• Title/Summary/Keyword: 폴리유산

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Manufacture of Continuous Glass Fiber Reinforced Polylactic Acid (PLA) Composite and Its Properties (연속 유리섬유 강화 폴리유산 복합재료의 제조 및 물성)

  • Roh, Jeong U;Lee, Woo Il
    • Composites Research
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    • v.26 no.4
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    • pp.230-234
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    • 2013
  • The continuous glass fiber reinforced poly-lactic acid (PLA) composite was manufactured by direct melt impregnation. The mechanical and thermal properties of continuous glass fiber reinforced PLA composite were observed. Measured properties were compared with the reference values of neat PLA and the injection molded glass fiber/ PLA composite. The continuous glass fiber reinforced PLA composite having a fiber volume fraction of 27.7% shows enhanced tensile strength of 331.1 MPa, flexural strength of 528.6 MPa, and flexural modulus of 24.0 GPa. The enhanced heat deflection temperature (HDT) and the increased cystallinity were also observed. The degree of impregnation as a function of pulling speed was also assessed. The degree of impregnation at the pulling speed of 5 m/min was over 90% in this research.

A Molecular Dynamics Simulation Study on the Thermoelastic Properties of Poly-lactic Acid Stereocomplex Nanocomposites (분자동역학 전산모사를 이용한 폴리유산 스테레오 콤플렉스 나노복합재의 가수분해에 따른 열탄성 물성 예측 연구)

  • Ki, Yelim;Lee, Man Young;Yang, Seunghwa
    • Composites Research
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    • v.31 no.6
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    • pp.371-378
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    • 2018
  • In this study, the thermoelastic properties of poly lactic acid (PLA) based nanocomposites are predicted by molecular dynamics (MD) simulation and a micromechanics model. The stereocomplex mixed with L-lactic acid (PLLA) and D-lactic acid (PDLA) is modeled as matrix phase and a single walled carbon nanotube is embedded as reinforcement. The glass transition temperature, elastic moduli and thermal expansion coefficients of pure matrix and nanocomposites unit cells are predicted though ensemble simulations according to the hydrolysis. In micromechanics model, the double inclusion (D-I) model with a perfect interface condition is adopted to predict the properties of nanocomposites at the same composition. It is found that the stereocomplex nanocomposites show prominent improvement in thermal stability and interfacial adsorption regardless of the hydrolysis. Moreover, it is confirmed from the comparison of MD simulation results with those from the D-I model that the interface between CNT and the stereocomplex matrix is slightly weak in nature.

Processing and Flexural Properties of Chopped Jute Fiber Reinforced PLA Sandwich Composites (황마 단섬유 강화 폴리유산 샌드위치 복합재의 제작 및 굽힘 특성)

  • Lee, Gyu Hee;Roh, Jeong U;Lee, Woo Il
    • Composites Research
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    • v.27 no.3
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    • pp.96-102
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    • 2014
  • In this study, we fabricated jute fiber reinforced polylactic acid (PLA) composite in the form of sandwich panel structure which includes core foam of chopped jute fiber reinforced PLA and outer skin layer of continuous glass fiber reinforced PLA. Flexural properties of the composite were assessed for different jute fiber weight fractions. Density of the core foam ranged from 0.31 to 0.67 $g/cm^3$ and void content fraction 0.51 to 0.71. The maximum flexural strength was 92.7 MPa at 12.5 wt.% of jute fiber content, and the maximum flexural modulus was 7.58 GPa at 30.0 wt.%. Cost analysis was also conducted. The cost to enhance the flexural strength of the applied structure was estimated to be $0.010USD/m^3/MPa$ for 12.5 wt.% fiber content.

Flavonoid production and antioxidant activity effect by lactic acid bacteria fermentation of deer antler extract (녹용추출물의 유산균 발효에 의한 플라보노이드 생성과 항산화활성 효과)

