• Title/Summary/Keyword: 폴리스티렌

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Selectivity and Permeability Characteristics of Pure CO2 and N2 Gases through Plasma Treated Polystyrene Membrane (플라즈마 처리된 폴리스티렌 막을 통한 순수한 CO2 와 N2 기체의 선택·투과 특성)

  • Hwang, Yui-Dong;Shin, Hee-Yong;Kwak, Hyun;Bae, Seong-Youl
    • Korean Chemical Engineering Research
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    • v.44 no.6
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    • pp.588-596
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    • 2006
  • The surface of polystyrene membrane treated by Ar, $O_2$ plasma, and the effects were observed before and after the treatment and permeability of $CO_2$, $N_2$ and selectivity of $CO_2$ relative to $N_2$ was measured using continuous flow gas permeation analyzer (GPA). The mole ratio of O over C in the surface was increased from 0 to 0.179 with Ar plasma treatment and route mean square of surface was increased from $15.86{\AA}$ to $71.64{\AA}$. Therefore the contact angle was decreased from $89.16^{\circ}$ to $18.1^{\circ}$. Thus Plasma treatments made surface of membrane tend to be highly hydrophilic. The optimum condition for the $CO_2$ permeability and ideal selectivity of the plasma treated membrane was as follows: the measurement of Ar (60 W, 2 min, $70^{\circ}C$) plasma treatment was $1.14{\times}10^{-12}[m^3(STP){\cdot}m/m^2{\cdot}sec{\cdot}atm]$ and 4.22. In the case of $O_2$ plasma treatment, the contact angle was decreased at $13.56^{\circ}$ with increase of O/C ratio ($0.189{\AA}$) and route mean square of surface ($57.10{\AA}$). The optimum condition for the $CO_2$ permeability and ideal selectivity of the plasma treated membrane was as follows: the measurement of $O_2$ (90 W, 2 min, $70^{\circ}C$) plasma treatment was $7.1{\times}10^{-12}[m^3(STP){\cdot}m/m^2{\cdot}sec{\cdot}atm]$ and 11.5. After plasma treatment, the changes of membrane surface were all subtly linked with both cross-linking and etching effects. Finally, it was confirmed that the gas permeation capacity and selectivity of the modified membrane with plasma could be improved by an appropriate control of the plasma conditions such as treatment time, the power input and sort of plasma gas.

3-D Rat Hepatocytes' Culture on Polystyrene Nanofibrous Scaffold (폴리스티렌 나노섬유상에서의 간세포의 3차원 배양)

  • Kim, Young-Jin;Ahn, Chang-Hyun;Oh, Hwan-Hee;Kim, Young-Jin;Yoon, Kwan-Han;Kang, Inn-Kyu;Kwon, Oh-Hyeong
    • Polymer(Korea)
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    • v.32 no.2
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    • pp.131-137
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    • 2008
  • We have fabricated polystyrene (PS) nanofibrous scaffold for hepatocyte culture by electrospinning method and subsequently coated with specific ligand of Poly[N-p-vinylbenzyl-O-$\beta$-D-galactopyranocyl-($1{\rightarrow}4$)-D-gluconamide](PVLA) to enhance hepatocytes attachment. Rat hepatocytes behavior on the PVLA-coated and non-coated PS nanofibrous matrices have been investigated. Electrospun PS nanofiber structures revealed randomly aligned fibers with average diameter of 500 nm. It is observed that PS nanofibrous matrix could incorporate many cells into the interior of the matrix probably due to the suitable pore size. Cell viabilities cultured on PVLA-coated PS nanofibrous mats were maintained for 3 weeks, while it was decreased rapidly on PVLA-coated PS dishes. High hepatic functions especially for albumin secretion and ammonia removal were maintained at least for 2 weeks on nanofibrous mats but rapidly decreased on flat PS dishes. These results indicate that nanofibrous structure enabled 3-D culture with high level of cell-cell contact results in providing cell-cell communications and subsequent long-term maintenance of specific cell functions.

