• Title/Summary/Keyword: 표면 연소

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Effect of La and Si Addition on Thermal Stabilization of Alumina (La 및 Si 첨가에 의한 알루미나의 열안정화 효과)

  • Lee, Chae-Hyun;Lim, Dae-Young;Kim, Jong-Ock;Seo, Doo-Won;Han, Moon-Hee
    • The Journal of Engineering Research
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    • v.3 no.1
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    • pp.215-222
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    • 1998
  • The effect of La and Si addition of the thermal stabilization of $\gamma-alumina$ powers have been studied. Reagent grade $La(NO_3)_3{\cdot}6H_2O$ and $Si(OC_2H_5)_4$ were used as starting materials. These additives were introduced by wet impregnation method. Both La and Si additives suppressed the sintering of alumina and were found to be good thermal stabilizers of $\gamma-alumina$. Especially, Si drastically suppressed the phase transition of alumina at high temperatures. The major mechanisms for the thermal stabilization of alumina were seemed to be new phase formation and retardation of surface diffusion by addition of La or Si into alumina matrix.

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Preparation of NaX Zeolite Coated Honeycomb Adsorbents and It's Carbon Dioxide Adsorption Characteristics (NaX 제올라이트가 담지된 허니컴 흡착제의 제조 및 이의 이산화탄소 흡착특성)

  • Yoo, Yoon-Jong;Kim, Hong-Soo;Singh, Ranjeet;Xiao, Penny;Webley, Paul A.;Chaffee, Alan L.
    • Applied Chemistry for Engineering
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    • v.20 no.6
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    • pp.663-669
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    • 2009
  • The honeycomb adsorbent was prepared for adsorbing and seadsorbent was prepared by using zeolite sheet, which contained zeolite as component. The steady-state adsorption properties and surface morphologies were analyzed and breakthrough characteristics were ananlyzed by providing 16% carbon dioxide mixed gas. By thermal regeneration, carbon dioxide concentration properties were analyzed, and the adsorptive separation process was compared between thermal swing adsorption and pressure swing adsorption after adsorbent temperature change during heating. The breakthrough results of the honeycomb showed possibility parating carbon dioxide from combustion exhaust gas, which had deep impact on climate change, and the characteristics of the adsorbent were studied. Na-X zeolite was coated on a honeycomb prepared with ceramic sheet or active carbon sheet so that the two honycomb can be used at high temperature. Third honeycomb of rotary adsorptive concentration process.

Fabrication of thick film type catalytic combustible gas sensor using parallel resistance heat source (병열형가열부를 이용한 후막형 접촉연소식 가스센서 제조)

  • Park, Jun-Sik;Lee, Jae-Suk;Hong, Sung-Jei;Park, Hyo-Derk;Shin, Sang-Mo
    • Journal of Sensor Science and Technology
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    • v.5 no.1
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    • pp.23-29
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    • 1996
  • Thick film type gas sensors with parallel Pt heaters were fabricated by screen printing process and investigated sensitivities for methane gas. The TR7905 was selected as Pt paste for heater by characterization the properties of TCRs and thick film microstructures. The average resistance of parallel Pt heaters was $1.8{\Omega}$, and the best TCR obtained was $3685\;ppm/^{\circ}C$. On the top of the Pt heaters, a sensing layer added with Pt and Pd as catalyst paste was screen printed and heat treated. The sensitivity of the sensor was 4.3mV/1000ppm for methane. The power consumption of the sensors was 2.12watts.

