• Title/Summary/Keyword: 폐실리콘

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Chromaticity Improvement of PEG Waste from Wire Sawing of Silicon Ingot (실리콘 잉곳 절삭시 발생하는 폐 PEG 색도 개선에 관한 연구)

  • Cho, Yun-Kyeong;Jung, Kyeong-Youl;Sim, Min-Seok;Lee, Gi-Ho
    • Korean Chemical Engineering Research
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    • v.50 no.2
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    • pp.310-316
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    • 2012
  • The chromaticity of polyethylene glycol (PEG) generated from the recyling of a silicone slurry waste was improved by using activated carbon powder and a carbon filter. The color change of the PEG waste was investigated by changing the amount of adsorbent, adsorption time and temperature. The surface area of activated carbon did not have a significant impact on improving the color of the PEG waste. According to the results for the APHA color variation of the PEG waste changing the amount of the carbon adsorbent, the optimal usage to achieve the low APHA value was 100~150 mg-C/g-PEG. From the investigatnion on the effect of the adsorption temperature range from $25^{\circ}C$ to $100^{\circ}C$, it was found that the optimal temperatures were $40{\sim}50^{\circ}C$ in terms of achieving the lowest APHA value. The variation of the APHA color was investigated by changing the operation condition of the activated carbon filters. The use of ACF was a good way to enhance the chromaticity of the PEG waste. As a result, the APHA value of the PEG waste (APHA=53 at the initial waste) was reduced to be 10 through the ACF purification. It was also confirmed that the performance of the used carbon adsorbent can be recovered by the washing with purified water.

Recycling of End-of-Life Photovoltaic Silicon Modules (사용 후 태양광 실리콘 모듈의 리싸이클링)

  • Kim, Joon Soo;Cho, Jae Young;Lee, Jae Kyung;Park, Areum;Park, Jin Hyuk;Yun, Hyun Mok;Jun, Yun-Su
    • Resources Recycling
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    • v.28 no.5
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    • pp.19-29
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    • 2019
  • Recently, it is increasing a amount of installized solar-cell rapidly, and waste Solar cell module are generated in according to the reduction of efficiency largely. Therefore, it is concerned at the environmental problems and recycling of valuable materials, greatly. The treatment processes of end-of-life photovoltaic modules are composed the disassembly of Aluminum frames, separation of Tempered glass, removal of Ethylene Vinyl Acetate and recovery of valuable Metals. For the efficient recycling, we are considered to the treatment technology seriously. And we are proposed on the general opinions according to the developing technology, EPR (Extended Producer Responsibility) problems and promotion plans for the activation of recycling industry.