Change of Dose Distribution on the Beam Axis of 60Co γ Ray and 10MV X-Ray with Part Thickness (치료부위(治療部位)두께에 따른 Co-60 γ선(線)과 10MV X선(線)의 선축상(線軸上) 선량분포(線量分布)의 변화(變化))

  • Kang, Wee Saing;Koh, Kyoung Hwan;Ha, Sung Whan;Park, Charn Il
    • Radiation Oncology Journal
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    • v.1 no.1
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    • pp.21-24
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    • 1983
  • The thickness of the part being irradiated is finite. Percent depth dose tables being used routinely are generally obtained from dosimetry in a phantom much thickner than usual patient. At or close to exit surface, the dose should be less than that obtained from the percent depth dose tables, because of insufficient volume for backscattering. To know the difference between the true absorbed dose and the dose obtained from percent depth dose table, the doses at or close to the exit surface were measured with plate type ionization chamber with volume of 0.5ml. The results are as follows; 1. In the case of $^{60}Co$, percent depth dose at a given depth increases with underlying phantom thickness up to the 5cm. 2. In the case of $^{60}Co$, the dose correction factor at exit surface which is less than 1, increases with part thickness and decreases with field size. 3. Exposure time may not be corrected when the part above 10cm in thickness is treated by $^{60}Co$. 4. In the case of 10MV x-ray, the dose correction factor is nearly 1 and constant for the underlying phantom thickness and field size, so the correction of monitor unit is not necessary for part thickness.

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A Case Study of "Engineering Design" Education with Emphasize on Hands-on Experience (기계공학과에서 제시하는 Hands-on Experience 중심의 "엔지니어링 디자인" 교과목의 강의사례)

  • Kim, Hong-Chan;Kim, Ji-Hoon;Kim, Kwan-Ju;Kim, Jung-Soo
    • Journal of Engineering Education Research
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    • v.10 no.2
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    • pp.44-61
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    • 2007
  • The present investigation is concerned chiefly with new curriculum development at the Department of Mechanical System & Design Engineering at Hongik University with the aim of enhancing creativity, team working and communication capability which modern engineering education is emphasizing on. 'Mechanical System & Design Engineering' department equipped with new curriculum emphasizing engineering design is new name for mechanical engineering department in Hongik University. To meet radically changing environment and demands of industries toward engineering education, the department has shifted its focus from analog-based and machine-centered hard approach to digital-based and human-centered soft approach. Three new programs of Introduction to Mechanical System & Design Engineering, Creative Engineering Design and Product Design emphasize hands-on experiences through project-based team working. Sketch model and prototype making process is strongly emphasized and cardboard, poly styrene foam and foam core plate are provided as working material instead of traditional hard engineering material such as metals material because these three programs focus more on creative idea generation and dynamic communication among team members rather than the end results. With generative, visual and concrete experiences that can compensate existing engineering classes with traditional focus on analytic, mathematical and reasoning, hands-on experiences can play a significant role for engineering students to develop creative thinking and engineering sense needed to face ill-defined real-world design problems they are expected to encounter upon graduation.

Development of Recirculating Wick Hydroponic Techniques for Safe Seed Tuber Multiplication of Potatoe (심지 양액재배법에 의한 상위급 씨감자의 안정적 대량생산)

  • Kang Bong Kyoon;Kim Chan Woo
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.49 no.6
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    • pp.447-451
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    • 2004
  • This study was conducted to establish the proper techniques of the recirculating wick hydroponics for safe seed tuber proliferation of potatoes (Solanum tuberosum L. CV. Dejima). To achieve these, several intact tubers (5, 10 and 20 g) and cut seed-pieces (two or four) were treated in wick hydroponic system beds. A polystyrene box (31cm in width, 20cm in height, 51cm in length, and $0.031m^3$ in volume) was placed on a styrofoam hox. Eight wicks $(width\;1.5cm\;{\times}\;length\;40cm) $ were put into each polystyrene hox and the boxes were filled with perlite + peatmoss (1 : 2, v/v) medium. Top fresh weight per plant increased with increasing the tuber size from 10 to 30g/tuber. As the tuber size increases from 10 to 30 g/tuher in case of uncut tuber, the marketable tuber (>5g) production per plant increased from 83.8 to 141.8 g/plant and the marketable tuber (>5g) production per plant of cut tuber was slightly higher than that of uncut treatment. Total tuber yield ranged from 4.16 to $6.56kg/m^2$ and the percentage of seed tubers was greater than $97\%$ for all treatments. These results indicate that seed tuber should be cut to produce large tuber $(\geq10g)$ in the recirculating wick hydroponic system.

