• 제목/요약/키워드: 폴리아미드6

검색결과 50건 처리시간 0.026초

PA6 사출성형품의 형상비에 따른 성형수축 거동 (Shrinkage Behaviors of PA6 polymer according to Shape Ratio of Product in Injection Molding)

  • 최윤식;한동엽;정영득
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2004년도 추계학술대회 논문집
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    • pp.308-311
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    • 2004
  • Nowadays, plastic industry has needed to produce parts that require high precision and quality. To make a high precision and quality part, before injection molding, plastic material is investigated about their properties such as shrinkage, warpage, etc. In this study, experiments were conducted with PA6(polyamid) to figure out shrinkage behavior according to three type aspect ratio of samples. The injection speed that affects on shear rate, molecular orientation within plastic part was determined as main variable of experiment. As a result of experimental study, part shrinkage had a tendency to be decreased by increasing injection speed and aspect ratio of samples.

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SLS 공정을 이용한 산업용 SFF 시스템용 신소재 고분자분말 개발 (Development of New Polymer Powders for the Industrial SFF system by using SLS Process)

  • 방영길;최기섭;박창현;김형일;임병석;김동수
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2007년도 춘계학술대회A
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    • pp.1404-1409
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    • 2007
  • Polymers for laser sintering were needed in order to fabricate the articles with the three-dimensional duplication equipment of SLS (selective laser sintering) process. The thermal properties, particle size, distribution, and shape of polymer powder had a close relation with the processibility of laser sintering. In this study, we prepared new polymer powders with uniform size and higher bulk density by wet process. Wet process consists of several finely-controlled steps such as dissolution, nucleation, propagation and crystallization. Several additives were added to improve the thermal, rheological, and flow properties.

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천연 올레인산 기반 폴리아미드계 TPEs 단량체 합성 (Synthesis of Monomers for Polyamide-type TPEs from Oleic Acid)

  • 고무현;김현수;김현정;신나라;유동원;김영규
    • Elastomers and Composites
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    • 제48권1호
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    • pp.24-29
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    • 2013
  • 식물성 오일로부터 추출한 물질을 기반으로 하여 열가소성 탄성체(thermoplastic elastomer, TPE) 중에서도 뛰어난 물성을 가진 것으로 잘 알려진 폴리아미드계 TPE(polyamide-type TPE, TPAE)의 단량체 합성공정을 개발하였다. 대다수의 식물성 오일에 함유되어 있는 불포화 지방산으로 잘 알려진 올레인산을 사용하여 TPAE의 단량체 6종($C_9$, $C_{10}$, $C_{11}$ ${\omega}$-amino acid 와 ${\alpha}$, ${\omega}$-dicarboxylic acid)을 좋은 수율로 합성하였다.

폴리아미드계 수지를 이용한 핫멜트 접착제의 기능 향상 - (III) 왁스와 충전제의 영향 - (Functional Improvement of Hot Melt Adhesive Using Polyamide Type Resin - (III) The Effect of Wax and Filler -)

  • 정경호;한경아;조욱상
    • 공업화학
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    • 제16권6호
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    • pp.827-833
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    • 2005
  • 본 연구에서는 폴리아미드계 수지를 이용하여 최적의 핫멜트 접착제 배합설계를 접착제 합성, 물성평가 및 철에 대한 접착력 평가를 통해 구축하고자 하였다. 최적 배합설계를 위해 앞선 연구결과에 따라 CM831과 843P의 기본 수지에 점착부여수지로 테르펜수지의 무게비를 각각 75/25/10으로 고정한 후 왁스, 충전제 등이 사용되었으며 이들의 종류와 첨가량이 접착제의 흐름 특성과 접착력에 미치는 영향을 조사하였다. 결과에 따르면 왁스의 경우 폴리에틸렌 왁스의 첨가량이 증가함에 따라 용융점도는 다소 감소하였지만 철과의 최적 접착력은 5 wt%에서 나타났다. 이는 접착제 자체의 기계적 물성과 밀접한 관계가 있음을 알 수 있었다. 충전제의 경우는 탈크가 10 wt% 첨가되었을 때 다소 높은 용융점도에 비해 우수한 접착성능을 나타내었다.