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Flame Retardant and Heat Radiating Composite Consisting of Polyurethane and Modified Boron Nitride (폴리우레탄과 개질된 질화붕소로 이루어진 난연성 방열 복합체)

  • Kim, Min-gyu;Lee, Chang-rock;Jo, Nam-Ju
    • Applied Chemistry for Engineering
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    • v.31 no.5
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    • pp.487-494
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    • 2020
  • Polyurethane/modified boron nitride (PU/m-BN) composite was synthesized from the poly(tetra methylene glycol) (PTMG), 4,4'-methylenebis(phenyl isocyanate) (MDI), and modified boron nitride (m-BN). The modification of boron nitride and synthesis of PU/m-BN composite were confirmed by Fourier transform infrared (FT-IR) spectroscopic analyses. The mechanical properties of the PU/m-BN composites were measured using the universal testing machine (UTM) and the thermal properties of the composites were investigated ser flash analysis (LFA) and UL94 measurements. As a result, the thermal conductivity of the polyurethane composite increased to 1.19 W/m·K, and the flame retardancy of the easy to burn polyurethane, which was not self-extinguishing was improved to UL94 V-1 grade.

Thermal Stabilization of Alumina by Ba Addition (Ba 첨가에 의한 알루미나의 열 안정화 효과)

  • Seo, Doo-Won;Han, Moon-Hee;Lee, Chae-Hyun
    • The Journal of Engineering Research
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    • v.2 no.1
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    • pp.139-145
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    • 1997
  • The effect of Ba addition on the thermal stabilization of $\gamma$-$Al_2O_3$ powders were studied. Ba additive was introduced into $\gamma$-$Al_2O_3$ powders by wet impregnation of $Ba(No_3)_3$.$6H_2O$. Ba additive was proved to be effective on the thermal stabilization of $\gamma$-$Al_2O_3$ powders by suppression of sintering. The optimum content of Ba was determined by 5 mol%, through the calcinations temperature range. It is suggested that the main reason of thermal stabilizaton is the substitution effect of large $Ba^{2+}$ ions into the $\Al^{3+}$ sites, which suppressed the surface diffusion of $\Al^{3+}$ ions.

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Evaluation of Gap Heat Transfer Model in ELESTRES for CANDU Fuel Element Under Normal Operating Conditions (CANDU형 핵연료봉의 정상상태 계산용 ELESTRES 코드내 간극 열전달 모델 평가)

  • Lee, Kang-Moon;Ohn, Myung-Yong;Lim, Hong-Sik;Park, Jong-Ho;Hwang, Son-Tae
    • Nuclear Engineering and Technology
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    • v.27 no.3
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    • pp.344-357
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    • 1995
  • The gap conductance between the fuel and the sheath depends strongly on the gap width and has a significant influence on the amount of initial stored energy. The modified Ross and Stoute gap conductance model in ELESTRES is based on a simplified thermal deformation model for steady-state fuel temperature calculations. A review on a series of experiments reveals that fuel pellets crack relocate, and are eccentrically positioned within the sheath rather than solid concentric cylinders. In this paper, the hue recently-proposed gap conductance models (offset gap model and relocated gap model) are described and are applied to calculate the fuel-sheath gap conductances under experimental conditions and normal operating conditions in CANDU reactors. The good agreement between the experimentally-inferred and calculated gap conductance values demonstrates that the modified Ross and Stoute model was implemented correctly in ELESTRES. The predictions of the modified Ross and Stoute model provide conservative values for gap heat transfer and fuel surface temperature compared to the offset gap and relocated gap models for a limiting power envelope.

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A Study on the Fire Risk Assessment and Prevention in the Recycling Process of Used Refrigerators (냉장고 파쇄 공정에서의 화재 위험성 및 예방에 관한 연구)

  • Lee, Su-Kyung;Song, Dong-Woo;Bae, Jeong-Ae
    • Fire Science and Engineering
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    • v.23 no.5
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    • pp.72-77
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    • 2009
  • In the recycling procedure of the refrigerator, the fire frequently breaks out. In this study, to clarify the exact cause of the fire, the components and concentration of the materials produced in the process are analysed as well as the problems in the process system, and the protective measure to prevent the fire and the explosion fundamentally is proposed. In this procedure, the preventive measures of fire by removing the combustible materials such as polyurethane and inflammable gases, by removing the ignition sources and by reducing the oxygen concentration to the minimum are proposed along with the protective measures to reduce the damage in the fire. In the crushing procedure where the fire or explosion can break out in diverse ways, the forced ventilation or exhaust system applied to the small partial ventilation facility are installed to reduce the concentration of inflammable gas mixture to lower than the inflammable limit by injecting and exhausting the air forcibly.