Dose Effect of Tissue Compensator for 6 MV X-Ray (두경부 방사선조사시 3차원조직보상체에 의한 피부선량)

  • Lee, Ho-Jun;Choi, Tae-Jin;Kim, Ok-Bae
    • Radiation Oncology Journal
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    • v.10 no.2
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    • pp.147-153
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    • 1992
  • It is ideal thing to compensate tissue deficit without skin contamination in curvatured irradiation field of high energy photon beam. The 3-dimensional compensating technique utilizing tissue equivalent materials to ensure an adequate dose distribution and skin sparing effect was described. This compensator was made of paraffin ($70\%$) and stearin wax ($30\%$) compound. The parameters for evaluation of the effect on skin dose in application of compensator were considered in the size of the field, the thickness of the compensator and the source-to-axis distance. The results are as follows; the skin doses were not changed even though application of the compensator, but depended on the field size and the source-to-axis distance, and the skin doses were only slightly changed within $1\%$ relative errors as increasing the thickness of the compensator in these experiments.

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Crosslinked Composite Polymer Electrolyte Membranes Based On Diblock Copolymer and Phosphotungstic Acid (디블록 공중합체와 인텅스텐산을 이용한 가교형 복합 고분자 전해질막)

  • Kim, Jong-Hak;Koh, Joo-Hwan;Park, Jung-Tae;Seo, Jin-Ah;Kim, Jong-Hwa;Jho, Young-Choong
    • Membrane Journal
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    • v.18 no.2
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    • pp.116-123
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    • 2008
  • Proton conductive hybrid nanocomposite polymer electrolyte membranes comprising polystyrene-5-poly (hydroxyethyl methacrylate) (PS-b-PHEMA), sulfosuccinic acid (SA) and phosphotungstic acid (PWA) were prepared by varying PWA concentrations. The PHEMA block was thermally crosslinked by SA via the esterification reaction between -OH of PHEMA and -COOH of SA. Upon the incorporation of PWA into the diblock copolymer, the symmetric stretching bands of the $SO_3^-$ group at $1187cm^{-1}$ shifted to a lower wavenumber at $1158cm^{-1}$, demonstrating that the PWA particles strongly interact with the sulfonic acid groups of SA. When the concentration of PWA was increased to 30wt%, the proton conductivity of the composite membrane at room temperature increased from 0.045 to 0.062 S/cm, presumably due to the intrinsic conductivity of the PWA particles and the enhanced acidity of the sulfonic acid in the membranes. The membrane containing 30wt% of PWA exhibited a proton conductivity of 0.126 S/cm at $100^{\circ}C$. Thermal stability of the composite membranes was also enhanced by introducing PWA nanoparticles.

Inhibition of Candida albicans Biofilm Formation by Coptidis chinensis through Damaging the Integrity of Cell Membrane (세포막손상 유발로 인한 황련의 캔디다 바이오필름 형성 억제)

