• Title/Summary/Keyword: 표면 습윤성

Search Result 91, Processing Time 0.033 seconds

핵융합로 디버터의 대면물질로 사용될 텅스텐의 상압열플라즈마 용사 코팅 공정 최적화 및 코팅질 향상을 위한 해석적 연구

  • Jin, Yeong-Gil
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2010.08a
    • /
    • pp.249-249
    • /
    • 2010
  • 핵융합로에서는 디버터의 열부하에 대한 안전성을 고려하기 위해 열전도도 및 열 저항성이 높은 텅스텐이 대면 물질로 고려되고 있으며, 경제적인 측면과 실용성 측면에서 텅스텐블록을 직접 제작하여 사용하는 것보다 텅스텐코팅이 효과적이라는 의견이 지배적이다. 또한 ASDEX Upgrade 에서는 탄소블럭에 텅스텐을 코팅하여 챔버 외벽 및 디버터 영역까지 구성하여 캠페인을 진행하였고, 재료적인 측면에서 안정성을 확인 하였다. 따라서 본 연구에서는 디버터 및 챔버외벽 등에 대한 대면물질을 구성하기 위해 상압 열플라즈마 제트를 이용하여 고온에서의 용융 및 냉각을 통해 모재에 텅스텐 피막을 적층하는 과정을 수행하고 있다. 기존의 연구를 통해 일부 공정 변수에 대해서는 이미 적정한 범위의 공정조건을 확보하였고, 기공도와 산화도 및 부착력 등의 물성치에 대한 추가적인 향상을 위해 주요 공정 변수에 집중하여 최적의 조건을 탐색하는 과정이 진행 중이다. 이를 위해 출력증가실험의 일환으로서 기존 36kW급 플라즈마 토치 전력을 한 단계 끌어 올려 48kW급 전력까지 단계적으로 상승시킴으로써 이에 따른 물성치 변화를 검증하고 있다. 현재 44kW 급까지 실험이 수행되었으며, 이를 통해 공극률 감소 및 미세구조 변화에 대한 결과를 얻었다. 실제로 토치의 출력을 증가시킴으로서 텅스텐 피막의 물성치가 변화하는 메커니즘은 플라즈마 제트의 중심부 온도 및 축방향 속도에 의해 결정된다. 중심부 온도가 상승하게 될수록 코팅을 위해 분사되는 분말의 용융률은 증가하지만 분말 외벽에 산화텅스텐이 형성될 가능성은 증가하게 되며, 플라즈마 제트의 모재를 향상 축방향 속도가 증가할수록 용융 된 분말이 모재에 증착 시 형성하는 형태가 원형에 가깝게 되므로 기공이 감소하는 효과가 발생한다. 특히 용융된 분말의 증착 형태는 모재의 온도 및 분말의 입사속도에 결정적이 영향을 받게 되며, 결국 모재와 분말사이의 습윤성에 의한 분말 분산속도가 분말의 입사속도에 버금갈 경우 분말은 모재 위에서 효과적으로 원형으로 전이하며 적층하게 된다. 이러한 전이 현상은 앞에서 언급한 모재의 온도 등에 의해 결정적으로 영향을 받게 되며, 모재의 온도가 전이온도 이하일 경우 폭파형태에서 원형으로 분말의 증착 형태가 전이하게 된다. 이외에 추가적으로 진행하고 있는 연구는 코팅 전처리에 해당하는 분말 효과이며, 특히 탄화텅스텐 분말을 통한 재료적 auto-shroud 효과와 미세분말을 이용한 분말 표면열속의 증가에 따른 용융률 증가효과를 연구에 포함할 계획이다. 이러한 연구는 열적, 그리고 재료적 해석을 바탕으로 해석적 접근을 통해 이루어진다.

