• Title/Summary/Keyword: 표면 전하법

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최근의 수직전계계산법 (1)

  • 박중근
    • 전기의세계
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    • v.34 no.5
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    • pp.299-304
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    • 1985
  • 수직전계 계산방법의 정밀도 및 근사과도의 평가의 기준이 되며 전하중첩법의 전위 및 전계 소계수식에 형태가 남아있다. 또한 영상전하가 전하중첩 및 표면전하법 등에서 이용되고 있는 것이 특징이다.

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Effects of Soil Component and Index ion on the Surface Charge Characteristics of some Korean arable soils (일부 경작지 토양의 표면전하 특성에 미치는 점토광물, 유기물 및 지표이온의 영향)

  • Ok, Yong-Sik;Choi, You-Suk;Lee, Sang-Eun;Lim, Soo-Kil;Chung, Nam-Hyun;Kim, Jeong-Gyu
    • Korean Journal of Soil Science and Fertilizer
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    • v.34 no.4
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    • pp.237-244
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    • 2001
  • Investigation on the surface charge properties of some Korean arable soils was performed by ion adsorption technique with two kinds of indifferent ion ($Na^+$ and $K^+$) at the range of pH 3 to 9 in bulk solution. The contribution of soil components(organic matter, oxides and clay mineral) on the surface charge density was determined at two soil depth with different solid particle composition When the pH of solution increased, the negative charge of soil surface was increased among the all soils, but positive charge were not appeared above pH 6. apparently. The magnitude of surface charge density measured by NaCl adsorption method showed ra nges of $0.01{\sim}2.84cmol_c{\cdot}kg^{-1}$ and $7.41{\sim}12.20cmol_c{\cdot}kg^{-1}$ at pH 3 and pH 9, respectively. Ion adsorption method using KCl as index ion overestimated than the method using NaCl as index ion. The content of organic matter is the strongest factor on the value of dCEC/dpH.

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The Study on the Measurement of Space Charge of Polyethylene Film for use in Power Equipment by TSSP Method. (전력설비용 Polyethylene Film의 열자극 표면 전위법에 의한 공간전하에 측정에 관한 연구)

  • 국상훈;이경섭
    • The Proceedings of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.4 no.4
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    • pp.68-78
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    • 1990
  • 절연파괴의 원인이 되는 절연체중의 공간전하의 여러 특성을 정량적으로 측정하였다. 전극에서의 주입전하가 트랩되어 주로 공간전하를 형성하는 것을 확인하였다. TSSP측정법으로 컬렉팅 전위를 결정하고 바이어스의 시간, 전압, 온도에 따른 공간전하 변화량을 측정하여 공간적 분포의 깊이를 조사하였다. 그리고 정상상태에 있어서 모델과 해석과 시험 결과가 비교적 잘 일치함을 발견하였다.

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Raman Spectroscopic Deconvolution of Strain and Charge Doping Effects in Graphene on SiO2/Si Substrate

  • Lee, Ji-Eun;Kim, Seon-Ho;Gang, Seong-Gyu;Yang, Seong-Ik;Lee, Yeong-Sik;Ryu, Sun-Min
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.155-155
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    • 2011
  • 그래핀(graphene)은 모든 탄소 원자가 표면에 존재하는 이차원 결정이기 때문에 다른 고체 표면에 고착될 때 인장 및 압축 변형(tensile & compressive strain)과 전하 도핑(charge doping)에 취약하다고 알려져 있다. 본 연구에서는 산화실리콘(SiO2/Si) 기판 위에 기계적으로 박리된 그래핀에 혼재되어 나타나는 기계적 변형과 전하 도핑 현상을 분석할 수 있는 라만 분광법 기술을 개발하고자 하였다. 대부분의 시료에서 기계적 변형으로 인해 라만 G-band와 2D-band의 진동수(${\omega}$)가 특별한 상관관계(${\Delta}{\omega}2D/{\Delta}{\omega}G$ = 2.0 ${\pm}$ 0.2)를 가진다는 사실을 확인하였다. 전자 친화도가 큰 F4-TCNQ (tetrafluorotetracianoquinodimethane)를 증착하여 화학적으로 p-형 전하 도핑을 유도한 그래핀에서는 기계적 변형과는 분명히 구별되는 상관관계(${\Delta}{\omega}2D/{\Delta}{\omega}G$ = 1.0 ${\pm}$ 0.3)가 관찰되었다. 본 연구는 라만 분광법을 통해 그래핀의 기계적 변형과 전하 도핑 정도를 정량적으로 분리해서 분석할 수 있는 방법을 제시해 준다.

