• Economic and Environmental Geology
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• v.17 no.4
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• pp.259-272
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• 1984

Fluid inclusion and stable isotope studies on the Sangdong tungsten skarn have led to a conclusion that the mineralizing fluids might be derived from a magma, which was inferred within 1km below the present Sangdong ore deposit. Mineral assemblages of the skarns appear to have formed under the equilibrium conditions as the fluids flow outward from a central fluid column, in which the quatz-mica occurs dominantly. A characteristic skarn showing mineralogical zonation by repeated over-prints. The quartz-mica zone at the central part of the Sangdong skarns shows the final stage of protracted fluid evolution. Thermodynamic conclusion based on simplified chemical compositions of major components may express quantitatively the conditions of the skarn formation by using diagrams.

• Proceedings of the Korea Contents Association Conference
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• 2006.05a
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• pp.351-355
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• 2006

The purpose of this study is to develop an efficient and useful equation of discharge measurement which can calculate easily discharge using only the surface velocity in both channels and rivers. The research results show: (1) Natural river have a propensity to establish and maintain an equilibrium state the corresponds to a value of the entropy parameter M; (2) Velocity distribution estimated by the method using surface velocity was compared with that of actual survey. It shows fairly close agreements between the estimated and the observed; (3) Developed equations for calculating the discharge using the surface velocity at the spot of the maximum velocity in a river section were established and show that the method of using fairly acceptable. An entropy based method for determining the discharge using only surface velocity in the rivers has been developed. The method presented is also efficient and applicable in estimating the discharge in high flows during the flood season that are very difficult or impossible to measure before, due to technical or theoretical reasons.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.11a
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• pp.221-224
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• 2008

A secant stiffness linear analysis method was developed for moment redistribution of moment-resisting frames. In the proposed method, rotational spring models are used for plastic hinges of the members whose flexural moments are needed to be redistributed. At the plastic hinges, secant stiffness is used to address the effect of the flexural stiffness reduced by inelastic deformation. Linear analysis is repeated with adjusted secant stiffness until the flexural equilibrium is satisfied in the structure and members. By using the secant stiffness analysis, the effect of the inelastic deformation on the moment redistribution can be considered. Further, the safety of plastic hinges can be evaluated by comparing the inelastic rotation resulting from the secant stiffness analysis with the rotational capacity of the plastic hinges. For verification, the proposed method was applied to a continuous beam tested in previous study. A application example for a multiple story moment-resisting frame was presented.

• Journal of Korean Society of Forest Science
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• v.82 no.1
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• pp.34-43
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• 1993

In this paper, the characteristics of cable logging operations are discussed from a standpoint of mechanics. An example of standing skyline operations is used to illustrate the mechanical principles. Using force and moment boundary conditions, the maximum allowable payload was formulated as a function of slope profile, system geometry and operation options. This formulation includes fundamental equations for log drag and single segment mechanics. The catenary link model is the basic assumption in simulating cable segment stretches. In order to demonstrate the solution procedures of the formulation, a computer model was developed. The model uses Secant algorithm to determine the solution of the complex nonlinear equation set. Finally, the computer model was demonstrated using a hypothetical data set.

• Journal of the Korean Geotechnical Society
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• v.19 no.5
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• pp.163-173
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• 2003

In this paper, a numerical comparison of predictions by limit equilibrium analysis and 3D analysis is presented for slope/pile system. Special attention is given to the coupled analysis based on the explicit finite difference code, FLAC 3D. To this end, an internal routine (FISH) was developed to calculate a factor of safety for a file reinforced slope according to shear strength reduction technique. The case of coupled analyses was performed for stabilizing piles in slope in which the pile response and slope stability are considered simultaneously. In this study, by using these methods, the failure surfaces and factors of safety were compared and analyzed in several cases, such as toe, middle and top of the slope, respectively. Furthermore, the coupled method based on shear strength reduction technique was verified by the comparison with other analysis results.

• Transactions of the Korean Society of Mechanical Engineers
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• v.9 no.1
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• pp.10-17
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• 1985

A new method is suggested for the solution of plane elasticity problems. With use of the dislocation model in the crack problems, the basic scheme of this method is to find equilibrium Burgers vectors of dislocations which are distributed along the boundary of the first fundamental boundary value problems. The stress distribution in the region can be found by superposition of the contributions of each dislocation. The method is applied to three cases with known analytical solutions, and to a V-notched specimen under uniaxial tension. The numerical results are compared with other available solutions. This method is effective and simple in its use, compared with other numerical methods. The method also provides very accurate solutions in the region except near the boundary where the discretization error is significant. The extrapolation method is suggested for the stresses in the boundary region. Extensive application are also suggested for a general estimate of the computational efficiency of the method.

