• Title/Summary/Keyword: 포화된 카올리나이트

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Assessment of the Models for Predicting the Thermal Conductivity of Saturated Kaolinite (포화된 카올리나이트를 이용한 열전도계수 예측모델의 신뢰성 검토)

  • Lee, Jangguen;Kim, Hakseung;Kang, Jaemo;Kim, Youngseok;Bae, Gyujin
    • Journal of the Korean GEO-environmental Society
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    • v.13 no.3
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    • pp.21-27
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    • 2012
  • Estimating the thermal conductivity of clayey soils is important for enhancing the performance of geoengineering structures in cold regions and clay barriers for nuclear waste repositories, but specimen disturbance, saturation, and heat boundary conditions of the test apparatus hinder reliable measurements of the thermal conductivity of saturated clayey soils. This paper presents the results of an experimental study carried out using modified consolidation tests with the needle probe method to measure thermal conductivity. Experimental consolidation tests with saturated kaolinite were performed to investigate the effect of effective stress and dry density on thermal conductivity for saturated kaolinite. In addition, thermal conductivity of soil particles were thoroughly investigated and experimental results were used to evaluate the accuracy of the models to predict thermal conductivity.

Dielectric and Electrical Resistivity Characteristics of Saturated Clay Subjected to Consolidation (포화된 점토의 압밀과정에 따른 유전상수와 전기전도도의 변화)

  • Kim, Yong-Sung;Oh, Myoung-Hak;Bang, Sun-Young;Park, Jun-Boum
    • Proceedings of the Korean Geotechical Society Conference
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    • 2004.03b
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    • pp.791-798
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    • 2004
  • 압밀현상에 따른 포화된 점토의 유전특성과 전기비저항 특성을 분석하기 위해서 전기적 측정이 가능한 Oedometer 압밀시험기를 준비하였다. 포화된 카올리나이트 시료에 대해서 실시한 압밀시험 결과, 압밀현상에 따른 직류 전기비저항과 1MHz (저주파대) 유전상수는 간극수의 소산에 따라 선형으로 증가하는 경향을 보였다. 점토의 전기비저항 특성은 압밀 현상 시 발생하는 흙의 함수량 및 공극비의 감소, 즉 흙의 구조적 특성에 의하여 변하는 것으로 나타났다. 반면, 포화된 점토의 유전 특징은 불포화 점토와는 달리 흙 표면에서 발생하는 분극현상에 의하여 크게 영향을 받는 것으로 나타났다.

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Effects of Humic Acid on the pH-dependent Sorption of Europium (Eu) to Kaolinite (PH 변화에 따른 카올리나이트와 유로퓸(Eu)의 흡착에 대한 휴믹산의 영향)

  • Harn, Yoon-I;Shin, Hyun-Sang;Rhee, Dong-Seok;Lee, Myung-Ho;Chung, Euo-Cang
    • Journal of Soil and Groundwater Environment
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    • v.14 no.4
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    • pp.23-32
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    • 2009
  • The sorption of europium (Eu (III)) onto kaolinite and the influence of humic acids over a range of pH 3 ~ 11 has been studied by batch adsorption experiment (V/m = 250 : 1 mL/g, $C_{Eu(III)}\;=\;1\;{\times}\;10^{-5}\;mol/L$, $C_{HA}\;=\;5{\sim}50\;mg/L$, $P_{CO2}=10^{-3.5}\;atm$). The concentrations of HA and Eu(III) in aqueous phase were measured by UV absorbance at 254nm (e.g., $UV_{254}$) and ICP-MS after microwave digestion for HA removals, respectively. Results showed that the HA sorption onto kaolinite was decreased with increasing pH and their sorption isotherms fit well with the Langmuir adsorption model (except pH 3). Maximum amount ($q_{max}$) for the HA sorption at pH 4 to 11 was ranged from 4.73 to 0.47 mg/g. Europium adsorption onto the kaolinite in the absence of HA was typical, showing an increases with pH and a distinct adsorption edge at pH 3 to 5. However in the presence of HA, Eu adsorption to kaolinite was significantly affected. HA was shown to enhance Eu adsorption in the acidic pH range (pH 3 ~ 4) due to the formation of additional binding sites for Eu coming from HA adsorbed onto kaolinite surface, but reduce Eu adsorption in the intermediate and high pH above 6 due to the formation of aqueous Eu-HA complexes. The results on the ternary interaction of kaolinte-Eu-HA are compared with those on the binary system of kaolinite-HA and kaolinite-Eu and adsorption mechanism with pH was discussed.