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A Study on the Surface Acid Amount and Surface Charge Density of Acid Treated γ-Alumina (산처리한 γ-알루미나의 표면 산량과 표면 전하밀도)

  • Hong, Young-Ho;Lee, Chang-Woo;Hahm, Yeong-Min
    • Applied Chemistry for Engineering
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    • v.9 no.3
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    • pp.377-382
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    • 1998
  • This study was carried out to investigate the relation between surface acidity and interfacial electrical characteristics of surface-treated ${\gamma}-alumina$ whose surface activity was increased. The points of zero charge (P. Z. C.) of ${\gamma}-alumina$ whose surface is treated with the sulfuric, nitric and hydro-chloric acid of various concentration were measured from the site-binding theory and mass transport method. The surface active sites were measured by amine titration method and Hammett indicator method. The interfacial properties at alumina/KCl(aq) interface were measured by potentiometric titration. From the experimental results, the following results were obtained. Pure ${\gamma}-alumina$ surface acidity decreases with the increase of calcination temperature at strength $H_o{\leq}+9.3$ Surface-treated alumina acidic properties increase with the anion loading on alumina surface. The surface ionization constants decrease with anion loading on alumina surface, then P. Z. C. decreases with acid amount on alumina surface. Acid amount of surface treated alumina can be correlated with surface charge density at strength $H_o{\leq}+4.8$ as follows. $SO_4^2-/Al_2O_3:Q_A=-0.172ln(0.0418{\sigma}+1.448)$ $NO_3^-/Al_2O_3:Q_A=-0.024{\sigma}-0.0189$ $Cl^-/Al_2O_3:Q_A=-0.01{\sigma}-0.2006$.

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Analysis of the Ionized Fields around HVDC Transmission Line by the Use of the Charge Simulation Method (전하중첩법을 이용한 직류 송전선 주변 이온장 해석)

  • Min Suk-Won;Song Ki-Hyun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.6 no.6
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    • pp.478-485
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    • 2005
  • This paper analysed the ionized fields around HVDC transmission line by the use of the charge simulation method. As this is very complex and expressed by a non-linear partial differential equations, it is hard to solve problems analytically. So, we developed a computer program which can apply in multi-polar HVDC transmission line with conductor bundles and calculated conductor surface gradient, corona current density and ion charge density to prove validity of a proposed algorithm in this paper.

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Preparation and Photo Conducting Characteristics of Plasma Polymerized Organic Photorecepter (플라즈마 중합법에 의한 유기 감광체 박막의 제조와 광전도 특성)

  • 박구범
    • Journal of the Korean Institute of Telematics and Electronics T
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    • v.36T no.3
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    • pp.19-25
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    • 1999
  • The photoreceptor films with double layer structure were prepared by the plasma polymerization and the dip-coating method. The blocking layer was coated with A1$_2$O$_3$ on the Al substrate and the charge generation layer was formed by H$_2$ phthalocyanine (H$_2$Pc). Poly 9-Vinylcarbazole was used as a charge transport layer. H$_2$Pc film prepared by the vacuum evaporation had absorption peaks on 613.6[nm] and 694.8[nm], and H$_2$Pc film prepared by the plasma polymerization had a dull peaks between 600 and 700[nm]. The surface potential of PVCz increased with increasing the applied voltage and the thickness of PVCz. The dark decay characteristic, the light decay time and the residual time increased with increasing the thickness of PVCz. The surface charge of PVCz of 15[${\mu}{\textrm}{m}$] thickness was 134[nc/$\textrm{cm}^2$] at the surface potential of -600[V] and the charge generation efficiency of H$_2$Pc was 0.034.

