• Journal of the Korean Geotechnical Society
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• v.22 no.8
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• pp.119-127
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• 2006

Granulated Blast Furnace Slag (GBFS) is produced in the manufacture process of pig-iron and shows a similar particle formation to that of natural sea sand and also shows light weight, high shear strength, well permeability, and especially has a latent hydraulic property by which GBFS is solidified with time. Therefore, when GBFS is used as a backfill material of quay or retaining walls, the increase of shear strength induced by the hardening is presumed to reduce the earth pressure and consequently the construction cost of harbor structures decreases. In this study, using the model sand box (50 cm$\times$50 cm$\times$100 cm), the model wall tests were carried out on GBFS and Toyoura standard sand, in which the resultant earth pressure, a wall friction and the earth pressure distribution at the movable wall surface were measured. In the tests, the relative density was set as Dr=25, 55 and 70% and the wall was rotated at the bottom to the active earth pressure side and followed by the passive side. The maximum horizontal displacement at the top of the wall was set as ${\pm}2mm$. By these model test results, it is clarified that the resultant earth pressure obtained by using GBFS is smaller than that of Toyoura sand, especially in the active-earth pressure.

• Applied Chemistry for Engineering
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• v.34 no.3
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• pp.264-271
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• 2023

In this study, ASCO^Ⓡ SLES-430 surfactant was synthesized by adducting 3 moles of ethylene oxide and 1 mole of propylene oxide to lauryl alcohol followed by a sulfation process, and the structure of the synthesized ASCO^Ⓡ SLES-430 was elucidated by performing FT-IR, ¹H-NMR and ¹³C-NMR analyses. Interfacial properties such as critical micelle concentration, static surface tension, emulsification index, and contact angle were measured, and environmental compatibility indices such as oral toxicity and skin irritation were also estimated for ASCO^Ⓡ SLES-430. Both results were compared with ASCO^Ⓡ SLES-226 and ASCO^Ⓡ SLES-328 SLES surfactants possessing 2 moles and 3 moles of ethylene oxide, respectively. In particular, both foaming ability and foam stability were evaluated for ASCO^Ⓡ SLES-430 and compared with ASCO^Ⓡ SLES-226 and ASCO^Ⓡ SLES-328, which have been widely used in detergent products, in order to test the potential applicability of ASCO^Ⓡ SLES-430 in detergent product formulation for a small capacity built-in washing machine.

• Journal of Internet of Things and Convergence
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• v.9 no.3
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• pp.93-98
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• 2023

In this paper, an artificial neural network based on simulated annealing was constructed. The mapping relationship between the parameters of micro-scaled flow channels electrochemical machining and the channel shape was established by training the samples. The depth and width of micro-scaled flow channels electrochemical machining on stainless steel surface were predicted, and the flow channels experiment was carried out with pulse power supply in NaNO3 solution to verify the established network model. The results show that the depth and width of the channel predicted by the simulated annealing artificial neural network with "4-7-2" structure are very close to the experimental values, and the error is less than 5.3%. The predicted and experimental data show that the etching degree in the process of channels electrochemical machining is closely related to voltage and current density. When the voltage is less than 5V, a "small island" is formed in the channel; When the voltage is greater than 40V, the lateral etching of the channel is relatively large, and the "dam" between the channels disappears. When the voltage is 25V, the machining morphology of the channel is the best.

