• Title/Summary/Keyword: 폐수 처리

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A Study on the sludge drying using waste heat of cogeneration plant (열병합발전소 보일러 폐열을 이용한 슬러지 건조 연구)

  • Ryu, Seung-Han;Lee, Sang-Hun;Shin, Dong-Hoon;Park, Jun-Hyung;Jo, Suk-Jin;Kwak, Sung-Sik;Woo, Young-Hoon;Jeon, Jong-Seok
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2011.11a
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    • pp.60-60
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    • 2011
  • 염색폐수의 정화에는 필연적으로 다량의 슬러지 폐기물이 발생한다. 염색폐수 슬러지는 그간 인근 공해 해상에 투기하는 해양 배출로 저렴하게 처리하였으나, 해양오염을 우려하는 국제협약(1972년 런던협약, 1996년 교토의정서)에 의하여 2008년 8월부터 배출기준이 강화되고 2012년 2월부터는 해양배출이 금지 될 예정이다. 염색폐수 슬러지의 해양 배출이 금지되면 대체 처리방법으로는 지정매립장을 통한 매립처리 방법이나 고온 소각시설에서의 소각처리 방법이 거론되고 있다. 그러나 매립처리는 슬러지 내 함유 수분으로 인한 침출수의 문제와 더불어 장기간 안정적으로 저렴하게 사용할 수 있는 대규모 처분장을 확보하기 어려운 실정이며 소각처리는 슬러지의 높은 함수율로 인해 소각 시보조 연료의 투입이 필연적으로 최근 원유가 급등 등 에너지 비용이 지속적으로 상승함을 고려할 때 소각처리비용 또한 상당한 고가가 될 것으로 예측된다. 이와 같이 슬러지 해양배출이 금지되면 섬유 염색업체들은 많은 환경비용 부담을 안을 것이다. 본 연구에서는 대규모 염색산업단지 공동폐수처리장에서 발생하는 염색폐수 슬러지의 효율적인 건조를 위해 산업단지 내의 열병합발전소에서 발생하는 보일러 폐열을 이용하였으며, 조건 특성 및 효율을 파악하기 위해 보일러 폐열의 특성을 고려하여 슬러지 두께 및 체류시간 등 건조공정 운영조건에 따른 변수별 연구를 수행하였다. 열병합발전소 보일러에서 배출되는 폐열은 온도가 $150^{\circ}C$ 정도로 기존의 슬러지 건조에서는 사용되는 $700^{\circ}C$에 비해서는 매우 저온이다. 하지만 보일러 배가스의 경우, 온도에 비해 많은 풍량을 가지고 있으므로 열량으로 환산시 충분히 가치가 있는 것으로 조사되었다. 염색폐수 슬러지의 경우, 함수율 70% 이내의 탈수 Cake 형태이므로 두께가 두꺼울수록 건조효율이 감소하였으며, 체류시간이 길어질수록 건조효율은 증가하나 20mm 이상에서는 건조효율이 급격히감소하였다. 이를 바탕으로 5톤/일 규모 슬러지 건조 Pilot Plant를 제작하여 운영하였는데, 염색폐수슬러지의 투입공정에서 슬러지와 열풍의 접촉면적을 넓혀 건조효율을 높이기 위하여 슬러지를 압출노즐을 이용하여 슬라이스 칩 형태로 제조하여 건조공정에 투입하였으며, 건조실 내에서도 건조효율의 상승을 위하여 내부열풍순환팬을 설치하여 운영하였다. Pilot 운영결과, 체류시간 52분에서 슬러지의 함수율은 70%에서 10%이하로 감소하였다.

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Nitrogen Removal in Livestock Wastewater Using Sequencing Batch Reactor (SBR을 이용한 축산폐수의 질소 제거)

  • Shin, Hang-Sik;Kim, Ku-Yong;Lee, Sang-Hyung;Lim, Jae-Lim
    • Journal of the Korean GEO-environmental Society
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    • v.4 no.3
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    • pp.61-67
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    • 2003
  • A new precess which consists of pre-dewatering device, post composting for solid phase and post sequencing batch reactor(SBR) for liquid phase was designed. Nitrogen in supernatants of dewatering device was removed by sequencing batch reactor. Experiments were carried out to investigate the SBR operation modes such as fill ratio, SRT, and operation cycle. The optimum fill ratio, SRT and aeration/non-aeration time were 1/12, 15days, and 2hr aeration / 1hr non aeraion, respectively. Methanol as an external carbon source increased denitrification when step feeding method was applied, not single feeding method.

