• Proceedings of the Korean Vacuum Society Conference
• /
• 2015.08a
• /
• pp.238.1-238.1
• /
• 2015

2차원 탄소나노재료인 그래핀은 본연의 우수한 물성으로 인하여 전자소자, 에너지 저장매체, 유연성 전도막 등 다양한 분야로의 응용가능성이 제기되었다. 그러나 실제적인 응용을 위해서는 그래핀의 구조적인 결함을 최소화하며, 특성을 자유로이 제어하거나 향상시키는 공정의 개발이 필요하다. 일반적으로 화학적 도핑은 그래핀의 전기적 특성을 제어하는 효율적인 방법으로 알려져 있다. 화학적 도핑의 방법으로는 그래핀을 특정 가스 분위기에서 고온 열처리하거나 활성종들이 존재하는 플라즈마에 노출시킴으로써, 그래핀을 구성하는 탄소원자를 이종원자로 치환하거나 표면에 흡착시켜 기능화 된 그래핀을 얻는 방법 등이 제시되었다. 특히 플라즈마를 이용한 도핑방법은 저온에서 단시간의 처리로 효율적인 도핑이 가능하고, 인가전력, 처리시간 등의 플라즈마 변수를 변경하여 도핑정도를 수월하게 제어할 수 있다는 장점을 가지고 있다. 그러나 플라즈마 내에 존재하는 극성을 띄는 다양한 활성종들로 인하여 그래핀에 구조적인 결함을 형성하여 오히려 특성이 저하될 수 있어 이를 고려한 플라즈마 공정조건의 설정이 필수적이다. 따라서 본 연구에서는 플라즈마에 노출된 그래핀의 Raman 특성을 고찰함으로써 화학적 도핑과 구조적인 결함의 경계를 확립하고 구조결함의 형성을 최소화한 효율적인 도핑조건을 도출하였다. 고품질 그래핀은 물리적 박리법을 이용하여 300 nm 두께의 실리콘 산화막이 존재하는 실리콘 웨이퍼 위에 제작하였으며, 평행 평판형 직류 플라즈마 장치를 이용하여 전극의 위치, 인가전력, 처리시간을 변수로 암모니아(NH3) 플라즈마를 방전하여 그래핀의 Raman 특성변화를 관찰하였다. 그래핀의 구조적 결함 및 도핑은 라만 스펙트럼의 D, G, D', 2D밴드의 강도비와 G밴드의 위치와 반치폭(Full width at half maximum; FWHM)의 변화를 통해 확인하였다. 그 결과, 인가전력과 처리시간이 증가함에 따라 그래핀의 도핑레벨이 증가되고, 이후에는 도핑효과가 없어지고 결함의 정도가 상승하는 천이구역이 존재하며, 이를 넘어서는 너무 높은 인가적력의 처리는 그래핀에 결함을 형성하여 구조적인 붕괴를 야기함을 확인하였다.

• Journal of Navigation and Port Research
• /
• v.31 no.8
• /
• pp.683-687
• /
• 2007

Hydroelastic deformation of pontoon type floating structure in waves is critical in structural design. Therefore, it is necessary to develop additional technology that make to dissipate the wave energy as the submerged horizontal plate. In this study, we investigate the characteristics of hydrodynamic interaction effect by the submerged plate affecting to the radiation forces on a pontoon type floating structure using numerical analysis. We have developed the numerical method based on the composite grid system that consists of moving and fixed grid to compute the radiation forces due to the heaving motion of pontoon type floating structure and submerged plate. The numerical simulations based on the finite difference method are carried out to solve the fully nonlinear free surface involving the breaking waves and compared with the experimental data to confirm the reliability of the numerical method. Then, we discuss the interaction effects on the hydrodynamic forces that could influence on the hydroelastic response of floating structure.

• KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
• /
• v.4 no.2
• /
• pp.24-32
• /
• 1998

This study examined the effects of recycling on chemical pulp fibers from multiple recycles. Firstly, water-pretreated alkaline photocopy paper was disintegrated by TAPPI standard disintegrator at room temperature. After dewatering, this pulp was dried in oven at $80^{\circ}C$ for 24hrs. A sequence of wetting, disintegrating and drying was one recycling cycle and this cyclic treatment was repeated from zero to five times. The recycled handsheet dropped to 90% of the original brightness after five cycles, and lost the most brightness in the first two cycles. However, it had a gain of 10% in opacity after five cycles. And, in this study, the method for determining residual ink(toner) content in recycled handsheets were estabilished by means of SEM-EDX and atomic absorptive photometer. The change of residual ink percentage on recycled paper showed the effect of recycling numbers on deinkability of waste paper. A slight decrease in deinkability was noted for the recycled handsheets, which may be due to the change of fiber surface free energy connected with fiber swelling.

• Journal of Korean Society of Coastal and Ocean Engineers
• /
• v.19 no.5
• /
• pp.484-491
• /
• 2007

Numerical experiments using a numerical wave tank have been performed to verier the nonlinear interaction between monochromatic waves and a submerged horizontal plate. As a model for numerical wave tank, we used a higher-order Boundary Element Method(BEM) based on fully nonlinear potential flow theory and CADMAS-SURF for solving Navier Stokes equations and exact free surface conditions. Both nonlinear models are able to predict the higher harmonic generation in the shallow water region over a submerged horizontal plate. CADMAS-SURF, which involves the viscous effect, can evaluate the higher harmonic generation by flow separation and vortices at the each ends of plate. The comparison of reflection and transmission coefficients with experimental results(Patarapanich and Cheong, 1989) at different lengths and submergence depths of a horizontal plate are presented with a good agreement. It is found that the transfer of energy from the incident fundamental waves to higher harmonics becomes larger as the submergence depth ratio decreases and the length ratio increases.

• Journal of the Korean Electrochemical Society
• /
• v.2 no.1
• /
• pp.23-26
• /
• 1999

The Langmuir adsorption isotherm at the $(Pt)/0.1M\;H_2SO_4$ electrolyte interface has been qualitatively analyzed using the ac impedance measurement and phase-shift method. The phase shift $(\phi)$ depends on both the cathode potential (E<0) and frequency (f) and is inversely proportional to the factional surface coverage $(\theta)$. At an intermediate frequency band (ca. $1\~100$ Hz), the phase-shift profile $(\phi\;vs.\;E)$ can be related to the fractional surface coverage $(\theta\;vs.\;E)$. The phase-shift profile $(\phi\;vs.\;E)$ can be used as an experimental method to estimate and analyze the Langmuir adsorption isotherm $(\theta\;vs.\;E)$. The equilibrium constant (K) and the standard free energy $({\Delta}G_{ads})$ of the adsorbed hydrogen atom $(H_{ads})\;and\;3\times10^{-4}$ and 20.1 kJ/mol, respectively.

• Journal of the Computational Structural Engineering Institute of Korea
• /
• v.16 no.1
• /
• pp.95-104
• /
• 2003

This paper deals with the analytic and FEM analyses of sloshing frequency response of incompressible, invicid and irrotational flow in two dimensional rectangular tank. We use Laplace equation based on potential theory as governing equation. For small amplitude sloshing motion, the linearized free surface condition was applied and the analytic solution as obtained by the separation of variables. To simulate the effect of the energy dissipation due to viscous damping, artificial viscous coefficient is introduced and the divergence of response at resonance frequencies may be avoided by this coefficient. This problem was solved by FEM using 9-node elements in order to predict the maximum amplitude of sloshing response. Numerical results of free surface height, fluid pressure and fluid force show good agreement with those by analytic solution. After verifying the test FEM program, we analyze the frequency response characteristics of sloshing to the fluid height.