산화철 폐촉매를 사용한 NiZn-페라이트웨 합성 및 자기적 특성

  • Park, Sang-Il;Hwang, Yeon;Lee, Hyo-Sook
    • Proceedings of the Korea Crystallographic Association Conference
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    • 2003.05a
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    • pp.26-26
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    • 2003
  • 산업 폐기물로서 전량 매립되고 있는 styrene monomer (SM) 공정에서 발생되는 산화철 폐촉매를 사용하여 NiZn-페라이트를 합성하였고, 그 자기적 특성을 조사하였다. 평균입경 0.5㎛로 미분쇄된 산화철 폐촉매에 NiO 및 ZnO를 혼합하여 900℃에서 하소한후 1230℃에서 5시간 동안 소결하여 스핀넬형 페라이트 소결체를 얻었다. Ni/sub x/Zn/ub 1-x/Fe₂O₄(x=0.36, 0.50, 0.66) 및 (Ni/sub 0.5/Zn/sub 0.5/)/sub 1-y/Fe/sub 2+y/O₄(y=-0.02, 0, 0.02) 조성에 대하여 초투자율을 측정하였다. S-parameter를 측정하여 반사 감쇄량을 계산하였다. Ni/sub 0.5/Zn/sub 0.5/fe₂O₄ 조성의 경우 밀도 5.38 g/㎤ kHz에서의 초투자율이 59인 특성을 얻었다. 산화철 폐촉매를 이용하여 X-band 주파수 영역에서 높은 전자파 흡수능을 갖는 전파흡수체를 제조할 수 있음을 확인하였다. Ni/sub 0.5/Zn/sub 0.5/Fe₂O₄ 조성에 대하여 1100℃에서 하소한 분말을 사용하여 실리콘 고무에 복합시킨 후 전파흡수능을 측정하였다. 폐촉매에는 산화철 이외에 CeO₂가 주된 첨가물로 함유되어 있어서 페라이트의 합성 후에도 2차상으로서 존재하였다. 출발 원료인 산화철 폐촉매에 존재하는 K₂O 및 CeO₂를 제거하기 위하여 산처리와 분산제를 이용한 CeO₂ 분리과정을 행하였다. 정제된 산화철 폐촉매에 NiO 및 ZnO를 혼합하여 900℃에서 하소하여 스핀넬형 페라이트를 합성하고 1325℃에서 5시간 소결하였다. 위와 마찬가지로 Ni/sub x/Zn/sub 1-x/Fe₂O₄(x=0.36, 0.50, 0.66)과 (Ni/sub 0.5/Zn/sub 0.5/)/sub 1-y/Fe/sub 2+y/O₄(y=-0.02, 0, 0.02) 조성에 대하여 자기적 특성을 조사하였다.화된 중성자빔으로 측정하였다 BPC-Si를 구부려 슬랩의 곡률반경을 변화시키면서 단색기-시료-검출기가 평행파 반평행배치일 때 Cu(111), (200), (220), (311), (331), (420)면의 회절선을 측정하여 각 조건에서 분해능과 강도를 평가하였다.료의 가시적 변화를 통해 illumination angle 1.25mrad(Dose rate : 334 × 10³ e/sup -//sec·n㎡)일 경우 약 3초 이내에 비정질화가 시작됨을 알 수 있었고 이는 약 1 × 10/sup 6/ e/sup -//sec·n㎡ 의 전자선량에 해당되며 이를 기준으로 각각의 illumination angle에 대한 임계전자선량을 평가할 수 있었다. 실질적으로 Cibbsite와 같은 무기수화물의 직접가열실험 시 전자빔 조사에 의해 야기되는 상전이 영향을 배제하고 실험을 수행하려면 illumination angle 0.2mrad (Dose rate : 8000 e/sup -//sec·n㎡)이하로 관찰하고 기록되어야 함을 본 자료로부터 알 수 있었다.운동횟수에 의한 영향으로써 운동시간을 1일 6시간으로 설정하여, 운동횟수를 결정하기 위하여 오전, 오후에 각 3시간씩 운동시키는 방법과 오전부터 6시간동안 운동시키는 두 방법을 이용하여 품질을 비교하였다. 각 조건에 따라 운동시킨 참돔의 수분함량을 나타낸 것으로, 2회(오전 3시간, 오후 3시간)에 나누어서 운동시키기 위한 육의 수분함량은 73.37±2.02%를 나타냈으며, 1회(6시간 운동)운동시키기 위한 육은 71.74±1.66%을 나타내었다. 각각의 운동조건에서 양식된 참돔은 사육초기에는 큰 변화가 없었으나, 사육 5일 이후에는 수분함량이 증가하여 15일에는 76.40±0.14, 75.62±0.98%의 수분함량을 2회와 1회 운동시킨 참돔의 육에서 각각 나타났다. 운동횟수에 따른 지질함량은 2회 운동시킨 참돔은 5.83±2.08, 1회 운

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Blood Compatibility of Hollow Fiber Membranes Treated by Plasma Polymerization (플라즈마 중합 처리된 중공사 막의 혈액 적합성)

