• Journal of the Korea Organic Resources Recycling Association
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• v.30 no.4
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• pp.5-13
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• 2022

The current environmental problem is that environmental pollution is accelerating due to the generation of large amounts of waste and indiscriminate consumption of energy. Fossil fuels, a representative energy production fuel, are burned in the process of producing energy, generating a large amount of greenhouse gases and eventually causing climate change. In addition, the amount of waste generated worldwide is continuously increasing, and environmental pollution is occurring in the process of waste treatment. One of the methods for simultaneously solving these problems is the energy recovery from and reduction of organic wastes. Sewage sludge generated in sewage treatment plants has been treated in various ways since ocean disposal was completely prohibited, but the amount generated has been continuously increasing. Since the sewage sludge contains a large amount of organic materials, it is desirable to recover energy from the sewage sludge and reduce the final discharged waste through anaerobic digestion. However, most of the excess sludge is a mass of microorganisms used in sewage treatment, and in order for the excess sludge to be anaerobically digested, the cell walls of the microorganisms must be destroyed first, but it takes a lot of time to destroy the cell walls, so high rates of biogas production and waste reduction cannot be achieved only by anaerobic digestion. Therefore, the pre-treatment process of solubilizing excess sludge is required, and the thermal solubilization process is verified to be the most efficient among various solubilization methods, and high rates of biogas production and waste reduction can be achieved by anaerobic digestion after destroying cell walls the thermal solubilization process. In this study, when pretreating TS 10% thickened excess sludge through a thermal solubilization system, a study was conducted on solubilization characteristics according to retention time and operating temperature variables. The experimental variables for the retention time of the thermal solubilization system were 30 minutes, 60 minutes, 90 minutes, and 120 minutes, respectively, while the operating temperature was fixed at 160℃. The soulbilization rates calculated through TCOD and SCOD derived from the experimental results increased in the order of 12.11%, 20.52%, 28.62%, and 31.40%, respectively. And the variables according to operating temperature were 120℃, 140℃, 160℃, 180℃, and 200℃, respectively, while the operating retention time was fixed at 60 minutes. And the solubilization rates increased in the order of 7.14%, 14.52%, 20.52%, 40.72%, and 57.85%, respectively. In addition, TS, VS, T-N, T-P, NH₄⁺-N, and VFAs were analyzed to evaluate thermal solubilization characteristics of thickened excess sludge. As a result, in order to obtain 30% or more solubilization rate through thermal solubilization of TS 10% thickened excess sludge, 120 minutes of retention time is required when the operating temperature is fixed to 160℃, and 170℃ or more of operating temperature is needed when the operating time is fixed to 60 minutes.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.37 no.12
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• pp.1079-1089
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• 2013

The flow characteristics in a solid particle incinerator are investigated numerically for high burning rate of wastes. The studied incinerator employs both a swirl flow used in the furnace of powerplants and a design concept applied to a rocket combustor. As the first step, the non-reactive flow field is analyzed in the incinerator with primary and secondary injectors through which solid fuel and air are injected. The deflection angle of a primary injector, inclination angle of a secondary injector, and gap between the two types of injectors are selected as design parameters. The swirl number is adopted for evaluating the degree of swirl flow and estimated over wide ranges of three parameters. The swirl number increases with deflection angle, but it is affected little by inclination angle. Recirculation zones are formed near the injectors, and their size affects the swirl number. The swirl number decreases with the zonal size of recirculation. From the numerical results, the design points can be found with strong swirl flow.

• Journal of computational fluids engineering
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• v.7 no.3
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• pp.17-26
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• 2002

Computational fluid dynamic(CFD) analysis has been frequently applied to the waste incinerators to understand the flow performance for various design and operating parameters. Since the computational modeling inevitably requires many simplifications and complicated sub-models, validity of the results should be carefully evaluated. In this study, major computational modeling and procedure of usual simulation methods for the grate-type waste incinerators were assessed. Usual simulation method does not explicitly incorporate the waste combustion, simply by assuming the combustion gas properties from the waste bed which is treated as an inlet plane. However, effect of this arbitrary assumption on the overall flow pattern is not significant, since the flow pattern is dominated by strong pattern of jet flows of the secondary air. Thus, this method is valid in understanding the effect of flow-related parameters. In analyzing the results, deriving conclusive information directly from temperature and chemical species concentration should be avoided, since the model prediction for the gaseous reaction and the radiation reveals significant discrepancies against the actual phenomena. Use of quantitative measures such as residence time is very efficient in evaluating the flow performance.

• Journal of Korean Society for Atmospheric Environment
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• v.33 no.5
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• pp.473-479
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• 2017

This study was designed to understand characteristics of oxy-combustion of coal, dried sewage sludge and solid refuse fuel (SRF). Thermogravimetric analysis was conducted by burning the fuels with air, 21% oxygen ($O_2$)/79% carbon dioxide ($CO_2$) and 30% $O_2/70%$ $CO_2$. Heating rates were varied as 5, 10, 25, 40 and $100^{\circ}C/min$. Complete coal combustion was found at the heating rates of 5, 10, 25 and $40^{\circ}C/min$, and different combustion behavior was found with the gas composition at the heating rates of 10, 25, 40 and $100^{\circ}C/min$. Coal combustion with 30% $O_2/70%$ $CO_2$ showed the highest while coal combustion with 21% $O_2/79%$ $CO_2$ showed the lowest combustion rate. On the other hand, the combustion of dried sewage sludge and SRF showed similar combustion behavior with respect to the combustion gas composition. This suggests that oxy-combustion of dried sewage sludge and SRF which contain a large amount of volatile matter may show similar combustion behavior to their air combustion.