PEDOT:PSS/그래핀 코팅된 폴리아미드/폴리우레탄 혼방 편직물 기반의 전기전도성 텍스타일 제조 (Fabrication of Electroconductive Textiles Based Polyamide/Polyurethan Knitted Fabric Coated with PEDOT:PSS/Non-oxidized Graphene)

  • ;조길수
    • 한국의류산업학회지
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    • 제24권1호
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    • pp.146-155
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    • 2022
  • We proposed a simple process of creating electroconductive textiles by using PEDOT:PSS(Poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate))/non-oxidized graphene to coat polyamide or polyurethane knitted fabric for smart healthcare purposes. Electroconductive textiles were obtained through a coating process that used different amounts of PEDOT:PSS/non-oxidized graphene solutions on polyamide/polyurethane knitted fabric. Subsequently, the surface, electrical, chemical, weight change, and elongation properties were evaluated according to the ratio of PEDOT:PSS/non-oxidized graphene composite(1.3 wt%:1.0 wt%; 1.3 wt%:0.6 wt%; 1.3 wt%:0.3 wt%) and the number of applications(once, twice, or thrice). The specimens' surface morphology was observed by FE-SEM. Further, their chemical structures were characterized using FTIR and Raman spectroscopy. The electrical properties measurement (sheet resistance) of the specimens, which was conducted by four-point contacts, shows the increase in conductivity with non-oxidized graphene and the number of applications in the composite system. Moreover, a test of the fabrics' mechanical properties shows that PEDOT:PSS/non-oxidized graphene-treated fabrics exhibited less elongation and better ability to recover their original length than untreated samples. Furthermore, the PEDOT:PSS/non-oxidized graphene polyamide/polyurethane knitted fabric was tested by performing tensile operations 1,000 times with a tensile strength of 20%; Consequently, sensors maintained a constant resistance without noticeable damage. This indicates that PEDOT:PSS/non-oxidized graphene strain sensors have sufficient durability and conductivity to be used as smart wearable devices.

상압 저온 플라즈마 전처리한 폴리아미드계 직물의 색농도 (Color Depth of Polyamide Fabrics Pretreated with Low-Temperature Plasma under Atmospheric Pressure)

  • 이문철
    • 한국염색가공학회지
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    • 제5권2호
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    • pp.134-138
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    • 1993
  • Wool, silk and nylon 6 fabrics were treated with low-temperature plasma under atmospheric pressure of acetone/argon or helium/argon for 30 and 180 sec, and then dyed with leveling type acid dye, C.I. Acid Red 18 and milling type acid dye, C.I. Acid Blue 83. In spite of short time of the plasma treatment for thirty seconds, the color depth of wool fabrics was increased remarkably with both of the plasma gases, aceton/argon or helium/argon and with the kinds of dyes i.e., levelin type or milling type. But the atmosperic low-temperature plasmas did not increase the depth of silk and nylon 6 fabrics dyed with both of the acid dyes regardless of the teated time and plasma gases. It seems that low-temperature plasma by atmospheric-pressure discharge is effective for improvement of dyeing of wools as is the same way with the low-temperature plasma by glow discharge. The kinds of plasma gases and treated time did not influnce the depth of wool fabric pretreted with the atmosperic low-temperature plasmas.

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지방산 폴리아미드계 비이온성 내구유연제의 제조와 유연효과에 관한 연구 (Preparation and Softening Effect of Fatty Polyamide Type Nonionic Durable Softer)

  • 고재용;전영제;홍의석;박홍수
    • 한국응용과학기술학회지
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    • 제12권2호
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    • pp.65-73
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    • 1995
  • 1, 3-Di(dodecanoyl)-2, 7-dioxy-6, 8-di(2-hydroxyethyl)-1, 3, 6, 8-tetraazacyclodecane(DDDT) and pentaerythritol monostearate(PMS) were synthesized as a main component for softner. O/W type softner(DPSA) was prepared by blending DDDT and PMS with polyoxyethylene(10) castor oil, polyoxyethylene(20) oleyl ether, and polyoxyethylene(10) monolaurate. After treatment of DPSA to all cotton fabrics, the physical properties such as tear strength, crease recovery, and flexing abrasion resistance were measured. As a result of the measurement, DPSA was proved to be durable softner with good softness.