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Seasonal Effects of Livestock Wastewater Treatment by a Constructed Wetland (인공습지에 의한 축산폐수의 처리시 계절적 영향)

  • Park, Jae-Hong;Kwon, Soo-Youl
    • Journal of Wetlands Research
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    • v.7 no.3
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    • pp.33-39
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    • 2005
  • Constructed wetlands are considered as an important tool for wastewater treatment, wastewater management and flooding control. In addition, one of the most promising technologies for application in many countries seems to be constructed wetlands due to their properties such as utilization of natural processes, simple construction, operation and maintenance, process stability, cost effectiveness, etc. This research is performed to find the possibility for treating livestock wastewater using a constructed wetland. The removal efficiencies of CODcr, TN, TP, SS, and color were 97.9%, 97.8%, 97.2%, 99.1%, and 84.9%, respectively. In particular, SS was completely removed. In conclusion, constructed wetlands could be applied to livestock wastewater treatment. Further, it needs time for stabilization to reduce the pollutants accumulated in soil.

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Oily Wastewater Treatment by Ceramic Membrane: A Review (세라믹 멤브레인을 통한 함유폐수의 처리: 리뷰)

  • Kwak, Yeonsoo;Rajkumar, Patel
    • Membrane Journal
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    • v.32 no.5
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    • pp.265-274
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    • 2022
  • Separation of oily wastewater, which is a byproduct of various industries such as petroleum refineries, is essential to not exceed the tolerance limit of wastewater streams. Ceramic membranes show potential in oily wastewater separation, due to their excellent oil removal efficiency, good chemical, thermal, and mechanical stability, and simple operation. However, widespread application of ceramic membranes is limited due to high material cost of alumina, silica, and other ceramic based materials used to fabricate them. Recent efforts to reduce material cost have been made, using fly ash and clay. This review examines the fabrication and efficiency of ceramic membranes in oily wastewater separation according to material: silica, alumina, and waste ash.

Treatment Level of a Pond System for Ecological Treatment and Recycling of Animal Excreta (생태적 축산폐수 처리 및 재활용 연못시스템의 폐수처리수준)

  • Yang, Hong-Mo;Rhee, Chong-Ouk
    • Korean Journal of Environmental Agriculture
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    • v.17 no.1
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    • pp.70-75
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    • 1998
  • A model of pond system is developed for treatment and recycling of excreta from twenty-five adult dairy cattle. It is composed of wastewater treatment ponds and small fish ponds. Those are three facultative ponds in series; primary-secondary-tertiary pond and these are designed to rear carps without feeding. A pit is constructed at the bottom of primary pond for efficient sludge sedimentation and effective methane fermentation. It is contrived to block into it the penetration of oxygen dissolved in the upper layer of pond water. The excreta from the cattle housed in stalls are diluted by water used for clearing them. The washed excreta flow into the pit. The average yearly $BOD_5$ concentration of influent is 398.7mg/l. That of the effluent from primary, secondary and tertiary pond of the system is 49.18, 27.9, and 19.8.mg/l respectively. Approximate 88, 93, and 95 % of BOD5 are removed in each pond. The mean yearly SS concentration of influent is 360.5 mg/l That of the effluent from each pond is 53.4, 45.7, and32.7mg/l respectively. Approximate 86, 88, and 91% of SS are removed in each pond. The $BOD_5$ concentration of secondary and tertiary pond can satisfy 30mg/l secondary treatment standard. The SS concentration of effluent from tertiary pond, however, is slightly greater than the standard, which results from activities of carps growing in the pond. The average yearly total nitrogen concentration of influent is 206.8mg/l and that of the effluent from each pond is 48.6, 30.8, and 21.0mg/l respectively. Approximate 74, 88, and 90% of total nitrogen are removed in each pond. The mean yearly total phosphorous concentration of influent is 20.7mg/l and that of the effluent from each pond is 5.3, 3.2, and 2.1mg/l respectively. Approximate 97, 98, and 99% of total phosphorous are removed in each pond. The high removal of nitrogen and phosphorous results from active growth of algae in the upper layer of pond water. Important pond design parameters for southern part of Korea -- areal loading of BOD5, liquid depth, hydraulic detention time, free board, and pond arrangement -- are taken up.

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Metabolic Responses of Activated Sludge to Pentachlorophenol in a SBR System (SBR 처리 장치에서 활성 슬럿지의 대사에 미치는 Pentachlorophenol의 독성 효과)