  • PDF

Effect of Nonionic Surfactant Solutions on Wetting and Absorbency of Polyethylene Terephthalate(PET) Fabrics (Part II) -Surfactants Characteristics and Fabric Properties- (비이온계 계면활성제 수용액이 PET직물의 습윤특성에 미치는 영향 (제2보) -계면활성제와 직물의 특성-)

  • Kim, Chun-Hee
    • Journal of the Korean Society of Clothing and Textiles
    • /
    • v.29 no.12 s.148
    • /
    • pp.1546-1553
    • /
    • 2005
  • The wetting behavior and liquid transport of nonionic surfactant solutions; Span 20 and Tween 20, 40, 60, 80, 21, 61, 81, 65 & 85: in polyethylene terephthalate(PET) fabrics are reported. Five different PET fabrics are used in this study. PET 1, 2 & 3 have different compactness in structure. PET 4 & 5 have similar physical properties to PET 2, however, PET 4 has heat set finish and PET 5 with rewetting agent. The wetting and water retention properties of PET fabrics are greatly improved by addition of nonionic surfactants. The aqueous liquid retention(W) vs. cosq and W vs. adhesion tension has positive linear relationship. Hydrophilic surfactants which have short hydrophobes and surfactants with unsaturated hydrophobe structures are more efffctive in improving the wetting properties of PET fabrics. PET fabric which has larger thread spacing shows greater value of water retention ratio(W/H) than PET fabric with smaller thread spacing if there are no surfactants present in the system, however, W/H values become very similar among these PET fabrics when the surfactants are added. If there are no surfactants present in the system, PET with heat set finish has smaller value and PET with rewetting agent has greater value of W/H than PET without finish even though the fabrics have the similar physical properties.

Distribution of Inorganic N from Fertigated and Broadcast-applied 15N-Urea along Drip Irrigation Domain (점적관수시 관비와 표면시비된 중질소 표지요소의 행동비교)

  • Yoo, Sun-Ho;Jung, Kang-Ho;Ro, Hee-Myong;Choi, Woo-Jung
    • Korean Journal of Soil Science and Fertilizer
    • /
    • v.34 no.4
    • /
    • pp.292-301
    • /
    • 2001
  • The objectives of this study were to measure the changes in soil moisture regimes and the distribution patterns of inorganic N derived from the fertigated $^{15}N$-labeled urea, and compare them with the results obtained from broadcast-applied soil under the same drip irrigation domain. In fertigated soil, a $^{15}N$-labeled urea solution of $117mg\;N\;L^{-1}$ was applied by surface drip irrigation for 4 weeks. In broadcast-applied soil, no the other hand, 4 g of $^{15}N$-labeled urea(1.87 g N) mixed thoroughly with 5 kg of soil was placed on the surface of packed soil. Soil water status was controlled by drip irrigation scheduled at soil matric potential of -50 kPa. A calibrated time-domain reflectometry probe was installed in the soil vertically 15 cm apart from a drip emitter to control drip irrigation. About 60% of urea-derived inorganic nitrogen was remained in the top zone between 0 and 10 cm depth of fertigated soil, while, most of the inorganic nitrogen (91%) was accumulated in the top zone of broadcast-applied soil. Of inorganic nitrogen derived from urea, the percentage of $NO_3{^-}$ was much higher for fertigation (99%) than for surface application (62%). The relatively lower recovery of urea-derived inorganic nitrogen of broadcast-applied urea-N (51%) than that of fertigated urea-N (89%) was attributable to enhanced $NH_3$ volatilization.

  • PDF

Experimental Study on Reducing Effect for Surface Temperature of Recycled Synthetic-Resin Permeable Block (재생 합성수지 투수블록의 표면온도 저감효과에 관한 실험적 연구)

  • Lee, Chul-Hee;Lee, Arum;Shin, Eun-Chul;Ryu, Byung-Hyun
    • Journal of the Korean Geosynthetics Society
    • /
    • v.18 no.1
    • /
    • pp.79-89
    • /
    • 2019
  • The field measurement and laboratory experiment were conducted to investigate the effect of reducing the surface temperature of the functional aspect of the heat island phenomenon of the permeable block which is made the recycled synthetic resin rather than the existing concrete permeable block. Field measurement was taken for 3 days in consideration of dry condition and wet condition and laboratory experiment was divided into dry condition, rainfall simulating condition, and wetting condition. The variations of temperature and the evaporation rate of water moisture content after experiment were confirmed. As a result of field measurement, it is confirmed that the surface temperature decreases due to the difference in albedo of the pore block surface rather than the cooling effect due to the latent heat of vaporization. The evaporation of moisture in a dry state where drought persisted or a certain level of moisture was not maintained in the surface layer. As a result of laboratory experiment, resin permeable block gives higher surface temperature when it is dry condition than concrete permeable block, but the evaporation of water in the pore is kept constant by capillary force in rainfall simulation condition, and higher temperature reduction rate. As a result of measuring the evaporation rate after laboratory experiment, it is confirmed that the effect of reducing temperature is increased as the evaporation rate of water is higher. Based on these results, correlation formula for evaporation rate and temperature reduction rate is derived.