에폭시를 반응성 상용화제로 사용하여 제조한 폴리에틸렌테레프탈레이트와 폴리아미드-6 알로이 섬유의 구조와 성질: 1. 알로이의 상분리에 미치는 에폭시의 효과 (Preparation and Properties of Poly(ethylene terephthalate)(PET)/Polyamide-6(PA6) Alloy Fibers using Epoxy as a Reactive Compatibilizer: I. Effect of Epoxy on the Phase Separation of PET/PA6 Alloys)

  • 조징;민병길;임목근;이광상;유영출;한재성
    • 한국염색가공학회지
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    • 제24권2호
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    • pp.145-151
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    • 2012
  • Polymer alloys of poly(ethylene terephthalate)(PET) and nylon6(PA6) which were not miscible each other by themselves were successfully prepared through melt compounding using a twin-screw extruder by utilizing epoxy as reactive compatibilizer. At the epoxy(DGEBA) amount of 0.5~2wt%, the domain size(average diameter) of the discontinuous phase could be reduced up to 0.2${\mu}m$ from 1-5${\mu}m$ that of the simple blend without epoxy. The reaction was presumed to happen mostly at interphase from the result of maximum increase of melt viscosity at the middle range of PET/PA6 blend ratio. It is expected that alloy fibers of PET/epoxy/PA6 with enough mechanical strength for use can be prepared.

일방향 혼합방사형 탄소섬유/폴리아미드 6 복합재료판의 제작조건과 굽힘파괴거동 (Fabrication of unidirectional commingled-yarn-based carbon fiber/polyamide 6 composite plates and their bend fracture performances)

  • 최낙삼
    • 대한기계학회논문집A
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    • 제22권2호
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    • pp.416-427
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    • 1998
  • Unidirectional commingled-yarn-based carbon fiber(CF)/polyamide(PA) 6 composite was fabricated under molding pressures of 0.4, 0.6 and 1.0 MPa to study its flexural deformation and fracture behavior. Fiber/matrix interfacial bonding area became larger with an increase of molding pressure from 0.4 to 0.6 MPa. For molding pressures .geq. 0.6 MPa, good flexural performance of similar magnitudes was attained. For the fracture test, four kinds of notch direction were adopted : edgewise notches parallel (L) and transverse (T) to the major direction of fiber bundles, and flatwise notches parallel(ZL) and perpendicular(ZT) to this direction. Nominal bend strength for L and ZL specimens exhibited high sensitivity to notching. ZL specimens revealed the lowest values of the critical stress intensity factor $K_c$ which was slightly superior to those of unfilled PA6 matrix. Enlargement of the compression area for T specimens was analyzed by means of the rigidity reduction resulting from the fracture occurrence.

가열조건이 폴리아미드지의 절연특성에 미치는 영향 (A Study on the heating conditions affect on the insulation characteristics of polyamid papers)

  • 선종호;김우성;김광화
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2000년도 하계학술대회 논문집 C
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    • pp.2047-2049
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    • 2000
  • In this study, we describe comparison of insulation characteristics of polyamid papers with heating conditions. The partial discharge behavior until breakdown and breakdown strength for thermal degradation films are observed in $SF_6$ gas chamber. The four layered NOMEX films of thickness of 50${\mu}m$ were used as solid insulation films and the sphere of which diameter is 40mm to sphere electrode system was used and each insulation films were inserted between sphere electrodes. The used gas pressure was 1.0bar and used temperature was each of 250$^{\circ}C$, 270$^{\circ}C$, 300$^{\circ}C$, 320$^{\circ}C$, 350$^{\circ}C$ and the voltage were applied until breakdown films.

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