  • Kim, Younhee
    • Korean Journal of Microbiology
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    • v.49 no.1
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    • pp.17-23
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    • 2013
  • Candida biofilms are organized microbial communities growing on the surfaces of host tissues or indwelling medical devices, and the biofilms show enhanced resistance against the conventional antifungal agents. The roots of Coptidis chinensis have been widely used for medicinal purposes in East Asia. The present study was aimed to assess the effect of C. chinensis aqueous extract upon preformed biofilms of 10 clinical Candida albicans isolates and the antifungal activities which contribute to inhibit the C. albicans biofilm formation. Its effect on preformed biofilms was judged using XTT [2,3-Bis-(2-Methoxy-4-Nitro-5-Sulfophenyl)-2H-Tetrazolium-5-Carboxanilide)] reduction assay, and metabolic activity of all tested strains was reduced significantly ($57.3{\pm}14.7%$) at $98{\mu}g/ml$ of the C. chinensis extract. The extract damaged the cell membrane of C. albicans which was analyzed by fluorescein diacetate and propidium iodide staining. The anticandidal activity was fungicidal, and the extract obstructed the adhesion of C. albicans biofilms to polystyrene surfaces, arrested C. albicans cells at $G_o/G_1$ as well, and reduced the growth of biofilms or budding yeasts finally. The data suggest that C. chinensis has multiple antifungal effects on target fungi resulting in preventing the formation of biofilms. Therefore, C. chinensis holds great promise for exploring antifungal agents from natural products in treating and eliminating biofilm-associated Candida infection.

Development of BNR(Biological Nutrient Removal) Process Using Expanded Polystylene(EPS) Media (Expanded Polystylene(EPS) 여재를 이용한 BNR(Biological Nutrient Removal) 공정 개발)

  • Ryu, Hong-Duck;Min, Kyung-Kook;Lee, Jeong-Hun;Choi, Kyoung-Young;Lim, Heun-Eun;Kim, Chul-Hwan;Lee, Sang-Ill
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.1
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    • pp.1-6
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    • 2006
  • Biological nutrient removal(BNR) process used in this study, which was packed with EPS(expanded polystylene) media, has more many advantages in aspect of reducing hydraulic retention time(HRT) of the process and having less effect of temperature in the winter season than commercial process in the present. Bench-scale study was performed using domestic wastewater. In the results, it was observed that the T-N removal efficiencies in HRT 6 hr and HRT 4 hr were 55% and 51%, respectively, showing the small reduction (about 4%) of T-N removal efficiency according to shortening of HRT. In comparison of T-N removal characteristic in summer and winter seasons, it showed that T-N removal efficiencies in summer and winter seasons were 65% and 54%, respectively, showing the 11% lower T-N removal efficiency in winter season than in summer season due to deterioration of nitrification in winter season. In the studies of influent loading rate and C/N ratio, the process showed stable effluent quality under the condition of broad influent loading rate and C/N ratio. Therefore, it is anticipated that the developed process in this study could be applicable to small wastewater treatment plant in nutrient removal.

Analysis of Styrene Dimer and Trimer in Cup Noodle Containers (컵라면 용기중의 스티렌다이머와 트리머의 분석)

  • Lee, Kwang-Ho;Jang, Young-Mi;Kwak, In-Shin;Yoo, Seung-Seok;Kim, Ki-Myeong;Choi, Byung-Hee;Lee, Chul-Won
    • Korean Journal of Food Science and Technology
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    • v.31 no.4
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    • pp.931-937
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    • 1999
  • Styrene dimers and trimers from polystyrene cup noodle containers were analyzed by GC and GC/MS extracted with various simulants. For the quantitation of styrene dimers and trimers, 1,3-diphenylpropane (DP) and benzyln-butyl phthalate (BBP) were chosen as the standards. The results showed that the average of the styrene dimers in the containers was 603 ppm, and that of trimers was 5731 ppm. Four styrene dimers, including 1,2-diphenyl-cyclobutane, were identified as well as seven trimers such as 2,4,6-triphenyl-l-hexene. The migration of the styrene dimers and trimers, from the cup noodle containers of polystyrene into foods, was conducted using simulants including boiling water as well as soybean oil and n-heptane. In addition to, the analysis of each migrated styrene was also performed filled with boiling water into noodle and soup after certain time (5, 10, 20, 30 min). The results showed that the migration of styrene dimers and trimers from cup noodle containers was not detected in the case of using boiled water or soybean oil as a simulant, while styrene dimers and trimers were detected 1.18 ppm and 14.21 ppm, respectively, when heptane was adopted as a simulant. In the case of filling with boiled water into noodle and soup, both styrenes were not detected at 5 min and 10 min, however, some samples standing for 20 min released styrene dimers and trimers as much as 0.009 ppm, and 0.019 ppm for 30 min.

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