• Polymer(Korea)
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• v.31 no.2
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• pp.160-167
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• 2007

This paper proposes a model for the solutions predicting the coefficient of thermal expansion of composites including fiber-like shaped$(a_1>a_2=a_3)$ and disk-like shaped$(a_1=a_2>a_3)$ inclusions like two dimensional geometries, which was analyzed by one axis and a single aspect ratio, $(\rho_\alpha=a_1/a_3)$. The analysis follows the procedure developed for elastic moduli by using the Lee and Paul's approach. The effects of the aspect ratio on the coefficient of thermal expansion of composites containing aligned isotropic inclusions are examined. This model should be limited to analyze the composites with unidirectionally aligned inclusions and with complete binding to each other of both matrix and inclusions having homogeneous properties. The longitudinal coefficients of thermal expansion $\alpha_{11}$ decrease and approach the coefficient of thermal expansion of filler, as the aspect ratios increase. However, the transverse coefficients of thermal expansion $\alpha_{33}$ increase or decrease with the aspect ratios.

• Polymer(Korea)
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• v.33 no.1
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• pp.39-44
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• 2009

Polymer substrates were fabricated by using poly (phenylene ether) as a base resin, N,N'-m-phenylenedimaleimide (PDMI) as a crosslinking agent and decabromodiphenylethane as a flame retardant. The effects of crosslinking agent and flame retardant on physical properties such as dielectric property of the substrate were investigated. Thermal curing feature of PDMI with or without an initiator was analyzed by DSC, and then, PPE-PDMI test compositions were designed based on this result. Composite sheets were cast by film coater, laminated under vacuum and pressure, and then, the changes of dielectric constant, dielectric loss, peel strength, solder heat resistance and inflammability according to increasing amount of PDMI and flame retardant were evaluated, Dielectric constant and dielectric loss showed increasing trend with increasing amount of PDMI and flame retardant, but solder heat resistance and inflammability were improved. Peel strength was obtained higher than 1 kN/m when PDMI above 10 wt% was added, but slightly decreased as the amount of flame retardant increased. From the measured gel contents, the reaction mechanism of PPE-PDMI system was deduced to the formation of network structure by crosslinking PDMI with PPE rather than the formation of semi-IPN structure. In conclusion, the polymer composite substrate materials with dielectric constant of 2.52$\sim$2.65 and dielectric loss below 0.002 at 1 GHz were obtained and they will be proper for high frequency applications.