  • Lee, Sam-Cheol;Kwon, O-Sung
    • Membrane Journal
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    • v.15 no.3
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    • pp.233-240
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    • 2005
  • Surface modification of polypropylene hollow fiber membranes was performed in order to develop blood-compatibility biomaterials for use in the blood contacting surfaces and oxygenation membranes of a lung assist device (LAD), important medical device even more useful. Blood compatibility of materials was determined by using anticoagulation blood and evaluating formation of blood clots on their surfaces as well as activation of plasma coagulation cascade, platelet adhesion, and aggregation. It was verified that the number of platelets on the silicone coated fibers was significantly lower than that on untreated fiber membrane, indicating improved blood compatibility. It was also found that the polypropylene hollow fiber membranes using plasma treatment exhibited suppression of complement activation in blood compatibility test.

Recovery of Metallurgical Silicon from Slurry Waste (Wafer Sawing 공정의 폐슬러리로부터 금속 실리콘 회수에 관한 연구)

  • Kim, Jong-Young;Kim, Ung-Soo;Hwang, Kwang-Taek;Cho, Woo-Seok;Kim, Kyung-Ja
    • Journal of the Korean Ceramic Society
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    • v.48 no.2
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    • pp.189-194
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    • 2011
  • Metallurgical grade silicon was recovered from slurry waste for ingot sawing process by acid leaching and thermal treatment. SiC abrasive was removed by gravity concentration and centrifugation. Metal impurities were removed by the acid leaching using HF/HCl. The remaining SiC was separated by the thermal treatment at $1600^{\circ}C$ in an inert atmosphere by the difference in melting points. The purity of the obtained silicon was found to be around 99.7%.

Melting and Refining of Cu Powder Scraped from Waste PCB with Fe2O3 (Fe2O3 첨가에 의한 폐PCB로부터 긁어낸 Cu분말의 용융 및 정제)

  • Heo, Su-Bin;Sohn, Ho-Sang
    • Resources Recycling
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    • v.26 no.4
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    • pp.95-100
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    • 2017
  • In this study, $Fe_2O_3$ was added as a flux to decrease melting temperature and refine during melting of Cu powder from scraped surface of the waste PCB (printed circuit board). The effect of $Fe_2O_3$ ratio to Cu powder and temperature on the recovery of Cu and content of impurities were investigated. It was found that the recovery of Cu was increased with increasing addition ratio of $Fe_2O_3$ and reaction temperature. The contents of O, Si and Fe in Cu phase were also decreased with increasing addition ratio of $Fe_2O_3$ and temperature. The formation of fayalite ($2FeO{\cdot}SiO_2$) and iron oxides phases in the slag was confirmed by XRD analysis after reaction with $Fe_2O_3$. Therefore, it was considered that the decrease of melting temperature and viscosity of slag by formation of fayalite slag contributed remarkably to the Cu recovery.

Studies of Physicochemical Properties of Baby Powder Developed from Rice-flour (쌀 분말을 이용한 유아용 파우더의 이화학적 특성 연구)

  • Han, Sang-Ik;Jang, Ki Chang;Seo, Woo Duck;Oh, Seong-Hwan;Ra, Ji-Eun;Song, Yu-Cheon;Lee, Jong-Hee;Kim, Byung-Joo;Nam, Min-Hee;Lee, Jin-Tae
    • Journal of Life Science
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    • v.23 no.7
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    • pp.879-885
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    • 2013
  • Baby powder is an astringent powder used to prevent diaper rash. It also has other cosmetic uses. In general, it is composed of talc powder (talcum powder). Talc powder is harmful if inhaled because it can cause significant lung damage. With the aim of developing a new rice-based baby powder, three kinds of rice varieties were selected and pulverized. To determine the cost-effectiveness of the different states of rice powder, several milling processes were tried, and the powder characteristics of the resulting rice powder, such as particle size, biological activities, digitalized color value, and moisture content before and after coating treatment with essential oil and silicon oil, were examined. "Goami" showed good flour characteristics with respect to lightness (92.0, $L^*$[D65] value) and particle size ($8.9{\mu}m$). SEM analysis showed that the rice powder particles coated in the essential oil and silicon oil showed a smoother and rounder appearance than those of the talc powder. In addition, the average particle size was decreased by the essential oil and silicon oil coating. The silicon oil coating solved the problem of moisture absorption in rice flour. Rice flour properly coated with essential oil and silicon oil shows great potential as a new material source of powder.

