean Ceramic Society
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• v.50 no.2
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• pp.142-148
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• 2013

Conventional cold isostatic pressing, slip casting, and filter pressing are not completely suitable for fabricating large plates because of disadvantages such as the high cost of equipment and formation of density gradient. These problems could be avoided by employing pressure-vacuum hybrid slip casting (PVHSC). In the PVHSC, the consolidation occurs not only by the compression of the slip in casting room, but also by vacuum sucking of the dispersion medium around the mold. We prepared the alumina bodies by the PVHSC in a static- or stepwise-pressure manner for loading up to 0.5 MPa using an aqueous slip. The green bodies were dried at $30^{\circ}C$ with 40 ~ 80% relative humidity. Under static pressure, casting induced a density gradient in the formed body, resulting in cracking and distortion after the firing. However, the stepwise pressure loading resulted in green bodies with homogeneous density, and the minimization of the appearance of those defects in final products. Desirable drying results were obtained from the cast bodies dried with 80% RH environment humidity. When sintered at $1650^{\circ}C$ for 4 h, the alumina plate made by stepwise-pressure casting reached full density (> 99.7% relative density).

• Journal of the Korean Ceramic Society
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• v.49 no.6
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• pp.592-600
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• 2012

Conventional methods for preparing ceramic bodies, such as cold isostatic pressing, gypsum-mold slip casting, and filter pressing are not completely suitable for fabricating large and thick ceramic plates owing to disadvantages of these processes, such as the high cost of the equipment, the formation of density gradients, and differential shrinkage during drying. These problems can be avoided by employing a pressure-vacuum hybrid slip casting approach that considers not only by the compression of the aqueous slip in the casting room (pressure slip casting) but also the vacuum sucking of the dispersion medium (water) around the mold (vacuum slip casting). We prepared the alumina formed bodies by means of pressure-vacuum hybrid slip casting with stepwise pressure loading up to 0.5 MPa using a slip consisting of 40 vol% solid, 0.6 wt% APC, 1 wt% PEG, and 1 wt% PVA. After drying the green body at $30^{\circ}C$ and 80% RH, the green density of the alumina bodies was about 56% RD. The sintered density of an alumina plate created by means of sintering at $1650^{\circ}C$ for 4 h exceeded 99.8%.This method enabled us to fabricate a $110{\times}110{\times}20$ mm alumina plate without cracks and with a homogeneous density, thus demonstrating the possibility of extending the method to the fabrication of other ceramic products.