• Journal of the Korean Chemical Society
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• v.30 no.2
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• pp.159-165
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• 1986

The effects of substituents, pressure and temperature on the dissociation constants of alkylpyrines(2, 3 and 4-methyl and ethyl) were studied by measuring the dissociation constants of pyridines by conductance method at various temperatures and pressures in aqueous solution. The constants were increased as the temperature increase but decreased as pressure increase. From the constants various thermodynamic properties were calculated and discussed the dissociation reactions. It was estimated that alkylpyridines have exceptional dissociation reactions.

• Journal of the Korean Chemical Society
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• v.32 no.5
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• pp.464-475
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• 1988

The complex formation of p-aminoazobenzene and its derivatives with Fe(III) and Mn(II) has been studied by UV and IR spectroscopy and conductometry. The effects of solvents, donor basicity, and other factors on the formation of these complexes have been examined. The vatio of metal to ligand for the complexes formed is 1 : 1, both in the solid state and in solution. The stability constants of Fe(III)-donor and Mn(II)-donor complexes are in the range of 10$^2$∼10$^4$ and 0.1∼1, respectively. The absorptivities are ~10$^4$ and ∼10$^3$ l/mol${\cdot}$cm respectively. Thermodynamic properties such as ${\Delta}H^{\circ}$, ${\Delta}G^{\circ}$ and ${\Delta}S^{\circ}$ are calculated from their stability constants utilizing Van't Hoff equation.

• 한국신재생에너지학회:학술대회논문집
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• 2007.11a
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• pp.445-448
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• 2007

석탄가스화 복합발전(IGCC)에서 석탄 가스화 기술이 전 공정의 성능에 큰 영향을 미치는 중요한 요소이다. 연료 및 산화제의 공급방식, 가스화기의 기본 구조, 벽면의 구성 방식, 용융 슬랙 및 생산되는 합성가스 배출 방식 등에 따라 가스화의 성능이 영향을 받는다. IGCC plant의 정확한 성능 해석을 위해서는 석탄가스화기 공정 모델의 정밀도를 높일 필요성이 있다. 기존의 열병합 발전 사이클 해석에서 적용되었던 열 및 물질정산과 평형계산 방식을 통하여 석탄가스화기 공정을 해석하는 방법을 확인, 정리하고 이를 개선하기 위한 절차 및 방안을 제시하고자 한다. 가스화기 내부 공정을 크게 탈휘발과 가스화의 단계로 구분하여 가스화기 출구조건을 예측하였으며, ASPEN PLUS를 이용한 공정해석을 실시하였다. 가스화기 출구에서의 합성가스는 주생성가스인 CO, $H_2$를 위주로 하여 조성을 얻을 수 있고, 그 결과들을 선행연구들과의 비교를 통하여 가스화기 모델의 분석을 실시한다. 그리고 가스화기 해석의 정밀도를 높이기 위한 향후 고려될 가스화기 모델에 관하여 논의한다.

• 한국신재생에너지학회:학술대회논문집
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• 2007.11a
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• pp.105-108
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• 2007

최근 세라믹 막은 우수한 화학적, 열적 안정성으로 기체 분리 공정에 각광을 받아왔다. 특히 혼합기체에서 고 순도의 수소를 분리해 내는 기술은 연료전지 공정에서 화학 에너지를 적기화학 에너지로 전환시키는데 중요한 역할을 차지한다. 본 연구에서는 MTES 템플레이팅 막을 이용하여 이 막 공정의 흡착 및 투과 특성을 규명하고, 이성분 혼합기체에서 고 순도의 수소를 추출해 낼 수 있는 최적 조건을 도출해 내었다. 또한, 기체 분리 거동을 살펴보기 위해 Gproms Simulator를 이용하였으며, 이때 기체상의 물질전달을 모사하기 위해 Dust Gas Model(DGM)을, 표면 확산 거동을 모사하기 위해 Generalized Stefan-Maxwell(GSM)식을 적용하였다. 이를 통해 평형론적 흡착 뿐 아니라 속도론적 흡착을 동시에 적용할 수 있게 하였다. MTES 템플레이팅 막의 흡착 및 분리능을 규명하기 위해 본 연구에서는 혼합기체의 투과, 분리 실험이 선행되었다. 실험 조건은 온도범위 $30{\sim}50$ $^{\circ}C$, 압력범위 $0{\sim}5$ atm에서 수행되었으며, 혼합기체는 2성분으로 수소 메탄, 수소-이산화탄소, 수소-질소로 기체의 구성비는 각각 50:50 이다. 본 연구를 통해 각 혼합 기체들이 정상상태에 도달하는 시간과 분리능을 계산해 내었으며, 이 분리능을 다시 온도와 압력에 따른 결과로 분석하여 어느 조건에서의 수소 분리도가 최고치를 보이는지를 규명했으며, 시뮬레이션과 비교, 대조하여 예측도를 검사하였다.