• Title/Summary/Keyword: 플라스틱 결함

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Contribution of Advanced or Alternative Process to Carbon-Dioxide Emission Reduction in Olefin Production Plant (올레핀(Olefin) 생산 공정에서 발생하는 이산화탄소 배출 저감을 위한 신기술 적용 효과)

  • Wee, Jung-Ho;Choi, Kyoung-Sik;Kim, Jeong-In;Lee, Sang-Hoon
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.8
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    • pp.679-689
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    • 2009
  • Light olefins are very important hydrocarbons widely used as the raw materials of the most petrochemicals including plastics and medicines. In addition, the nation's olefin production capacity is regarded as one of the key indicators to predict the nation's economic scale and growth. Steam cracking of naphtha (or called "NCC (Naphtha Cracking Center) technology"), the traditional process to produce light olefins, is one of the most consuming energy processes among the chemical industries. Therefore, this process causes tremendous $CO_2$ emission. To reduce the energy consumption and $CO_2$ emission from NCC process, the present paper, firstly, investigates and analyses some alternative technologies which can be potentially substituted for traditional process. Secondly, applying the alternative technologies to NCC process, their effects such as energy savings, $CO_2$ emission reduction and CER (Certified Emission Reduction) were estimated. It is found that the advanced NCC process can reduce approximately 35% of SEC (Specific Energy Consumption) of traditional NCC process. This effect can lead to the reduction of 3.3 million tons of $CO_2$ and the acquisition of the 128 billion won of CER per year. Catalytic cracking of naphtha technology, which is other alternative processes, can save up to approximately 40% of SEC of traditional NCC process. This value equates to the 3.8 million tons of $CO_2$ mitigation and 147 billion won of CER per year.

Comparision of Preservation of Liquid Boar Semen between Lactose-Egg Yolk and $B\ddot{u}tschwiler$ Diluents (돼지 액상정액 보존을 위한 Lactose-Egg Yolk와 $B\ddot{u}tschwiler$ 희석액의 비교)

  • Park, C.S.;Cheon, Y.M.;Xu, Z.
    • Korean Journal of Animal Reproduction
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    • v.20 no.2
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    • pp.101-109
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    • 1996
  • This study was done to find out the methods of long-term use of liquid boar semen in 100 ml plastic bottle for artificial insemination and to investigate differences between Lactose-Egg yolk and Biitschwiler diluents according to storage temperature, and effect of final glycerol concent ration in Lactose-Egg yolk diluent. Liquid boar semen diluted with Lactose-Egg yolk diluent showed significantly higher sperm motility (p<0.05) after 0.5 and 2h incubation at 37$^{\circ}C$,than Butschwiler diluent at all storage length when it was preserved in the 5$^{\circ}C$ refrigerator. The NAR acrosome in Lactose-Egg yolk diluent a after 0.5 and 2h incubation at 37$^{\circ}C$, respectively, during preservation periods was similar to that in Biitschwiler diluent. When liquid boar semen was preserved at 15$^{\circ}C$, liquid boar semen in the Butschwiler diluent showed significantly higher percentages of sperm motility and NAR acrosome from third day to seventh than that in Lactose-Egg yolk diluent. In the effect of final glycerol concentration of liquid boar semen in the Lactose-Egg yolk diluent, the final glycerol concentration of 2% showed higer percentages of sperm motility and NAR acrosome than that of 0, 1, 3, and 5%. Farrowing rate, litter size and average pig weight at birth did not differ significantly between Lactose-Egg yolk and But schwiler diluents. As a result of this study, we found out that liquid boar semen can be stored for 6-7 days at 5$^{\circ}C$ in Lactose-Egg yolk diluent and at 15$^{\circ}C$ in Butschwiler diluent.

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Heavy metal exposure assessment of recycled plastic buckets (재활용 플라스틱 제품 중 고무대야의 중금속 노출량 평가)

  • Kim, Min-Sun;Kim, Woo Il;Shin, Sun Kyoung;Kang, Young-Yeul;Cho, Yoon-A;Jeong, Seong-Kyeong;Jin, Na;Yeon, Jin-Mo;Lee, Ji-Young
    • Analytical Science and Technology
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    • v.26 no.1
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    • pp.67-72
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    • 2013
  • This study has been conducted to provide a management plan for recycled products (plastic wastes) by identifying hazardous substances present in it and conducting exposure assessment. The concentration of 7 heavy metals (Cd, Cr, Cu, Fe, Hg, Pb, Zn) was analyzed. Exposure scenario was assumed by the consumption of kimchi made in a recycled plastic bucket. According to the analysis, all of the analyzed samples were within the food code standard level except one sample (137.03 mg/kg, sum of Cd, $Cr^{6+}$, Pb and Hg). In leaching test, all of heavy metals were within the leaching standard (Standards specifications of utensil and container-Packing). In an oral exposure test, Fe, Pb and Zn were detected in cabbages and were below PMTDI (Provisional Maximum Tolerable Daily Intake). As one of the recycled plastic buckets exceeded the standard level, we conclude not to recommend the recycled plastic buckets for cooking purpose.