Interpretation of Electrical Resistivity Tomogram with Contents of Clay Minerals for the Land Creeping Area (점토광물 함유량을 고려한 땅밀림 산사태 지역의 전기비저항 자료의 해석)

  • Kim, Jeong-In;Kim, Ji-Soo;Lee, Sun-Joong;Cho, Kyoung-Seo;Kim, Jong-Woo
    • The Journal of Engineering Geology
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    • v.31 no.2
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    • pp.187-197
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    • 2021
  • Clay mineral content of weathered zone is a key parameter for landslide studies. Electrical resistivity tomography is usually performed to delineate the geometry of complex landslides and to identify the sliding surface. In clay-bearing weathered zone, parallel resistivity Archie equation is employed to investigate the effect of conductivity added (resistivity reduced) by clay minerals of kaolinite and montmorillonite, which is dependent on their specific surface area and cation exchange capacities (CEC). A decrease of overall resistivity and apparent formation factor is observed with increasing pore-water resistivity, significantly in montmorillonite. Formation factor is found decreased with increasing porosity and decreasing cementation factor. Parallel Archie equation was applied to the electrical resistivity data from the test area (Sinjindo-ri, Taean-gun, Chungcheongnam-do, Korea) which experienced land creeping in the year of 2014. A panel test with varying clay-mineral contents provides the best fit section when the theoretical section constructed with the assumed contents approaches the field section, from which the clay-mineral content of the weathered zone is estimated to be approximately 10%. Resistivity interpretation schemes including the clay mineral contents for land creeping studies explored in this paper can be challenged more when porosity, saturation, and pore-water resistivity are provided and they are included in the numerical resistivity modeling.

Thermal Conductivity Measurement of Saturated Clayey Mixtures using Oedometer Consolidation and Constant Rate of Strain Consolidation Tests (표준압밀시험 및 일정변형율 압밀시험 결과를 이용한 포화된 혼합 점성토의 열전도계수 측정에 관한 실험적 연구)

  • Kim, HakSeung;Kwon, HyungSeok;Lee, Jangguen;Cho, Nam Jun;Kim, Hyun-Ki
    • The Journal of Engineering Geology
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    • v.22 no.3
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    • pp.275-281
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    • 2012
  • Thermal distribution in soils must be considered in engineering designs and constructions, including estimates of frost heave and thaw settlement, infrastructure in cold regions, and geothermal systems. Because thermal conductivity is a key parameter for evaluation of thermal distribution in soils, it must be accurately estimated. The thermal conductivity of fine-grained soils has been widely studied in recent years; however, few studies have reported a reliable method for experimental measurement. The present study presents the results of an experimental investigation of the thermal conductivity of a saturated kaolinite-silica mixture with respect to the variation of dry density. Thermal conductivities were measured in Constant Rate of Strain (CRS) consolidation tests, and the experimental data were analyzed to evaluate the accuracy of the new measurement system. In addition, we present an evaluation method for predicting thermal conductivity in fine-grained soils.

Thermal Conductivity of Saturated Unfrozen Kaolinite during Consolidation (포화된 카올리나이트의 압밀에 따른 열전도계수에 관한 연구)

  • Kim, Hak-Seung;Lee, Jang-Guen;Kang, Jae-Mo;Kim, Young-Seok;Hong, Seung-Seo
    • The Journal of Engineering Geology
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    • v.21 no.2
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    • pp.157-162
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    • 2011
  • Experimental tests have been performed to measure the thermal conductivity of unsaturated soils, and computational models have been widely used to predict thermal conductivity. However, measured values of the thermal conductivity of unsaturated soils cannot be compared with predicted values because of the gradient in moisture content within unsaturated soils. In this study, experimental consolidation tests on saturated unfrozen kaolinite were performed to investigate the effect of dry density and moisture content on thermal conductivity. The results were used to evaluate the validity of a model employed to calculate thermal conductivity.

