• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.388.2-388.2
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• 2014

최근 그래핀 연구와 더불어 2차원 구조의 나노소재에 대한 관심이 급증하면서 육각형의 질화붕소(hexagonal boron nitride; h-BN) 박막(nanosheet) [1]이나 붕소 탄화질화물(boron caronitride; BCN) 박막 [2,3]와 같은 2차원 구조체에 대한 연구가 활발히 진행되고 있다. 그 중 BCN은 반금속(semimetal)인 흑연(graphite)과 절연체인 h-BN이 결합된 박막으로 원소의 구성 비율에 따라 전기적 특성을 제어할 수 있다는 장점이 있다. 따라서 다양한 나노소자로의 응용을 위한 연구가 활발히 진행되고 있다. 본 연구에서는 폴리스틸렌(polystyrene, PS)과 보레인 암모니아(borane ammonia)를 고체 소스로 이용하여 열화학기상증착법을 이용하여 BCN 박막를 SiO2 기판 위에 직접 합성하였다. SEM과 AFM 관측을 통해 합성된 BCN 박막을 확인하였으며, RMS roughness가 0.5~2.6 nm로 매우 낮은 것을 확인하였다. 합성과정에서 PS의 양을 조절하여 BCN 박막의 탄소의 밀도를 성공적으로 제어하였으며, 이에 따라 전기적인 특성이 제어되는 양상을 확인하였다. 또한 합성온도 변화에 따른 BCN 박막의 전기적인 특성이 제어되는 양상을 확인하였다. 추가적으로 같은 방법을 이용하여 BCN 박막을 Ni 위에서 합성하여 SiO2 기판위에 전사 하였다. 합성된 BCN 박막의 구조적 특징과 화학적 조성 및 결합 상태를 투과전자현미경(transmission electron microscopy), X-선 광전자 분광법(X-ray photoelectron spectroscopy)을 통해 조사하였다.

• Magazine of the Korean Society of Agricultural Engineers
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• v.38 no.6
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• pp.83-95
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• 1996

The normal cement concrete is widely used material to build the construction recently, but it has a fault to increase the dead load on account of its unit weight is large compared with strength. So, main purpose of this study was to establish the physical and mechanical properties of lightweight concrete using expanded polystyrene bead on fine aggregate and natural gravel, expanded clay and pumice stone on coarse aggregate. The test rusults of this study are summarized as follows; 1. The water-cement ratio of concrete using pumice stone was larger than that of the concrete using natural gravel and expanded clay. 2. The unit weights of concrete using pumice stone and expanded caly were shown less than 1,000g/$m^3$. 3. The compressive strengths of all types were shown less than 60kg/$cm^2$, tensile and bending strengths were shown less than l3kg/$cm^2$ and 3lkg/$cm^2$$^2$, respectively. 4. The pulse velocity of concrete was shown similar with using natural gravel and pumice stone, and shown the lowest using pumice stone. 5. The dynamic modulus of elasticity of concrete was shown considerably smaller, and shown the lowest using pumice stone. 6. The static modulus of elasticity of concrete using expanded clay and pumice stone were shown considerably smaller, and shown 22% ~29% as compared with the dynamic modulus of elasticity. 7. The stress-strain curves of concrete were shown similar, generally. And the curves were repeated at short intervals increase and decreased irregularly.

• Membrane Journal
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• v.29 no.1
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• pp.61-65
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• 2019

Anisotropic particles have been issued in various fields due to their unique physical properties. Herein, a novel dynamic phase separation method (DPS) is introduced to fabricate anisotropic acorn-like nanoparticles. DPS consists of two dynamic conditions; solvent evaporation and nonsolvent induced precipitation. The bottom layer is controlled by feeding the water as a non-solvent diluent, and the phase separation of the upper layer relies on the diffusion and evaporation of a volatile good solvent. At this condition, the acorn-like particles were fabricated. Under a closed box filled with water (spontaneous phase separation), monodisperse polystyrene (PS) particles were synthesized. At the coexistence between DPS and spontaneous phase separation, the sizes of cap and particle were changed. Also, the volume of PS solutions influences on the particle shape. Since the unique structures could be utilized into various applications, if advanced techniques such as membrane-based controlled water feeding is developed, monodisperse acorn-like particles could be tuned.

• The Korean Journal of Rheology
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• v.7 no.1
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• pp.19-27
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• 1995

정밀사출성형품을 생산하기 위해서는 성형조건의 변화가 최종 사출품에 어떠한 영 향을 미치는 가에 대한 연구가 필요하다. 본논문에서는 성형조건을 조직적으로 변화시키며 가장 간단한 원반형상의 사출품에 남는 복굴절의 분포를 측정함으로써 성형조건의 변화가 최종 사출품의 광학적 이방성의 구조에 어떠한 영향을 미치는 가에 초점을 맞추었다. 광탄 성적 성질이 많이 다른 폴리스틸렌과 폴리카보네이트를 재료로 지름이 10.16cm 이고 두께 가 2mm인 금형을 사용하였다. 두께 방향의 복굴절양과 광학 주축각의 분포를 통해 보압크 기가 최종사출품의 광학적 이방성, 특히 내측의 두 개의 정점값에 미치는 영향을 알수 있었 다. 한편 서로 다른 두 물질의 광학적, 물리적 성질의 차이점에 기인한 복굴절 분포의 구조 적 차이점도 발견할수 있었다. 이 실험 데이터는 컴퓨터 모사에의한 최종사출품의 잔류 응 력과 광학적 이방성 예측에도 중요한 자료가 되리라 믿는다.