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Carrier density and mobility modification of CVD graphene by plasma treatments (플라즈마 처리에 따른 CVD 그래핀의 전하 농도 및 이동도 변화에 관한 연구)

  • Choe, Min-Seop;Mun, In-Yong;Im, Yeong-Dae;A, Seung-Hwan;Yu, Won-Jong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2012.05a
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    • pp.214-214
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    • 2012
  • 화학기상증착법을 통해 대면적 합성이 가능해진 그래핀의 개발로 인해 그래핀에 관한 연구가 활발히 진행되었다. 특히, 플라즈마 처리에 관한 연구를 통해 그래핀의 도핑이 가능하다는 것이 밝혀졌고 이는 곧 그래핀 내의 전하 농도를 변화시킬 것으로 예상된다. 따라서 본 연구에서는 Van der Pauw 방법을 통해 플라즈마 처리에 따른 그래핀 내의 전하 농도와 면저항을 측정하고 이를 통해 이동도를 계산하는 실험을 진행하였다.

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Comparison of the Ion Adsorption Method, Potentiometric Titraion and Backtitration Technique for Surface Charge measurement in Ultisol, Alfisol, and Inceptisol (Ultisol과 Alfisol 및 Inceptisol 토양에서 토양표면전하 측정에 사용된 이온흡착법, 전위차 적정법 및 역적정법간의 비교)

  • Lee, Sang-Eun;Neue, Heins Ulitz;Park, Jun-Kyu;Lim, Sookil H.
    • Korean Journal of Soil Science and Fertilizer
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    • v.26 no.3
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    • pp.160-171
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    • 1993
  • Surface charge characteristics of Ultisol(Luisiana soil from Philippines), Alfisol(Maahas soil from Philippines), and Inceptisol(Yongii soil from Korea) were studied by way of potentiometric titration, backtitration technique, and ion adsorption method(or CEC - AEC method). The PZNC(point of zero net charge) values determined by ion adsorption method were much lower than the natural pHs in all soils, indicating that all soil samples bore net negative surface charge. The PZSE (point of zero salt effect) values determined by potentiometric titration and backtitration technique were identical in Luisiana and Yongii soils but not in Maaghas soil. All soils showed higher PZSE values than PZNC values probably due to the influence of permanent negative charge. The permanent charge calculated by the theory of Uehara and Gillman (1980) occupied quite low portion of the CEC measured at pH 7 in all soils. Backtitration technique corrected errors of potentiometric titration at extreme pH. However, it still overestimate the surface charge compared with ion adsorption method. Therefore, the ion adsorption method was recommanded for the surface charge measurement of the usual soils which have high negative charge components.

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Electrochemical Impedance Spectroscopy (EIS) study of the Corrosion Resistance of Zn-Mg coatings with 6.72wt.% Mg contents (6.72wt.% Mg 함량을 갖는 Zn-Mg 박막의 침지 시간에 따른 전기화학적 임피던스 분광법 (EIS) 연구)

  • Bae, Gi-Tae;Ra, Jeong-Hyeon;Lee, Sang-Yul
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2015.05a
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    • pp.174-174
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    • 2015
  • 아연 도금 강판은 우수한 내식성으로 인해 널리 사용되고 있지만 최근 아연의 자원 고갈 및 지속적인 가격 상승문제로 인해 아연의 사용량을 줄이기 위한 연구 들이 진행 중이다. 최근 마그네슘이 첨가 된 아연 박막이 기존 아연 도금 강판에 비해 우수한 내식성을 갖는 결과들이 보고 된 바 있다. 본 연구에서는 비대칭 마그네트론 스퍼터링 방식을 활용해 합성된 Zn-Mg 박막을 전기화학적 임피던스 분광법 (EIS)을 통해 침지시간에 따른 전하이동저항의 변화를 분석하였다. EIS와 XRD 분석 결과에서 Zn-Mg 박막이 부식되면서 형성되는 안정한 simonkolleite 상이 전하이동저항의 증가에 큰 영향을 미치는 것으로 판단된다.

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