Risk Assessment of Fire and Explosion of Methane (메탄의 화재 및 폭발 위험성 평가)

  • Ha Dong-Myeong
    • Journal of the Korean Institute of Gas
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    • v.9 no.2 s.27
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    • pp.1-7
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    • 2005
  • The thermochemical parameters for safe handling, storage, transport, operation and process design of flammable substances are explosive limit, flash point, autoignition temperature, minimum oxygen concentration, heat of combustion etc.. Explosive limit and autoignition temperature are the major physical properties used to determine the fire and explosion hazards of the flammable substances. Explosive limit and autoignition temperature of methane fur LNG process safety were investigated. By using the literatures data, the lower and upper explosive limits of methane recommended 4.8 vol$\%$ and 16 vol$\%$, respectively. Also autoignition temperatures of methane with ignition sources recommended $540^{\circ}C$ at the electrically heated cruicible furnace (the whole surface heating) and recommended about $1000^{\circ}C$ in the local hot surface. The new equations for predicting the temperature dependence and the pressure dependence of the lower explosive limits for methane are proposed. The values calculated by the proposed equations were a good agreement with the literature data.

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Influences of the Surface Pollution Cause by the Marine Growth on Ship Hulls on Engine Performance and Output (선체 해양생물의 선저오염이 엔진성능과 출력에 미치는 영향)

  • Jung, Kyun-Sik
    • Journal of Advanced Marine Engineering and Technology
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    • v.39 no.4
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    • pp.399-404
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    • 2015
  • The cost of fuel in ships has recently increased due to a rapid increase in international oil prices and international restrictions regarding the greenhouse effect generated from the burning of fuel. Therefore, different methods for changing the hull designs for improving energy efficiency, developing coating for reducing friction resistances, developing additives for improving engine thermal efficiency, and low-speed operation for reducing fuel consumption have been considered. The developments of high-speed, large-scale, and energy-saving vessels are deemed essential to adapt to the recent high oil price era. Therefore, it is important to analyze Precisely the qualitative and quantitative changes in the resistance value of the local areas of the hull surface. In this study, the engine performance before and after docking was analyzed to examine friction resistance caused by marine growth on the hull as a basic study for improving the energy efficiency. The result was then presented by comparing it with the previous data for 2.5 years between docks to investigate the performance of the main engine, the change in friction resistances and loads, the fuel consumption and ship speed.

Heat Transfer on Slot Film Cooling for Convergent Nozzle (축소노즐내 슬롯 막냉각에서의 열전달 특성)

  • 조용일;유만선;정학재;조형희
    • Journal of the Korean Society of Propulsion Engineers
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    • v.5 no.1
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    • pp.34-41
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    • 2001
  • A study has been conducted to observe the slot film cooling effect on a convergent nozzle wall. The slot film cooling is used to protect the nozzle wall from the hot combusted gas by the coolant injected from the slot around the inner wall of the nozzle. The film cooling effectiveness and the heat transfer to the nozzle wall are influenced significantly by the blowing ratio of the coolant to the main flow and those are also influenced by the shape of the slot and the flow acceleration in the nozzle. In the present study, the heat transfer for the various blowing ratios has been performed by the experimental method and the results are compared with the results computed by the empirical formula. The numerical method has been conducted to compare the film cooling effectiveness of the convergent nozzle with that of the cylinder. For the relatively low blowing ratio, the cooling effectiveness increases sharply as the blowing ratio increases, and the increasing rate slows down for the high blowing ratio.

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