대기압 플라즈마 소스로 식각한 Wafer 반사율 분석

  • Gwon, Hui-Tae;Lee, Ye-Seul;Hwang, Sang-Hyeok;Jo, Tae-Hun;Yang, Chang-Sil;Gwon, Gi-Cheong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.403.1-403.1
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    • 2016
  • 일반적으로 실리콘 태양전지의 표면 텍스쳐링 공정방식은 습식 텍스쳐링 방식과 건식 텍스쳐링 방식 2가지로 나뉘어진다. 하지만 현재 습식 텍스쳐링 방식의 경우 Solution을 사용하기 때문에 폐용액으로 인한 환경오염 및 Wafer 오염과 같은 단점을 가지고 있다. 또한 건식 텍스쳐링 방식의 경우는 진공 상태에서 진행되므로 높은 유지 비용이 가장 큰 단점으로 대두 되고 있다. 그러므로 기존의 방식과 다르게 진공을 사용하지 않는 대기압 플라즈마 소스를 텍스쳐링 공정에 적용하였다. 본 연구에서는 대기압 플라즈마 소스로 식각한 Wafer의 반사율을 가스 종류와 유량별 측정하여 분석하였다. 측정된 반사율을 통해 대기압 플라즈마 소스가 텍스쳐링 공정에 적용할 수 있는지 확인하였다.

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Development of Composite Sr Ferrite EM Wave Absorbers for GHz Frequency (GHz 대역용 복합형 Sr 페라이트 전파 흡수체의 개발)

  • Kim, Dong-Il;Moon, Sang-Hyun;Shin, Sung-Jae;Song, Jae-Man;Kim, Ki-Man
    • Journal of Navigation and Port Research
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    • v.28 no.6
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    • pp.503-507
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    • 2004
  • We prepared EM wave absorbers by using recycled Sr ferrite for GHz frequency, and investigated the effects of carbon additions and preparation temperatures on their EM wave absorption properties. A Sr ferrite EM wave absorber with the ratio of Sr ferrite: silicon rubber: carbon = 80 : 13.6: 6.4 wt% prepared at 7$0^{\circ}C$ showed -24 dB at 9.4 GHz and -23 dB at 5.5 GHz for 2 mm and 3 mm thickness, respectively.

Effect of Initial Silicon Scrap Size on Powder Refining Process During High Energy Ball Milling (HEBM) (폐실리콘의 고에너지 밀링 과정에서 초기 입자 크기가 분말의 미세화에 미치는 효과)

  • Song, Joon-Woo;Kim, Hyo-Seob;Kim, Sung-Shin;Koo, Jar-Myung;Hong, Soon-Jik
    • Journal of Powder Materials
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    • v.17 no.3
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    • pp.242-250
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    • 2010
  • In this research, the optimal manufacturing conditions of fine Si powders from Si scrap were investigated as a function of different initial powder size using the high-energy ball milling equipment, which produces the fine powder by means of an ultra high-energy within a short duration. The morphological change of the powders according to the milling time was observed by Scanning electron microscopy (SEM). With the increasing milling time, the size of Si powder was decreased. In addition, more energy and stress for milling were required with the decreasing initial powder size. The refinement of Si scrap was rapidly carried out at 10min ball milling time. However, the refined powder started to agglomerate at 30 min milling time, while the powder size became uniform at 60 min milling time.