• Proceedings of the KIEE Conference
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• 2002.11a
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• pp.248-250
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• 2002

본 논문은 당뇨병의 지표물질인 glucose의 농도를 극미량의 시료를 사용하여 정량 할 수 있는 방법을 개발하기 위하여 효소 고정화 전극을 제작하였다. 전극은 실리콘 웨이퍼상에 마이크로 크기의 전극을 반도체 공정을 이용하여 제작하였고, 전기 화학적 방법으로 마이크로 전극에 전도성 고분자 Polypyrrole(PPy) 및 glucose oxidase(GOx)를 고정화한 고감도의 전기화학 전극을 개발하였다. 도전성 고분자의 전기 화학적 중합은 순환 전압 전류법으로 하였으며, 용액의 액성에 따른 효소의 표면 전하를 이용하여, 도전성 고분자를 코팅한 전극에 일정한 전압을 인가하고 GOx를 도우핑 하였다. 제작된 전극은 시간대 전류법으로 glucose의 농도에 따른 감도 측정결과 마이크로 리터의 시료에 $5{\mu}A$/decade를 얻었다. 전극의 표면분석은 Scanning electron microscopy(SEM), Energy dispersive X-ray spectroscopy(EDX)를 이용하였다.

• 전자공학회논문지 IE
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• v.44 no.3
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• pp.6-11
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• 2007

In this study, which was performed to identify a degradation mechanism in macromolecular insulating material, the contact angle, surface potential decay, surface resistance rate and XPS analysis were compared after exposure of fibre-glass-reinforced polymer laminate to plasma discharge. In the case of chemical changes arising from plasma treatment, carboxyl radicals were generated mainly in the plasma-treated surface, which was rapidly changed to a hydrophilic surface. In the corona potential decay study to determine the electrical changes, leading to a negative surface for the untreated specimen. However, in the case of the hydrophilic surface, a lot of carboxy radicals(-COO) acting as positive polarity were generated, resulting in a positive surface. Owing to such a positive surface, the charges of applied negative polarity were decreased rapidly.

• Journal of the Korean Vacuum Society
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• v.18 no.4
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• pp.281-287
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• 2009

Pd was deposited on magnesium-oxide-covered magnesium ribon substrate by metal thermal evaporation method in high vacuum. The electronic and chemical properties of Pd samples with different coverages were studied using in-situ X-ray Photoelctron Spectroscopy (XPS) and Field Emission Scanning Electron Microscopy (SEM). For relatively lower amounts of Pd deposited(< 1nm), separate Pd particles could be observed, whereas at higher Pd coverages, Pd thin films caused by agglomeration of Pd nanoparticles was found. The metal support interaction with Pd-support was observed. The Pd atoms on the metal oxide/metal interface were partially negative charged by charge transfer.

• Korean Journal of Materials Research
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• v.10 no.8
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• pp.564-568
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• 2000

Langmuir-Blodgett(LB) 법은 미래의 분자전자소자를 위한 가장 유력한 수단이며, 이러한 분자박막 소자는 그 성질이 분자는 배향에 영향을 박데 되므로 현재 새로운 물질을 이용하여 분자전자소자의 제작에 있어 관심을 모으고 있다. 본 연구에서는 (N-docosyl quinolinium)-TCNQ(1:2) 전하 이동 착물 LB 막의 분자 배향을 UV/vis 편광흡수 스펙트럼과 FT-IR transmission 및 reflection-absorption 스펙트럼의 흡수강도를 비교하여 정량적으로 평가하였다. 그 결과 TCNQ의 transition dipole moment의 각은 약 56~58。 였으며, 알킬 고리의 경사각은 약 11.1~13。였다. 제작된 Z-형 LB 막의 표면은 고압에서 중앙 높이 차가 3~4$\AA$으로 평탄하였다.

• The Transactions of the Korean Institute of Electrical Engineers C
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• v.49 no.6
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• pp.341-345
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• 2000

This paper analysed the induced electric field of human body under the 765 kV transmission line considering permittivity and conductivity. As permittivity of human body is very high as 106 at 60 Hz, special numerical computation technique is Surface Charge Method(SCM) for composite media with extremely different properties is applied to reduce calculation error of induced electric field inside the human body.

• The Transactions of the Korean Institute of Electrical Engineers
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• v.34 no.9
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• pp.341-348
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• 1985

This paper deals with a surface charge simulation method of calculating three-dimensional electric fields and capacitance. The principle is to divide the electrode surface into rectangular or triangular elements of which charge density is the linear function of the electrode coordinate and to formulate a linear equation for the coefficients of charge density function and to determine those coefficients by boundary conditions. It has been shown that the method can give satisfactory results for thin rectangular plates where the other methods is difficult to be applied.

• Proceedings of the KIEE Conference
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• 1999.07e
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• pp.2117-2119
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• 1999

In this paper, the electric fields inside GIS with metal impurity is analysed by the use of 3 dimensional Surface Charge Method. We find the metal impurity makes electric field distribution inside GIS non-uniform and causes breakdown of $SF_6$ gas in GIS.

• Proceedings of the KIEE Conference
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• 2000.07c
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• pp.1987-1989
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• 2000

In this paper, electric field distribution of dielectric sphere considering surface or volume resistivity is analysed by the use of rotational symmetric charge simulation method. We applied three methods such as ${\alpha},{\beta}$ modified $\beta$ method to check electric field calculation error. We find f method and modified $\beta$ method are suitable to simulate volume and surface resistivity respectively.

• Applied Chemistry for Engineering
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• v.9 no.3
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• pp.361-363
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• 1998

The CNDO/2 calculations have been applied on cluster models for the representative hydroxyls on faujasite surface to get total energies, dipole moments, Wiberg bond orders and formal charge densities. Quantum chemical calculations indicate that the acid strength of surface hydroxyls of faujasite depends on the geometry of hydroxyls and the Si/Al ratios of framework. The $Br{\ddot{o}}nsted$ acid strength of bridging hydroxyl is higher than that of isolated hydroxyls. The stabilities of cluster models increased with increase of the Si/Al ratios.

• Journal of Adhesion and Interface
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• v.22 no.4
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• pp.144-152
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• 2021

Understanding charge transfer across the interface between organic semiconductor and gate insulator gives insight into the development of high-performance organic memory as well as highly stable organic field-effect transistors (OFETs). In this work, we firstly unveil a novel interfacial charge transfer mechanism, in which hole transfer from organic semiconductor to polymer insulator was nonlinearly boosted by localized states coupling. For this, OFETs based on rubrene single crystal semiconductor and Mylar gate insulator were fabricated via vacuum lamination, which allows stable repetition of lamination and delamination between semiconductor and gate insulator. The surfaces of rubrene single crystal and Mylar film were selectively degraded by photo-induced oxygen diffusion and UV-ozone treatment, respectively. Consequently, we found that the interfacial charge transfer and resultant bias-stress effect were nonlinearly boosted by coupling between localized states in rubrene and Mylar. In particular, the small number of localized states in rubrene single crystal provided fluent pathway for interfacial charge transport.