• Title/Summary/Keyword: 포름알데하이드

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New Catalyst for Durable Press Finish of Cotton Fabrics Treated with Glyoxsl (Glyoxal 처리에 의한 면직물의 DP가공시 새로운 촉매)

  • 유영하;방은숙;김승일;이의소
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.04a
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    • pp.423-424
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    • 2003
  • 셀룰로스 직물은 easy care 성능을 부여하기 위하여 가교제로 처리된다. 현재 공업적으로 가장 많이 이용되고 있는 DMDHEU와 같은 N-methyol 가교제는 공정 중 또는 처리된 제품의 저장 중에 발암물질인 포름알데하이드를 유리시키는 경향이 있어 포름알데하이드를 유리시키지 않는 가교결합제의 개발이 활발하게 연구되고 있다. 이러한 비포르말린계 가교제 중 글리옥살은 그 성능은 매우 뛰어나지만 DP 처리시 사용되는 촉매인 aluminium sulfate는 처리직물의 강도저하와 황변을 일으키는 단점을 지니고 있다[1]. (중략)

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Measurements of HCHO during ozone intensive study in Seoul, 2001 (2001년 서울시 오존 집중 측정 시기 HCHO의 측정)

  • 홍상범;김규수;이재훈
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2002.04a
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    • pp.319-320
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    • 2002
  • 포름알데하이드(HCHO)는 보건학적인 영향과 광화학 스모그 형성과정의 중요한 역할로 인해 많은 연구의 대상이 되어왔다. 포름알데하이드(HCHO)의 도심지 대기 환경에서 가장 중요한 인위적인 발생원은 산업활동 및 자동차의 배기가스이며 식물의 연소과정(biomass burning)에서도 방출되는 것으로 알려져 있다. 또한 대기환경에 존재하는 휘발성 유기화합물들과 OHㆍ과의 광 화학적 산화과정을 통하여 2차적으로 형성된다. 한편, 주요 소멸과정으로는 광분해(photolysis) 과정과 OHㆍ과의 반응이다. (중략)

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Effect of Additives on Durable Press Cotton Fabrics with Glyoxal-Aluminium Ammonium Sulfate (Glyoxal-Aluminium Ammonium Sulfate에 의한 DP가공에서 첨가제의 영향)

  • 유영하;방은숙;김승일;이의소
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10b
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    • pp.84-87
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    • 2003
  • 셀룰로즈 직물은 easy care 성능을 부여하기 위하여 가교제로 처리된다. 현재 공업적으로 가장 많이 이용되고 있는 DMDHEU와 같은 N-methyol계 가교제는 공정 중 또는 처리된 제품의 저장 중에 발암물질인 포름알데하이드를 유리시키는 경향이 있어 포름알데하이드를 유리시키지 않는 가교결합제의 개발이 활발하게 연구되고 있다. 이러한 비포르말린계 가교제 중 글리옥살은 그 성능은 매우 뛰어나지만 DP 처리시 사용되는 촉매인 aluminium sulfate는 처리직물의 강도저하와 항변을 일으키는 단점을 지니고 있다[1]. (중략)

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Determination of Trace Amounts of Formaldehyde in Water Using High Performance Liquid Chromatography and Acetylacetone as a Derivative Reagent (아세틸아세톤 유도체화 시약과 HPLC를 이용한 미량 포름알데하이드 수질분석)

  • Lee, Ki-Chang;Park, Jae-Hyung;Lee, Wontae
    • Journal of Korean Society of Environmental Engineers
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    • v.37 no.2
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    • pp.81-86
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    • 2015
  • A simple analytical method to quantify formaldehyde in water at lower levels (${\mu}g/L$) was developed using a high performance liquid chromatography (HPLC) and acetylacetone as a derivative reagent. Unlike conventional methods, no extraction and/or concentration were required. The derivative reagent was added into samples and reacted for 30 minutes at $80^{\circ}C$ prior to the analysis of formaldehyde using HPLC. The method detection limit and the limit of quantification for this method were 1.6 and $5.0{\mu}g/L$, respectively. This method also achieved high precision (0.6-3.0%) and accuracy (91.6-106.3%). The recovery rates for various environmental samples ranged from 92.0 to 115.2%.

First-time estimation of HCHO column in major cities over Asia using multiple regression with satellite data (위성자료와 다중회귀분석법을 이용한 아시아 주요도시의 포름알데하이드 칼럼농도 추정연구)

  • Choi, Wonei;Hong, Hyunkee;Park, Junsung;Lee, Hanlim
    • Korean Journal of Remote Sensing
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    • v.31 no.6
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    • pp.523-530
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    • 2015
  • A Multiple Regression Method (MRM) is used for the first time with Ozone Monitoring Instrument (OMI) and Moderate Resolution Imaging Spectroradiometer (MODIS) data to estimate formaldehyde (HCHO) Vertical Column Density (VCD). For a 3.5-year period from January 2005 through July 2008, HCHO VCD estimation is investigated in cities over Asia in two categorized areas: (1) Major cities in Northeast Asia (Beijing, Seoul, and Tokyo), (2) Major cities in Southeast Asia (New Delhi, Dhaka, and Bangkok). In the Major cities in Northeast Asia, there are good agreements between HCHO estimated by the multiple linear regression method ($HCHO_{MRM}$) and HCHO measured by OMI ($HCHO_{OMI}$) (0.78 < $R^2$ < 0.82). However, in Major cities in Southeast Asia, there were poor agreements between $HCHO_{OMI}$ and $HCHO_{MRM}$ (0.24 < $R^2$ < 0.39). In addition, an unbiased assessment of the MRM performance using modeling and validation groups shows that the performance of the MRM based on separate modeling and validation groups is comparable to that using all the data for deriving Multiple Regression Equations (MREs). This study demonstrates that MRM can be an alternative tool for HCHO estimation in certain areas over Asia.

The study on the measurement of formaldehyde in saliva and urine by GC-MS (가스크로마토그래프-질량분석기에 의한 타액 및 뇨 중 포름알데하이드 분석법 연구)

  • Shin, Ho-Sang;Ahn, Hye-Sil
    • Analytical Science and Technology
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    • v.19 no.2
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    • pp.149-154
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    • 2006
  • A gas chromatography-mass spectrometric method was developed for the determination of formaldehyde in urine and saliva. In a 20 mL glass tube, 0.2 mL of urine or saliva was taken. Further, 1.8 mL of 0.1 M HCl, 0.1 mL of 2,000 mg/L 2,4-dinitrophenyl hydrazine and $20{\mu}l$ of 500 mg/L acetone-$d_6$ as internal standard were added in the tube and sealed tightly with cap. The solution was shaken for 20 min at room temperature and extracted using 4 mL of toluene. The extract was concentrated and redissolved with $100{\mu}l$ of acetonitrile, and then measured by gas chromatography-mass spectrometer (selected ion monitoring). The detection limit was 2.0 ng/mL and 0.5 ng/mL in saliva and urine, respectively. The calibration curves showed good linearity with r = 0.997 and 0.998 for saliva and urine, respectively. The method was used to analyze formaldehyde in rat urine after oral exposure. The developed method may be use ful to the monitoring for formaldehyde exposure in human.