• Journal of the Korea Organic Resources Recycling Association
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• v.31 no.2
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• pp.63-71
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• 2023

Increased nitrogen in the water system has become an important environmental problem around the world, as it causes eutrophication, algae bloom, and red tide, destroys the water system, and undermines water's self-purification. The most common form of nitrogen in the water system is ammonium ion (NH₄⁺), and the largest portion of ammonium ions comes from wastewater. NH₄⁺ is a major contributor to eutrophication, which calls for appropriate treatment and measures for ammonium removal. This study produced biochar by applying Sorghum × drummondii, a type of biomass with a great growth profile, analyzed the adsorption capacity of Sorghum × drummondii biochar produced from the changing carbonization temperature condition of 200 to 400℃ in the ammonium ion range of 10 to 100 ppm, and used the results to evaluate its potential as an adsorbent. Carbonization decomposed the chemical structure of Sorghum × drummondii and increased the content of carbon and fixed carbon in the biochar. The biochar's pH and electrical conductivity showed high adsorption potential for cations due to electrical conductivity as its pH and electrical conductivity increased along with higher carbonization temperature. Based on the results of an adsorption experiment, the biochar showed 54.5% and 17.4% in the maximum and minimum NH₄-N removal efficiency as the concentration of NH₄-N increased, and higher carbonization temperature facilitated the adsorption of pollutants due to the biochar's increased pores and specific surface area and subsequently improved NH₄-N removal efficiency. FT-IR analysis showed that the overall surface functional groups decreased due to high temperature from carbonization.

• Journal of the Society of Cosmetic Scientists of Korea
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• v.49 no.2
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• pp.159-167
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• 2023

Titanium dioxide (TiO₂) is commonly used in sunscreen formulations to protect the skin surface and prevent the penetration of harmful ultraviolet (UV) rays by the physical scattering action of light. However, a disadvantage of using TiO₂ is that it can cause white turbidity when used on skin due to its inactive mineral ingredient. In addition, when TiO₂ particles are reduced to nanosize to eliminate opacity, they can increase the transmittance of visible light and reduce whitening, but may lead to serious skin problems, such as allergic inflammation. To overcome these issues, the bandgap of TiO₂ was controlled by adjusting the amount of oxygen defect and nitrogen amount, resulting in color TiO₂ tailored to the skin. This innovative technology can reduce the whitening phenomenon and effectively block blue light, which is known to cause skin aging by inducing active oxygen. The bandgap controlled TiO₂ compounds proposed in this study are hypoallergenic, broad-spectrum, and environmentally friendly. Furthermore, these compounds have been shown to significantly enhance sun protection factor (SPF) of sunscreens, demonstrating their compatibility with blue light blocking products.

• Journal of the Society of Cosmetic Scientists of Korea
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• v.49 no.2
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• pp.97-106
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• 2023

In this study, we would like to study the stabilization of the high content of ceramide formulation by containing cyclodextrin. Ceramide, which constitutes the intercellular lipid, a human skin barrier, is a very important ingredient in moisturizing maintenance by protecting moisture in the skin and strengthening the skin barrier. However, since ceramide is poorly soluble, even if it is included in the cosmetic formulation, it has a problem that it is slowly gelled or crystallized and deposited over time, making it difficult to containing a high amount of ceramide. Cyclodextrin is a cyclic oligosaccharide connected with glucose molecules and has a cylindrical structure with hydrophilic outer surface and hydrophobic inner surface, which is known to improve the physicochemical properties of drugs such as improving solubility and absorption of poorly soluble drugs. We demonstrated the stability of the formulation containing high amount of ceramide by measuring hardness and observing emulsion drops with polarized microscope. This study also demonstrated that the high-content ceramide formulation containing cyclodextrin has the effect of preventing gelation or crystallization of ceramide, thus having excellent environmental conditions stability and skin moisturization.

• Composites Research
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• v.36 no.3
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• pp.180-185
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• 2023

This paper investigates the impact of fiber dispersion on the internal structure and mechanical strength of SiC_f/SiC composites manufactured using spread SiC fibers. The fiber volume ratio of the specimen to which spread SiC fiber was applied decreased by 9%p compared to the non-spread specimen, and the resin slurry impregnated between the fibers more smoothly, resulting in minimal matrix porosity. In order to compare the fiber dispersion of each specimen, a method was proposed to quantify and evaluate the separation distance between fibers in composite materials. The results showed that the distance between fibers in the spread specimen increased by 2.23 ㎛ compared to the non-spread specimen, with a significant 42.6% increase in the distance between fiber surfaces. Furthermore, the 3pt bending test demonstrated a 49.3% higher flexural strength in the spread specimen, accompanied by a more uniform deviation in test data. These findings highlight the significant influence of SiC fiber dispersion on achieving uniform densification of the SiC_f/SiC matrix and increasing mechanical strength.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.30 no.5A
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• pp.433-442
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• 2010