• Transactions of the Korean hydrogen and new energy society
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• v.10 no.4
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• pp.233-243
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• 1999

Combustion characteristics of synthetic gas from flame pyrolysis gasification of polymetric wastes are reported and the applicability of synthetic gas from flame pyrolysis gasification to a gas engine system is presented. Engine power is easily predicted by the volume percentage of the synthetic gas. Measurements have been made to obtain the range of flame existence in the function of volume percentage of CO and $H_2$ gases in the synthetic gas. In order to clarify the emission of the flames, NOx measurements by chemiluminescent analyser are taken in flames with different equivalent ratios. From the results of the engine performance data we also have demonstrated that the output of the gas engine modified from a LPG engine is about 5 ps at normal rating. We conclude that synthetic gas from flame pyrolysis gasification of polymetric wastes is applicable to a gas engine system.

• Applied Chemistry for Engineering
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• v.29 no.1
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• pp.1-9
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• 2018

Microalgae is considered as one of environmentally sustainable and potential feedstocks to produce biodiesels. However, recent studies on life cycle assessments (LCA) of microalgal buidiesels have shown that energy requirement is not small to produce biodiesel from microalgae, especially during cultivation stage. The costs for carbon sources, nutrients like nitrogen or phosphorous, and water for cultivation can contribute up to 80% of the total medium costs. In the present article, recent trends on the utilization of several promising nutrient sources such as municipal wastewaters, organic fertilizers, combustion exhaust emissions and organic solid wastes were reviewed, and the potential strategies to be used as substitutes of artificial culture media, especially for the biodiesel production, were discussed.

• Resources Recycling
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• v.24 no.6
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• pp.17-23
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• 2015

Flue gas desulfurization(FGD) is the technique to remove $SO_2$ gas from stack gases of coal-fired plants. Many researcher have studied to replace the desulfurizing agent because FGD systems use a lot of limestone and energy. In this study, we use the limestone sludge which is a by-product of steel industry in order to replace desulfurizing agent of FGD system by control the particle size of limestone sludge. And desulfurization performance test is implemented by investigating $SO_2$ gas removal properties upon the characteristic of the limestone sludge with various particle size.

• Journal of the Korean Society of Industry Convergence
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• v.22 no.2
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• pp.105-110
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• 2019

Most titanium alloy waste with cutting oil was discarded without recycling process so that it can be caused by metal and oil fires. However, there is no fire management system and studies on the titanium or titanium alloy waste in spite of high fire risk. The purpose of this experimental study is to identify the fire risk of the titanium alloy waste with cutting oil. We collected the 120g waste which was made in the biomedical titanium alloy cutting process. The waste was burned and conducted thermal image analysis with infrared camera. The experimental results which illustrated the process, characteristics, and trends of fire are presented. Firstly, the cutting oil was burned and partially the titanium alloy waste was burned. The maximum temperature of the fire was more than $650^{\circ}C$ in some specific spots. These results means when a lot of titanium alloy waste with cutting oil was ignited, this fire could connect the titanium fire. In other words, the fire has a flammable liquid fire and combustible metal fire at the same time. The experimental study could be used fire prevention, response, and investigation of the titanium alloy waste.

• Korean Journal of Materials Research
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• v.33 no.10
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• pp.385-392
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• 2023

A solution combustion process for the synthesis of hollandite (BaAl₂Ti₆O₁₆) powders is described. SYNROC (synthetic rock) consists of four main titanate phases: perovskite, zirconolite, hollandite and rutile. Hollandite is one of the crystalline host matrices used for the disposal of high-level radioactive wastes because it immobilizes Sr and Lns elements by forming solid solutions. The solution combustion synthesis, which is a self-sustaining oxi-reduction reaction between a nitrate and organic fuel, generates an exothermic reaction and that heat converts the precursors into their corresponding oxide products in air. The process has high energy efficiency, fast heating rates, short reaction times, and high compositional homogeneity. To confirm the combustion synthesis reaction, FT-IR analysis was conducted using glycine with a carboxyl group and an amine as fuel to observe its bonding with metal element in the nitrate. TG-DTA, X-ray diffraction analysis, SEM and EDS were performed to confirm the formed phases and morphology. Powders with an uncontrolled shape were obtained through a general oxide-route process, confirming hollandite powders with micro-sized soft agglomerates consisting of nano-sized primary particles can be prepared using these methods.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.17 no.4
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• pp.375-387
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• 2019

In this study, the radiation dose rates for the design basis fuel of 360 assemblies CANDU spent nuclear fuel transportation cask were evaluated, by measuring radiation source terms for the design basis fuel of a pressurized heavy water reactor. Additionally, radiological safety evaluation was carried out and the validity of the results was determined by radiological technical standards. To select the design basis fuel, which was the radiation source term for the spent fuel transportation cask, the design basis fuels from two spent fuel storage facilities were stored in a spent fuel transportation cask operating in Wolsung NPP. The design basis fuel for each transportation and storage system was based on the burnup of spent fuel, minimum cooling period, and time of transportation to the intermediate storage facility. A burnup of 7,800 MWD/MTU and a minimum cooling period of 6 years were set as the design basis fuel. The radiation source terms of the design basis fuel were evaluated using the ORIGEN-ARP computer module of SCALE computer code. The radiation shielding of the cask was evaluated using the MCNP6 computer code. In addition, the evaluation of the radiation dose rate outside the transport cask required by the technical standard was classified into normal and accident conditions. Thus, the maximum radiation dose rates calculated at the surface of the cask and at a point 2 m from the surface of the cask under normal transportation conditions were respectively 0.330 mSv·h^-1 and 0.065 mSv·h^-1. The maximum radiation dose rate 1 m from the surface of the cask under accident conditions was calculated as 0.321 mSv·h^-1. Thus, it was confirmed that the spent fuel cask of the large capacity heavy water reactor had secured the radiation safety.