• Applied Chemistry for Engineering
• /
• v.27 no.2
• /
• pp.199-204
• /
• 2016

The adsorption of Rhodamine-B dye using granular activated carbon from aqueous solution was investigated. Adsorption experiments were carried out as a function of the adsorbent dose, pH initial concentration, contact time and temperature. The equilibrium adsorption data showed a good fit to Langmuir isotherm model. Based on the estimated Langmuir separation factor ($R_L$ = 0.0164~0.0314), our adsorption process could be employed as an effective treatment method. The kinetics of adsorption followed the pseudo first order model. Also, the negative values of Gibbs free energy (-4.51~-13.44 kJ/mol) and positive enthalpy (128.97 kJ/mol) indicated that the adsorption was spontaneous and endothermic process. The isosteric heat of adsorption increased with increase in the surface loading indicating lateral interactions between the adsorbed dye molecules.

• Elastomers and Composites
• /
• v.39 no.3
• /
• pp.234-243
• /
• 2004

The elastomeric and conductive polyurethane (PU) films were prepared by poly(propylene glycol) (PPG), toluene 2,4-diisocyanate, 3-methylthiophene (3-MT) at various preparation conditions, such as the reaction time, the $FeCl_3$ concentration, the weight ratio of the 3-MT to PU and the reaction temperature for the diffusion-oxidative reaction. The conductive poly (3-methylthiophene) (PMT) layers via the diffusion-oxidative reaction of 3-MT and ferric chloride were formed by immersing the film in organic solution of $FeCl_3$/ethyl acetate. The preparation conditions greatly affected the electrical conductivity of the 3-MT/PU composite. The effects of the reaction time and temperature on morphology and surface free energy were investigated by scanning electron microscopy (SEM) analysis and contact angle measurement, respectively. The conductivity of the composite was as high as 42 S/cm.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2008.11a
• /
• pp.385-388
• /
• 2008

Recycled fine aggregate has low quality because it contains large amount of old mortar. So, its usage is limited to a lower value-add, such as the roadbed material etc. Also, alkaline water occurred from treatment process of the waste concrete is becoming the cause of environmental problem. Accordingly, this study is to develop on the high quality recycled fine aggregate produced by low speed wet abraser using sulphuric. We investigated the properties of compressive strength of the mortar which was manufactured using recycled fine aggregate containing calcined gypsum produced by earlier mentioned process. Test results indicate that concrete using recycled fine aggregate containing calcined gypsum is higher compressive strength than concrete using other sands.

• Journal of the Korean Electrochemical Society
• /
• v.4 no.1
• /
• pp.14-20
• /
• 2001

The Langmuir adsorption isotherms of the under-potentially deposited hydrogen (UPD H) and the over-potentially deposited hydrogen (OPD H) at the single crystal Pt(100)/0.5 M $H_2SO_4$ and 0.5 M LiOH aqueous electrolyte interfaces have been studied using the phase-shift method. The phase-shift profile $({-\varphi}\;vs.\;E)$ for the optimum intermediate frequency can be used as a useful method to estimate the Langmuir adsorption isotherm $(\theta\;vs.\;E)$ at the interfaces. The equilibrium constant (K) for the OPD H and the standard free energy $({\Delta}G_{ads})$ of the OPD H at the Pt(100)/0.5M $H_2SO_4$ aqueous electrolyte interface are $1.5\times10^{-4}$ and 21.8 kJ/mol, respectively. At the Pt(100)/0.5 LiOH aqueous electrolyte interface, K transits from 1.9(UPD H) to $6.8\times10^{-6}$(OPD H) depending on the cathode potential (E) and vice versa. Similarly, ${\Delta}G_{ads}$ transits -1.6 kJ/mol (UPD H) to 29.5 kJ/mol (OPD H) depending on E and vice versa. The transition of K and ${\Delta}G_{ads}$ is attributed to the two distinct adsorption sites of the UPD H and OPD H on the Pt(100) surface. The UPD H and the OPD H at the Pt(100) interfaces are the independent processes depending on the H adsorption sites rather than the sequential processes for the cathodic $H_2$ evolution reactions.