A Numerical Study on the Alignment of Surface Structures on Silicon-germanium Thin Films under a Localized Modulation of Surface Diffusivity (표면확산계수의 국부적 제어를 통한 실리콘-게르마늄 박막상 표면구조물의 정렬에 관한 수치해석적 연구)

  • Kim, Yun Young;Han, Bong Koo
    • Journal of the Computational Structural Engineering Institute of Korea
    • /
    • v.28 no.1
    • /
    • pp.79-83
    • /
    • 2015
  • This paper presents a numerical study on the alignment of ridge-like surface structures evolving on silicon-germanium thin films under localized modulation of surface diffusivity. A situation is considered in which the surface diffusion of film material is selectively promoted such that its morphology is perturbed to periodic patterns. To simulate the growth behavior, a governing equation is formulated taking the surface chemical potential into account, and its solution is numerically sought using a finite-difference method. Results show that an initially planar surface coalesces upon the diffusivity modulation, and the surface structures can be aligned by changing the frequency of modulation condition. This research suggests a bottom-up fabrication technique that can manage the regularity of surface structures for thin film devices.

Characteristics of Bond Strength as Types of Primer for the Facilities of Anti-corrosion Waterproofing Materials by the Reversed Pressure and Concrete Surface Condition (내부 방수⋅방식재의 프라이머 종류별 역수압 작용 및 콘크리트 표면 상태에 따른 부착강도 특성)

  • Oh, Sang-Keun;Heo, Neung-Hoe;Shin, Hong-Chul;Choi, Sung-Min
    • Journal of the Korea institute for structural maintenance and inspection
    • /
    • v.18 no.1
    • /
    • pp.68-74
    • /
    • 2014
  • Recently, concrete facility as advanced water treatment facilities is extending in the water treatment facilities according to raise awareness of pure drinking water and delicious water. For this reason, it is increased to the necessity need to make the standard and the development of waterproofing and anti-corrosion materials for concrete structures applied water treatment tank. So, related research has become active recently. However, as the limit of research focused on durability improvement of top coating material, it is insufficient to study on the adhesion strength between the concrete surface and primer. Therefore, there is to confirm the adhesion of between concrete surface and the three primers used as anti-corrosion waterproofing materials, and to investigate the properties of adhesion strength according to the condition such as dry condition, wet condition, and water pressure condition of the concrete surface in this study.

The Effect of Dimensions of Micro-post on Oleophobic Property (마이크로 기둥 구조의 크기가 소유성 특성 발현에 미치는 영향)

  • Kim, Nam-Kyung;Kim, Hae-Ji
    • Journal of the Korean Society of Manufacturing Process Engineers
    • /
    • v.17 no.5
    • /
    • pp.91-96
    • /
    • 2018
  • The oleophobic property of surfaces modified with micro-post structures are investigated for a range of micro-post diameter ($11-23{\mu}m$) and pitch ($20-40{\mu}m$). The contact angle of an oil droplet on surfaces with various micro-post dimensions was calculated using the Cassie-Baxter model and did not show a good agreement with the measured contact angle. From measurement, the micro-post with diameter of $23{\mu}m$ and pitch of $32{\mu}m$ was found to have the highest contact angle ($134.3^{\circ}$).

Evaluation of friction force varied by non-slip surface patterns of deck (데크의 논슬립가공 표면형태 변이에 따른 마찰성능 변화 평가)

  • Han, Yeonjung;Lee, Ju-Hee;Park, Yonggun;Choi, Yun-Ho;Yeo, Hwanmyeong
    • Journal of the Korean Wood Science and Technology
    • /
    • v.40 no.6
    • /
    • pp.397-405
    • /
    • 2012
  • Installation of deck has been on the rise in Korea recently, but there is little of research on the safety of deck. One of the major factors affecting maneuverability of a pedestrian is frictional force between an outsole of shoe and a surface of the deck. The frictional force is influenced by many factors such as raw material variance of deck, surface convex shape of deck, outsole patterns of shoes, and moist condition of contact surface between deck and shoes. This study focused on evaluating the effect of these factors on the frictional force. Two kinds of deck, which were made of natural wood and wood plastic composite, were used in this study. The surface convex patterns of deck were classified to single nonslip (longitudinal groove processing) and double nonslip (longitudinal and transverse groove processing). Two kinds of shoe outsole patterns, W-shape and rectangle-shape, were used in the tests. Also, the friction tests were carried out at dried surface conditions and water-adsorbed surface condition.