• Korean Journal of Optics and Photonics
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• v.18 no.4
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• pp.286-291
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• 2007

We theoretically investigated the far-field radiation pattern of epi-signal from a polystyrene sphere in coherent anti-Stokes Raman scattering (CARS) microscopy with an objective lens of high numerical aperture. We calculated the field distribution of the incident laser beams under the tight-focusing condition and the far-field radiation pattern through coherent addition of radiation from the nonlinear polarizations (Hertzian dipoles) as the origin of CARS signal generation. The epi-radiation patterns for polystyrene spheres of different diameters are calculated, and the pattern of a sphere is also compared with that of a shell fer a diameter of 1100 nm. We finally show how the radiation pattern of the polystyrene sphere changes as the center of the sphere shifts from the focus of the beam.

• Polymer(Korea)
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• v.24 no.6
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• pp.763-769
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• 2000

The multifunctional cation exchangers, sulfonated polypropylene-g-(acrylic acid/styrene) [PP-g-(AAc/Sty)] were synthesized by the irradiational grafting of AAc and Sty onto PP staple fabric with electron beam accelerator and its subsequent sulfonation. The highest degree of grafting obtained was 190% at a monomer mixture of 30 vol% AAc: 70 vol% Sty and a solvent mixture of 30 vol% water : 70 vol% methanol and the degree of grafting decreased with an increase of the AAc content in the monomer mixture at constant solvent content. Maximum ion exchange capacity of the copolymer was 4.6 meq/g. The Li$^{+}$ adsorption ability of the copolymer synthesized in the study was the best among PP-g- AAc, sulfonated PP-g-Sty, and sulfonated PP-g-(AAc/Sty).).

• Applied Chemistry for Engineering
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• v.7 no.5
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• pp.938-945
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• 1996

The present studies are to describe the grafting reaction of styrene in various solvents to polypropylene fabric by the simultaneous method using Co-60. The influence of various factors such as absorbed dose, dose rate, type of solvent, acid and multifunctional monomer were evaluated. At constant absorbed dose, the grafting yield was found to be higher at low dose rate. The initial rate of grafting was found to be proportional to a 0.56 power of dose rate. The inclusion of mineral acid in the grafting solution led to an increase in radiation grafting yield at almost all monomer concentration examined. Multifunctional monomer was also effective to increase grafting yield. The addition of both acid and multifunctional monomer was found to accelerate the grafting yield much more than the separate addition of two additives.

• Proceedings of the Membrane Society of Korea Conference
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• 2004.05b
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• pp.65-68
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• 2004

Proton-exchange membranes have attracted much attention in the past few decades due to their important application in fuel cell systems. The mainly used proton-exchange membranes are perfluoropolymers such as DuPont's Nafion$^{(R)}$ and Asahi Chemical's Aciplex$^{(R)}$ because of their high performance including high proton conductivity ＆ mechanical strength, and excellent thermal ＆ chemical stability.(omitted)ted)

• Proceedings of the KIEE Conference
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• 1994.07b
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• pp.1400-1402
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• 1994

Plasma polymerized thin films was prepared using an interelectrod inductively coupled gas-flow-type reactor. Styrene was chosen as the monomer to be used. This thin films were also delineated by the electron-beam apparatus with an acceleration voltage 30kV, and the pattern in the resist was developed with RIE 80 with argon gas mixture ratio, pressure and RF power. The molecular structure of thin films was investigated by GPC and FT-IR and then was discussed in relation to its quality as a resist. In the case of plasma polymerization, thickness of resist could be controlled by discharge duration and power. Also etch rate is increased as to growing pressure with RIE 80.

• Proceedings of the KAIS Fall Conference
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• 2000.10a
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• pp.223-225
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• 2000

일반적으로 많이 사용되는 고강도 스티로폼은 원료모분을 스팀발포기를 사용하여 수십배로 일차 발포한 후 금형에 넣어 스팀으로 성형한다. 이러한 스티로폼은 단열성이 뛰어난 장점이 있지만 강도가 약하여 내구성이 요구되는 재료로는 부적당하였다. 한편 자동생산공정에 사용되는 로봇 트레이는 고강도 정전기 방지 기능이 필요하게 되었고, 5배 정도의 저발포 스티로폼을 이용한 로봇 트레이가 일부 생산되고 있다. 스팀을 이용한 성형 가공의 경우 모분이 표면에서 발포 융착된 후 내부로 열이 잘 전달되지 못하여 내부 융착이 잘되지 않는 단점을 가지고 있다. 이 단점을 보완하기 위하여 물의 높은 유전율을 이용한 유전가열을 사용하여 내부 융착을 용이하게 시킬 수 있다. 본 연구는 원료모분을 3배이하로 일차 발포한 폴리스틸렌 원료를 이용하여, 스팀에 의한 성형이 아닌 고주파 유전가열을 이용한 성형 방법에 의하여 만들어진 성형물의 비젼과 문제점을 제시하였다. 본 연구에 사용한 고주파는 나무 집성가공에 많이 사용되는 13.6MHz를 사용하였고, 금형은 두랄루민 금형과 목형을 사용하여 시험하였으며, 이의 장단점 및 문제점을 비교하였다. 스팀성형가공에 비하여 내부융착이 훨씬 뛰어났으며, 일부 문제점을 보완하면 진보된 생산공정이 될 것으로 기대된다.