  • Kim, Hyun-Kyoung
    • The Journal of the Convergence on Culture Technology
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    • v.8 no.2
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    • pp.399-408
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    • 2022
  • As part of research on the development of functional materials for antlers, lactic acid fermentation of antler extract was performed. It was intended to develop a functional material with enhanced total polyphenol and flavonoid content and enhanced antioxidant activity. During the fermentation of lactic acid bacteria, the number of proliferation, total polyphenol and total flavonoid content, DPPH radical scavenging and antioxidant activity were quantified and evaluated. As a result of adding these four types of lactic acid bacteria to the antler water extract substrate, the number of lactic acid bacteria measured was 2.04~5.00×107. Meanwhile, a protease (Baciullus amyloliquefaciens culture: Maxazyme NNP DS) was added to the antler extract to decompose the peptide bonds of the contained proteins. Then, these four types of lactic acid bacteria were added and the number of lactic acid bacteria increased to 2.84×107~2.21×108 as the result of culture. The total polyphenol contents were 4.82~6.26g/mL in the lactic acid bacteria fermentation extracts, and after the reaction of protease enzyme and lactic fermentation, increased to 14.27~20.58 g/mL. The total flavonoid contents were 1.52~2.21 g/ml in the lactic acid bacteria fermentation extracts, and after the protease reaction and fermentation, increased to 5.59~8.11 mg/mL. DPPH radical scavenging activities of lactic acid bacteria fermentation extracts was 17.03~22.75%, but after the protease reaction and fermentation, remarkably increased to 32.82~42.90%.

Preparation and Performance Improvement of Polylactic acid based composites by stereocomplex (스테레오 컴플렉스를 이용한 폴리유산 복합재 제조 및 성능 개선)

  • Hong, Chae-Hwan;Kim, Yeon-Hee;Park, Jun-Seo;Nam, Byeong-Uk
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.3
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    • pp.1671-1676
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    • 2015
  • A unique crystallization behavior of poly(L-lactide)(PLLA)/poly(D-lactide)(PDLA) stereocomplex(SC) was observed when a PLLA/PDLA blend was subjected to the specific melting conditions. Therefore, we tried to blend PLLA and PDLA at overall composition to form PLA stereocomplexes. Moreover, impact modifier and reinforcement materials such as talc and glass fiber added to enhance the mechanical and thermal properties such as impact strength and heat distortion temperature(HDT). As a result, we got one representative result, one composite recipe with HDT $115^{\circ}C$. For more economic technology, we tried to blend PLLA and Polypropylene at overall composition and we got another representative result which could be applied to current PP/talc composites and ABS materials. The core technology of this might be the well dispersion of glass fibers into the matrix resin such as PP, PLLA and impact strength modifier.

하이드록시 아파타이트와 폴리유산 블렌드에서 하이드록시 아파타이트의 화학적 개질의 영향

  • Lee, Won-Gi
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2007.05a
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    • pp.545-547
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    • 2007
  • 본 연구에서는 생체 적합성이 뛰어난 HA가 고분자와의 낮은 친화성을 개선하기 위하여 HA를 화학적으로 개질하여 고분자와의 친화성을 높이는 연구를 수행하였다. 결과에서 나타나 바와 같이 효과적으로 개환중합을 이용하여 HA를 효과적으로 개질하였고 고분자와의 복합재료에 대한 특성을 고찰 하였다.

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입체화학을 이용한 생분해성 고분자인 폴리유산의 스트레오 콤플렉스 형성 조절 및 특성연구

  • Lee, Won-Gi
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2007.05a
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    • pp.558-560
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    • 2007
  • l-PLA와 d-PLA사이의 complex형성은 화학 양론적으로 동일 몰비에서 강력한 상호 작용력에 기인한다. 이러한 특성을 이용하여 PLA블렌드 계에서 stereochemistry를 이용하여 블렌드 한 성분에 defect를 부여함으로서 complex정도를 조절함으로서 다성분 고분자계의 표면 조성의 조절(표면 물성의 조절)과 생분해성의 조절이 가능함을 보였다.

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Processing and Mechanical, Thermal and Morphological Properties of Poly(lactic acid)/Poly(butylene succinate) Blends (폴리유산/폴리부틸렌숙시네이트 블랜드의 가공 및 기계적, 열적, 형태학적 특성)

  • Kim, Dae Keun;Cho, Donghwan
    • Journal of Adhesion and Interface
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    • v.15 no.1
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    • pp.14-21
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    • 2014
  • In the present work, PLA/PBS blends with poly(lactic acid) (PLA) and poly(butylene succinate) (PBS) at different contents were processed by using a twin-screw extruder and an injection molding machine, and then their mechanical, thermal and morphological properties were investigated. The mechanical properties such as flexural strength, flexural modulus, tensile strength and tensile modulus and thermal properties such as melting behavior, dynamic mechanical thermal properties and thermal stability significantly depended on the contents of PLA and PBS. However, the heat deflection temperature of the blends was not significantly influenced by the contents of PLA and PBS. Also, the fracture surfaces of PLA/PBS blends were changed from a brittle pattern to a ductile pattern with increasing the PBS contents.