고온압착 건조 처리시 표면처리를 통한 고강도 라이너지 개발

  • 최병수;윤혜정;류정용;신종호;송봉근
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
    • /
    • 2000.11a
    • /
    • pp.63-63
    • /
    • 2000
  • 저급의 고지 원료를 두께 방향으로 고온 압착을 가하여 건조함으로써 전반적인 종이 물성 을 향상시키는 콘디벨트 건조 방식은 70년대 중반부터 80년대에 이르는 10여년에 걸친 개발 과정을 거쳤으며 90년대에 들어서 핀랜드의 Inkeroinen에 위치한 V alemt- Tarnpella의 연구 소에 최초의 파일로트 설비가 설치되었으며 그 후 1996년에는 핀랜드 ENSO사의 P Pank밟oski 판지공장에 설치됨으로써 세계 최초의 상업생산설비를 이루게 되었다. 기존의 실린더 건조 기술과 비교할 때 콘디벨트 건조방식은 건조속도를 약 5-15배 향상시킬 수 있 으며, 건조 에너지 절감에 큰 효과가 있을 뿐만 아니라 기존의 실린더 건조시 종이가 폭방 향으로 수축되 어 인장 stiffness와 압축 강도 동의 종이 물성 이 저 하되 는 반면 습윤상태 의 섬유를 120도씨이상에서 가열에 의해 리그닌을 연화시킴과 동시에 섬유의 유연성을 증가시켜 준다. 그리고 높은 압력을 가해줌으로써 섬유간의 결합 면적을 증가시키고 건조시 종이의 폭방향의 수축을 감소시켜 인장강도, 내부결합강도, 밀도, 표면평활성, 투기저항성 등 종이의 물성을 대폭 향상시켜주는 혁신적인 제지기술로 인정받고 있으며 국내의 경우 현재 1998년 부터 상업생산을 이루어짐으로써 그 공헌도는 매우 크다고 할 수 있다. 골판지의 주원료가 되는 국산 골판지 고지 (Korean old corrugated container, K KOCC)의 거듭된 재생처리로 인하여 미세분의 함량이 전체 지료의 절반 이상에 달할 뿐만 아니라, 섬유가 각질화와 단섬유화로 인하여 고온압착 건조처리 만으로는 골판지 고지로 생 산된 원지의 강도를 버진펄프로 생산된 원지가 가지는 강도에 준하는 강도로 향상시키는데 한계점을 가지게 된다. 유럽의 제지선진국들은 골판지 원지의 강도를 향상시키는 방편으로 표변에 전분 사이즈 프레스 처리를 도입하였으며 본 연구에서는 고온 압착 건조 처리 설비를 활용한 전분 표면처리의 가능성을 검토하고 골판지 원지의 강도를 향상시키기 위한 표면처리조건을 탐색하였다.

  • PDF

Effect of the Structure of the Smallest Poresize Layer on the Permeability of PES Microfiltration Membranes (최소 기공층 구조가 PES계 정밀여과막 투과 성능에 미치는 영향)

  • Kim, No-Won
    • Membrane Journal
    • /
    • v.19 no.1
    • /
    • pp.25-33
    • /
    • 2009
  • PES (polyethersulfone) membranes with highly enhanced their asymmetry were prepared by phase inversion process. The membranes were prepared by using PES/DMF (N,N-dimethylformamide)/TSA (p-toluenesulfonic acid)/PVP (polyvinylpyrrolidone) casting solution and water coagulant. The pre-coagulation of membrane surface which was induced by an addition of TSA as a demixing agent and PVP as a swelling polymer in the PES solution and humid exposure time, played a crucial role in determining morphological properties and the PWP (pure water permeation) performance. The PES solution was coated on polyester film under condition of 80% humidity for a while ($72{\sim}144$ sec) before immersing in a coagulation bath. The characterization of membranes was carried out by a capillary flow porometer, a FE-SEM and a permeation test apparatus. As the thickness of the smallest pore size layer (SPL) decreased, the asymmetry of membrane increased under conditions of 20 wt% of TSA and 10 wt% of PVP in 11 wt% of PES solution during longer humid contact time. As a result, the membranes showed a remarkable increase of PWP.