A control of chloride diffusion coefficient is very essential for service life of reinforced concrete (RC) structures exposed to chloride attack so that much studies have been focused on this work. The purpose of this study is to derive the intended diffusion coefficient which satisfies intended service life and propose a technique for optimum concrete mixture through genetic algorithm(GA). For this study, 30 data with mixture proportions and related diffusion coefficients are analyzed. Utilizing 27 data, fitness function for diffusion coefficient is obtained with variables of water to binder ratio(W/B), weight of cement, mineral admixture(slag, flay ash, and silica fume), sand, and coarse aggregate. 3 data are used for verification of the results from GA. Average error from fitness function is observed to 18.7% for 27 data for diffusion coefficient with 16.0% of coefficient of variance. For the verification using 3 data, a range of error for mixture proportions through GA is evaluated to 0.3~9.3% in 3 given diffusion coefficients. Assuming the durability design parameters like intended service life, cover depth, surface chloride content, and replacement ratio of mineral admixture, target diffusion coefficient, where exterior conditions like relative humidity(R.H.) and temperature, is derived and optimum design mixtures for concrete are proposed. In this paper, applicability of GA is attempted for durability mixture design and the proposed technique would be improved with enhancement of comprehensive data set including wider range of diffusion coefficients.

• Analytical Science and Technology
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• v.19 no.4
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• pp.301-308
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• 2006

Pitch-coated anatase $TiO_2$ typed was prepared by $CCl_4$ solvent mixing method with different mixing ratios. Since the carbon layers derived from pitch on the $TiO_2$ particles were porous, the pitch-coated $TiO_2$ sample series showed a good adsorptivity and photo decomposition activity. The BET surface area depends on the pitch contents, which was made by changing the mixing ratios of the pitch with the raw $TiO_2$. The SEM results present to the characterization of porous texture on the pitch-coated $TiO_2$ sample and pitch distributions on the surfaces for all the materials used. From XRD data, a weak and broad carbon peak of graphene with pristine anatase peaks were observed in the X-ray diffraction patterns for the pitch-coated $TiO_2$. The EDX spectra show the presence of C, O and S with strong Ti peaks. Most of these samples are richer in carbon and major Ti metal than any other elements. Finally, the excellent photocatalytic activity of pitchcoated $TiO_2$ with Uv/Vis spectra between absorbance and time could be attributed to the homogeneous coated pitch on the external surface by $CCl_4$ solvent method.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.30 no.4A
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• pp.353-359
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• 2010

Cementitious matrix based composites are vulnerable to the drying shrinkage crack during the curing process. In this study, the drying shrinkage induced fracture behavior of the fiber reinforced concrete is simulated and the effects of the fiber reinforcement conditions on the fracture characteristics are analysed. The numerical model is composed of conduit elements and rigid-body-spring elements on the identical irregular lattice topology, where the drying shrinkage is presented by the coupling of nonmechanical-mechanical behaviors handled by those respective element types. Semi-discrete fiber elements are applied within the rigid-body-spring network to model the fiber reinforcement. The shrinkage parameters are calibrated through the KS F 2424 free drying shrinkage test simulation and comparison of the time-shrinkage strain curves. Next, the KS F 2595 restrained drying shrinkage test is simulated for various fiber volume fractions and the numerical model is verified by comparison of the crack initiating time with the previous experimental results. In addition, the drying shrinkage cracking phenomenon is analysed with change in the length and the surface shape of the fibers, the measurement of the maximum crack width in the numerical experiment indicates the judgement of the crack controlling effect.