  • KIM Sung-Jae;Benefield Larry D.
    • Journal of Aquaculture
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    • v.6 no.4
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    • pp.323-338
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    • 1993
  • The primary objective of this study was to examine the toxic effects of PCP on activated sludge and to analyze its metabolic responses while treating wastewater containing pentachlorophenol (PCP) in a sequencing batch reactor (SBR) system operating under different control strategies. This study was conducted in two phases 1 and 2 (8-hr and 12-hr cycles). Each phase was operated with two control strategies I and II. Strategy I (reactor 1) involved rapid addition (5 minutes to complete) of substrate to the reactor with continuous mixing but no aeration for 2 hours. Strategy II (reactor 2) involved adding the feed continuously during the first 2 hours of the cycle when the system was mixed but not aerated. During both phases each reactor was operated at a sludge age of 15 days. The synthetic wastewater was used as a feed. The COD of the feed solution was about 380 mg/L. After the reference response for both reactors was established, the steady state response of each system was established for PCP feed concentrations of 0.1 mg/L, 1.0 mg/L, and 5.0 mg/L in SBR systems operating on both 8-hr and 12-hr cycles. Soluble COD removal was not inhibited at any feed PCP concentrations used. At 5.0 mg/L feed PCP concentration and in SBR systems operating on phase 2, the concentrations or ML VSS were decreased; selective pressure on the mixed biomass might be increased, narrowing the range of possible ecological responses; the settleability of activated sludge was poor; the SOURs were increased, showing that the systems were shocked. Nitrification was made to some extent at all concentrations of feed PCP in SBR systems operating on phase 2 whereas in SBR systems operating on phase 1 little nitrification was observed. Then, nitrification will be delayed as much as soluble COD removal is retarded due to PCP inhibition effects. Enhanced biological phosphorus removal occurring in the system operating with control strategy I during phase 1 of this work and in the presence of low concentrations of PCP was unreliable and might cease at anytime, whereas enhanced biological phosphorus removal occurring in the system operating with either control strategy I or II during phase 2 of this work and in the presence of feed PCP concentrations up to 1.0 mg/L was reliable. When, however, such processes were exposed to 5.0 mg/L PCP dose, enhanced phosphorus removal ceased and never returned.

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A Study on the Application of Heat Pump System for Heat Recovery in Dyeing Wastewater (염색폐수 열회수를 위한 열펌프시스템 적용 연구)

  • 장기창;박성룡;이영수;이상남;라호상;박준택
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 2002.05a
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    • pp.57-67
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    • 2002
  • 염색산업은 공정특성상 다량의 증기와 고온수가 필요한 에너지 다소비 산업으로 원가절감에 의한 경쟁력 향상을 위해서는 에너지사용량 절감을 위한 노력이 절실히 요구되는 산업이다. 염색가공공정은 정련, 감량 등 처리공정을 통해 조업, 생산하고 있는데, 이 공정과정에서 다량의 폐수가 발생되고 있으며, 배출된 폐수는 각 공장의 저류조에 집수 되어 공동폐수처리장으로 방류된다.(중략)

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Development of Biological Denitrification Process using Sulfur for the Wastewater Containing Low BOD (저농도 BOD함유 폐수의 황(S)을 이용한 생물학적 탈질공정 개발 (SPAD 공정))

  • 광주과학기술원, 한국과학기술원;한국과학기술원;동명산업
    • Environmental engineer
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    • v.19 s.186
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    • pp.66-73
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    • 2002
  • 우리나라 하수의 특성이 유기물 농도가 질소 농도에 비하여 매우 낮기 때문에 외국의 종속영양 탈질 공법을 그대로 적용하기가 힘들며 적용한다 할지라도 외부탄소원을 넣어야 하므로 경제적인 처리는 불가능하다. 산업폐수의 경우에 있어서도 유기물농도가 질소농도에 비하여 낮은 폐수의 경우는 값비싼 외부탄소원을 넣어주어야 한다. 따라서 폐수 특성에 맞는 효율적이고 경제적인 질소화합물 제거 기술의 개발은 불가피하다. 따라서 종속영양탈질공정의 경제성 문제 및 기존의 황탈

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방사선조사에 의한 축산폐수의 질산화 효율 향상

  • Kim, Tak-Hyeon;Kim, Tae-Hun;Lee, Jae-Gwang;Yu, Seung-Ho;Lee, Myeon-Ju
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2006.05a
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    • pp.358-360
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    • 2006
  • 축산폐수내의 질소 성분의 효율적인 처리를 위하여 생물학적 질산화반응과 방사선조사기술을 결합시키는 연구를 수행하였다. 축산폐수에 방사선을 조사하여 줌으로써 생성되는 라디칼들에 의하여 폐수내 난분해성 유기물들의 생분해도가 향상되어 짧은 HRT에도 불구하고 완전한 NH$_4^+$-N의 산화가 이루어졌다.

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Development of Biological Denitrification Process Using Sulfur for the Wastewater Containing Low BOD (저농도 BOD함유 폐수의 황(S)을 이용한 생물학적 탈질공정 개발 (SPAD 공정))

  • 김인수;오상은;범민수;이성택;이창수;김민수
    • Environmental engineer
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    • s.183
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    • pp.70-77
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    • 2001
  • 우리나라 하수의 특성이 유기물 농도가 질소농도에 비하여 매우 낮기 때문에 외국의 종속영양 탈질 공법을 그대로 적용하기가 힘들며 적용한다 할지라도 외부탄소원을 넣어야 하므로 경제적인 처리는 불가능하다. 산업폐수의 경우에 있어서도 유기물농도가 질소농도에 비하여 낮은 폐수의 경우는 값비싼 외부탄소원을 넣어주어야 한다. 따라서 폐수 특성에 맞는 효율적이고 경제적인 질소 화합물 제거 기술의 개발은 불가피하다. 따라서 종속영양탈질공정의 경제성 문제 및 기존의 황탈

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