Root zone environments in two cropping system within a year for Kyoho grapes (포도 '거봉'의 2기작 재배에서 근권환경 특성)

  • 오성도;김용현
    • Journal of Bio-Environment Control
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    • v.6 no.4
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    • pp.235-241
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    • 1997
  • This study was performed to investigate the behaviour of root zone environments under the control of soil temperature and tension of soil moisture near the root Bone of 'Kyoho' grapes tree grown on restricted root zone system in plastic greenhouse. Maximum diurnal air temperature inside plastic greenhouse ranged between 25.1 and 32.7$^{\circ}C$, and the average of nocturnal air temperature inside plastic greenhouse maintained at 18$^{\circ}C$ in winter season. Also the minimum diurnal relative humidity ranged between 50 and 55%, and the maximum nocturnal relative humidity ranged between 84 to 87%. At a depth of 15cm from soil surface, the average soil temperature maintained at 25.6$^{\circ}C$ for under-ground heating, and appeared to 17.4$^{\circ}C$ for unheated condition. Although the tension of soil moisture just after irrigation sharply decreased to pF 1.5, the tension of soil moisture at the depth of 15cm maintained at pF 2.0~2.2. It is suggested that the tension of soil moisture at the depth of 15cm might be used as the standard for the determination of irrigation set point. Effective drainage system is needed to prevent the spindly and succulent growth of vine trees grown in restricted root zone system.

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Occurrence, Injury aspects and Effect of insecticide applications of Liriomyza trifolii Burgess on Tomato Cultivated in Plastic house (토마토에서 아메리카잎굴파리의 발생, 가해양상 및 살충제처리 효과)

  • Park, Jong-Dae;Uhm, Ki-Baik;Yoo, Jae-Gi;Kim, Sang-Chul
    • The Korean Journal of Pesticide Science
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    • v.4 no.2
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    • pp.50-55
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    • 2000
  • Occurrence, Injury aspects and control effect of some chemicals were investigated on tomato in plastic house from 1997 to 1998. Adults trapped by yellow sticky trap and sweeping net were increased from late May abruptly. Survey of population densities by yellow sticky trap was more clear than sweeping net. Damaged leaves were found out all the year round in continuous cropping fields and rate of damaged leaves was below 20% in early April and increased gradually up to 80% level after late May. Otherwise, damaged leaves were appeared from 6 weeks after transplanting in first growing field and then damaged leaves was 80% level in spring culture. In autumn culture, rate of damaged leaves was maintained 80% level from transplanting to harvesting date regardless of cultivation years. Number of adults was trapped from late May and peak was late June but mature larva was $6{\sim}8$ individuals in spring culture. In autumn culture, adult and larval densities was maintained high for 3 weeks after transplanting but begun to decrease from 4 weeks(early September). Chlorfenapyr EC, cyromazine WP and abamectin EC could suppress larval populations of Liriomyza trifolii effectively.

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Moire Interferometry Measurement and Numerical Analysis for Hygroscopic Swelling of Al-Polymer Joint (Al-Polymer 접합체의 흡습팽창에 대한 모아레 간섭 측정 및 수치해석)

  • Kim, Kibum;Kim, Yong-Yun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.6
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    • pp.3442-3447
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    • 2014
  • A simple method to evaluate the hygroscopic characteristics of polymer of microelectronic plastic package is suggested. To evaluate the characteristics, specimens were prepared, and the internally absorbed moisture masses were measured as a function of the absorbing time and calculated numerically. The hygroscopic pressure ratio was calculated by heat transfer analysis supported by commercial FEM code because the hygroscopic diffusion equation has the same form as the heat transfer equation. The moisture masses were then summed by the self developed code. The nonconductive polymers had quite different characteristics for the different lots, even though they were the same products. The absorbed moisture mass variations were calculated for several different characteristics, and the optimal curve of the mass variation close to experimental data was selected, whose solubility and diffusivity were affected by the hygroscopic characteristics of the material. The method can be useful in the industrial fields to quickly characterize the polymer material of the semiconductor package because the fast correspondence is normally required in industry. The weight changes in the aluminum-nonconductive-polymer joint due to moisture absorption were measured. The deformed system was also measured using the Moire Interferometry system and compared with the results of finite element analysis.

Study on Oxidation Properties of Biodiesel Blended Fuels according to Storage Circumstances (저장 환경에 따른 바이오디젤 혼합연료의 산화특성 규명 연구)

  • Min, Kyong-Il;Yim, Eui-Soon;Jung, Chung-Sub;Kim, Jae-Kon;Na, Byung-Ki
    • Journal of the Korean Applied Science and Technology
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    • v.30 no.4
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    • pp.701-714
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    • 2013
  • Recently, due to the activation policy of biodiesel, the blending biodiesel to petroleum product is increasing. Low-temperature fluidity and oxidation stability are the most significant issues to the marketers and end users of biodiesel. Thus, the way to control the quality of biodiesel blended fuels was investigated by duplicating the real storage situation of biodiesel blended fuels and evaluating the effect of oxidation trend and quality degradation. From the results of oxidation degradation test of biodiesel blended fuels, no special quality degradation has been observed through the evaporation for 18 weeks in a summer season under a storage circumstance without exposure to the sun light. However, the severe quality degradation was observed in PE vessel in only 2 weeks of storage. This oxidation degradation was also verified with FT-IR spectrum change. However, the special symptom cannot be distinguished by the quality test because the quality specifications were satisfied despite of the drastic oxidation degradation. Namely, the problem in a vehicle could be occurred by oxidation materials(polymer, organic acid. etc.) under oxidation even though it satisfied the quality specification.

