• Title/Summary/Keyword: 푸리에 변환 분광

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푸리에 변환 적외선 분광분석에 의한 에피층의 두께 측정 기술

  • Jeong, Seong-Hwa;Kim, Sang-Gi;Kwon, Oh-Joon
    • ETRI Journal
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    • v.13 no.2
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    • pp.54-61
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    • 1991
  • 에피택시층의 두께는 푸리에변환적외선분광분석(FTIR)을 이용하여 간단하고 비파괴적으로 측정할 수 있음이 알려져 있다. 본고에서는 측정법의 기본적인 배경을 살펴보고 실제 시편의 측정결과를 제시하며 본 두께 측정법의 적용 가능성 및 문제점에 대해 논의한다.

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Cement Paste Hardened Body with High Temperature Exposure Time Fourier Transform Infrared Spectroscopy (고온 노출 시간에 따른 시멘트 페이스트 경화체의 푸리에 변환 적외분광 분석)

  • Kim, Min-Hyouck;Cho, Hyeon-Seo;Lee, Gun-cheol
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2019.05a
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    • pp.120-121
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    • 2019
  • In this study, FT-IR analysis was performed by exposing cement paste to high temperature in order to characterize the change of hydration behavior of concrete structure damaged by fire accident. As the holding time increased, the Al-O vibration region increased due to the increase of Si-O symmetric Ca2(SiO4) and Brownilerite, and the OH stretching region tended to increase due to thermal decomposition of Ca(OH)2.

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Determining the Thickness of a Trilayer Thin-Film Structure by Fourier-Transform Analysis (푸리에 변환을 이용한 3층 구조 박막의 두께 측정)

  • Cho, Hyun-Ju;Won, Jun-Yeon;Jeong, Young-Gyu;Woo, Bong-Ju;Yoon, Jun-Ho;Hwangbo, Chang-Kwon
    • Korean Journal of Optics and Photonics
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    • v.27 no.4
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    • pp.143-150
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    • 2016
  • The thickness of each layer in a multilayered system is determined by a Fourier-transform method using spectroscopic reflectance measurements. To verify this method, we first generate theoretical reflectance spectra for three layers, and these are fast-Fourier-transformed using our own Matlab program. Each peak of the Fourier-transformed delta function denotes the optical thickness of each layer, and these are transformed to physical thicknesses. The relative thickness error of the theoretical model is less than 1.0% while a layer's optical thickness is greater than 730 nm. A PI-(thin $SiO_2$)-PImultilayeredstructure produced by the bar-coating method was analyzed, and the thickness errors compared to SEM measurements. Even though this Fourier-transform method requires knowing the film order and the refractive index of each layer prior to analysis, it is a fast and nondestructive method for the analysis of multilayered structures.

The quantitative analysis of combustive gases on fire by remote passive open path FT-IR spectrometer (Passive open-path FT-IR spectrometer를 사용한 원거리 화재 연소 가스 정량 분석)

  • Cho, Nam Wook;Cho, Won Bo;Kim, Hyo Jin
    • Analytical Science and Technology
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    • v.26 no.2
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    • pp.120-124
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    • 2013
  • It was studied to analyze the $CO_2$, CO, $SO_2$ standard gases of combustion gases by the open path FT-IR spectrometer with passive mode for remote analysis of air pollutant and volcano gases without IR lamp. As result, it was confirmed to have good linearity with more than 0.9 as correlation coefficients on the calibration curve of $CO_2$, CO concentration by MLR method. But in the case of $SO_2$, because the correlation coefficients were 0.88, the linearity could be lower. Finally, the concentration of three gases was predicted on in-site fire experiment under the condition of quantitative analysis. It could measure high $CO_2$ concentration as predicted result, but didn't measure the CO and $SO_2$. According to the result, it was possible to measure the combustion gases to long distance by only open path FT-IR spectrometer without infrared lamp.

Analysis of sampling noise effect of Interferometer on FTIR Spectrometer (FTIR 분광용 간섭계의 샘플링 잡음 영향 분석)

  • Bae, Hyo-Wook;Park, Do-Hyun;Ra, Sung-Woong;Choi, Seung-Ki
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.44 no.4
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    • pp.10-17
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    • 2007
  • FTIR(Fourier Transform Infrared) spectrometry is a useful method to obtain infrared spectra of materials in gas phase by registering the interferogram of a target material using an interferometer, and then performing a Fourier transform on the interferogram to obtain the spectrum. In this paper, sampling noise effect on signal processing of the rapid scan interferometer was studied with relation to sampling the interferogram points at the improper location and empirically verified.

Development of Lyocell-Based Graphite Fabric for Aerospace (항공우주용 리오셀계 흑연화 직물 개발)

  • Park, Gil-Young;Kim, Nam-Kyu;Kim, Yun-Chul;Seo, Sang-Kyu;Chung, Yong-Sik
    • Journal of the Korean Society of Propulsion Engineers
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    • v.25 no.4
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    • pp.36-42
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    • 2021
  • In this study, the impregnation of Lyocell fabrics was performed using phosphoric acid, ammonium phosphate, diammonium hydrogen, triammonium phosphate as phosphorus flame retardant, to fabricate continuous graphite fabrics using lyocell fiber. The physical and chemical structure changes were investigated by thermogravimetric, Fourier-transform infrared spectroscopy, C-nuclear magnetic resonance, X-ray diffraction, and weight analyses, By analyzing the thermal behavior of phosphorus flame retardant, conditions for the temperature, gas, and residual time of the pyrolysis process were set. Graphite fabrics with a tensile strength of 1,007.19±11.47 N/5 cm and yield of 25.3% were fabricated using continuous pyrolysis, carbonization and graphitization process.

Preparation of Dye Sensitized Solar Cell Using Coumarin Dyes Extracted from Plants (식물에서 추출한 천연 쿠마린계 염료를 이용한 염료감응 태양전지의 제조)

  • Jung, Onyu;Lee, Sang-Soo
    • Korean Chemical Engineering Research
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    • v.51 no.1
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    • pp.157-161
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    • 2013
  • Low priced and environment-friendly natural dye from coumarin- containing plants for the dye sensitized solar cell (DSSC) was developed. Dyes were extracted from cinnamon and angelica that contained coumarin derivatives, and DSSCs employing these dyes were prepared. PV efficiency of 0.75% was obtained from cinnamon dye, which is comparable to the highest efficiency reported in precedent studies about natural dye DSSC. It was confirmed by UV-visible and FT-IR spectroscopy that coumarin derivatives in the plants acted as photosensitive material.

Study on the Generation of Leakage Current by the Fourier Transform Infrared Analysis (푸리에변환 적외선분광분석법에 의한 누설전류의 발생 원인에 대한 연구)

  • Oh, Teresa
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.6
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    • pp.514-519
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    • 2007
  • The surfaces of $SiO_2$ films were treated by PMMA diluted solutions, and analyzed the chemical shift from Fourier Transform Infrared Spectrometer. The $SiO_2$ film treated by PMMA diluted solution changed the properties of the surface, and showed the blue and red shift according to the concentration of PMMA. The C-H bond elongation effect due to the high electro-negative atom chlorine showed the red shift, and makes the final material with the cross-link structure. The leakage current was efficiently reduced at the sample No 7 with the red shift, witch depends on the electron deficient group.