Origin of B, Br and Sr in Groundwater from Bukahn-myeon, Yeongcheon, Gyeongbuk Province, with Emphasis on Hydrochemistry (지하수의 수질화학적 특징과 붕소, 브롬, 스트론튬 성인에 대한 고찰)

  • Choo, Chang-Oh;Lee, Jin-Kook;Lee, Chang-Joo;Park, Ki-Ho;Jeong, Gyo-Cheol
    • The Journal of Engineering Geology
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    • v.19 no.2
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    • pp.235-250
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    • 2009
  • Environmental elements such as B, Br, and Sr in groundwater from Bukahn-myeon, Yeongcheon, Gyeongbuk Province, were investigated in order to know their origin with emphasis on hydrochemistry. pH ranges from 7.37 to 8.39. B content is 0.41${\sim}$4.62 mg/L with an average 1.74 mg/L and Br content is 0${\sim}$3.24 mg/L with an average 2.22 mg/L, and Sr content is 0.93${\sim}$8.64 mg/L with an average 2.76 mg/L. The water types plotted by the Piper diagram are different but mostly $Ca-HCO_3$. Some constituents contributing to EC are Na, $SO_4$, Cl with high determinative coefficients($R^2$) of 0.85, 0.70, 0.90, respectively. The coefficients($R^2$) of Cl to Na, K, $SO_4$ are 0.54, 0.68, 0.53, respectively. It should be noted that there are high cocfficients($R^2$) of B-Sr and $Sr-SO_4$ with 0.65, 0.64, respectively. The Cl/Br ratios are 5.21${\sim}$30.70 due to significant depletion of Cl. The $SO_4/Cl$ ratios are 1.32${\sim}$27.24 with an average of 5.92, ascribed to abundant introduction of $SO_4$ or significant depletion of Cl. Chemical speciation calculated shows that B exists mostly as $H_3BO_3$ with less $H_2BO^-_3$ and Br exists as only $Br^-$. Sr exists mostly as $Sr^2$ with less $SO_4$. Saturation index represents that goundwater is supersaturated with respect to barite, kaolinite, illite, K-mica, and smectite while it is slightly undersaturated with respect to silica, gypsum, anhydrite, talc, chrysotile, feldspar, kaolinite, illite, K-mica, and smectite. The saturation index of celestine is -2.23${\sim}$-0.13 indicating more Sr can be incorporated into groundwater. Groundwater is still much undersaturated to halite. It is likely that the origin of S and Sr was related to the Yucheon volcanic rocks. Br might be originated from the local geological features with introduction of anthropogenic matters.

Hydrochemistry of Groundwater at Natural Mineral Water Plants in the Okcheon Metamorphic Belt (옥천계변성암 지역의 먹는샘물 지하수의 수리지구화학적 특성)

  • 추창오;성익환;조병욱;이병대;김통권
    • Journal of Korea Soil Environment Society
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    • v.3 no.3
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    • pp.93-107
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    • 1998
  • Because of its stable quantity and quality, groundwater has long been a reliable source of drinking water for domestic users. Rapid economic growth and rising standards of living have in recent years put severe demands on drinking water supplies in Korea. Groundwaters that are currently being used for natural mineral water were hydrochemically evaluated and investigated in order to maintain their quality to satisfy strict health standards. There exist 15 natural mineral water plants in the Okcheon metamorphic belt. Characteristics of groundwaters are different from those of other areas in that electrical conductivity, hardness, contents of Ca, Mg and $HCO_3$are relatively high. The content of major cations is in the order of Ca>Mg, Na>K, whereas that of major anions shows the order of $HCO_3$>$SO_4$>Cl>F. The fact that the Ca-Mg-HCO$_3$type is mostly predominant among water types reflects that dissolution of carbonates that are abundantly present in the metamorphic rocks plays an important part in groundwater chemistry. Representative correlation coefficients between chemical species show Mg-$HCO_3$(0.92), Ca-$HCO_3$(0.88), Ca-Mg(0.80), Ca-Cl(0.78), Mg-$SO_4$(0.78), Ca-$SO_4$(0.71), possibly due to the effect by dissolution of carbonates, gypsum or anhydrite. Determinative coefficients between some chemical species represent a good relationship, especially for EC-(K+Na+Ca), Ca-$HCO_3$, Ca-Mg, indiacting that they are similar in chemical behaviors. According to saturation index, most chemical species are undersaturated with respect to major minerals, except for some silica phases. Groundwater is slightly undersaturated with respect to calcite and dolomite, whereas it is still greatly undersaturated with respect to gypsum, anhydrite and fluorite, Based on the Phase equilibrium in the systems $NA_2$O-$Al_2$$O_3$-$SiO_2$-$H_2$O and $K_2$O-$Al_2$$O_3$-$SiO_2$-$H_2$O, it is clear that groundwater is in equilibrium with kaolinite, evolved from the stability area of gibbsite during water-rock interaction. It is expected that chemical evolution of groundwater continue to proceed with increasing pH by reaction of feldspars, with calcite much less reactive.

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