New Technology Development for Production of Alternative Fuel Oil from Thermal Degradation of Plastic Waste (폐플라스틱의 열분해에 의한 대체 오일 생산의 신기술 개발)

  • Lee, Kyong-Hwan;Roh, Nam-Sun;Shin, Dae-Hyun
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2005.10a
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    • pp.34-46
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    • 2005
  • For treating a huge amount of plastic waste with the environment problem, pyrolysis of plastic waste into alternative fuel oil is one of important issue in recycling methods. This study was introduced over the trend of generation of plastic waste, pyrolysis technology in domestic and foreign countries, basic technology in pyrolysis process and new technology of pyrolysis developed in KIER (Korea Institute of Energy Research). The characteristics of process developed in KIER are the continuous loading treatment of mixed plastic waste with an automatic control system, the minimization of wax production by circulation pyrolysis system in non-catalytic reactor, the reuse of gas produced and the oil recovery from sludge generated in pyrolysis plant, which have greatly the advantage economically and environmetally. The experiment result data in 300 ton/yr pilot plant showed about 81 wt% liquid yield for 3 days continuous reaction time, and also the boiling point distribution of light oil (LO) and heavy oil (HO) produced in distillation tower was a little higher than that of commercial gasoline and diesel, respectively.

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Effects of Storage Conditions on Weight Loss and Free Sugar Composition of Fresh Ginseng (보관조건에 따른 수삼의 중량과 유리당 조성 변화)

  • Chang, Jin-Kyu;Kim, Cheon-Sug;Nho, Kil-Bong;Cho, Byung-Goo
    • Journal of Ginseng Research
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    • v.29 no.2
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    • pp.113-118
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    • 2005
  • This study was to examine the effect of the opening ratio (area of spile hole/total surface area) of plastic container and storage temperature on physicochemical changes of fresh ginseng. At room temperature ($19\~23^{\circ}C$, RH $40\~61\%$), fungi and spoilage were observed 4 and 10 days, respectively after storing the fresh ginseng in a closed container. In storage container with $1\%$ opening ratio, fungi appeared 8 days after storage. In the container with $5\%$ and $10\%$ opening ratio, fresh ginseng showed excessive loss of moisture on the surface only after 4 days. The weight loss was most remarkable in the container with 5 and $10\%$ opening ratio. Content of maltose and sucrose decreased gradually in accordance with storage time but the extent of decreasing ratio was less significant in the container with lower opening ratio. At low temperature $(4\~9^{\circ}C,\;RH\;72\~92\%)$, no fungi but $10\%$ loss of weight was observed in the container with $5\%$ and $10\%$ opening ratio after 12 days storage. But in the tightly closed container and $1\%$ opening ratio for spiting, fresh ginseng showed good appearance even after 30 days of storage. Free sugars, especially maltose revealed gradual decrease but sucrose gradually increase following decrease at the beginning. This result suggests that storage condition of low temperature and opening ratio of plastic box less than $1\%$ can extend storage span of fresh ginseng significantly.

Preparation and characterization of CoAl2O4 blue ceramic nano pigments by attrition milling (어트리션밀을 이용한 CoAl2O4 나노 무기 안료의 제조 및 특성 평가)

  • Lee, Ki-Chan;Yoon, Jong-Won;Kim, Jin-Ho;Hwang, Kwang-Taek;Han, Kyu-Sung
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.23 no.5
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    • pp.255-264
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    • 2013
  • Cobalt aluminate ($CoAl_2O_4$) is a highly stable pigment with excellent resistance to light, weather, etc., which has resulted in widespread use as a ceramic pigment. Due to the unique optical characteristics, $CoAl_2O_4$ is generally used as a coloring agent to decorate porcelain products, glass, paints and plastics. Here, $CoAl_2O_4$ pigments were synthesized by polymerized complex method and solid state reaction. Then $CoAl_2O_4$ pigment were grinded using the attrition milling with 1 mm size zirconia ball for 3 hours. The attrition milling process was performed at the constant speed of 800 rpm and ball to powder weight ratio (BPR) was 100 : 1. The characteristics of synthesized pigment were analyzed by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), particle size analyser (PSA) and CIE $L^*a^*b^*$. The XRD patterns of $CoAl_2O_4$ show single phase spinel structure. The particle size of $CoAl_2O_4$ measured by FE-SEM, TEM and PSA analysis was in the range of 100~200 nm. The blue color of obtained $CoAl_2O_4$ pigments could be confirmed through CIE $L^*a^*b^*$ measurement.