• Journal of the Korean Institute of Telematics and Electronics D
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• v.35D no.12
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• pp.30-40
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• 1998

We have calculated ultra-low energy silicon-self ion implantations and silicon damages through classical molecular dynamics simulation using empirical potentials. We tested whether the recently developed Environment-Dependent Interatomic Potential(EDIP) was suitable for ultra low energy ion implantation simulation, and found that point defects formation energies were in good agreement with other theoretical calculations, but the calculated vacancy migration energy was overestimated. Most of the damages that are produced by collision cascades are concentrated into amorphous-like pockets. Also, We upgraded MDRANGE code for silicon ion implantation process simulation. We simulated ultra-low energy boron ion implantation, 200eV, 500eV, and 1000eV respectively, and calculated boron profiles with silicon substrate temperature and tilt angle. We investigated that below 1000eV, channeling effect must be considered.

• Journal of the Korean Geophysical Society
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• v.5 no.4
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• pp.293-303
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• 2002

Applying elastic plate model, we estimated elastic thickness and rigidity of the lithosphere in southern part of the Korean Peninsula($332km{\times}332km$ area of which center is $36.5^{\circ}N$ in latitude and $127.5^{\circ}E$ in longitude) by analysing terrain data and gravity data measured up to 2002. We tried to exclude the East Sea in choosing the study area because it has different tectonic environment. The mean Moho depth was estimated to be 30 km by power spectrum analysis of gravity data in the study area, Assuming one layer crust and applying elastic plate model, the loads with wavelengths of greater than 300 km are locally compensated, loads with wavelengths in the range 80-300km are partially supported by the strength of the lithosphere, and loads with wavelengths of less than 80km are almost completely supported by lithospheric strength. Assuming crustal model and rigidity, we calculated predicted coherence and compared it with observed coherence. As a result, we wert able to estimate the effective elastic thickness to be of 15 km(corresponding flexural rigidity is $3.0{\times}10^{22}Nm$). This indicates that the crust of the study area is relatively weaker than other old and stable continental regions but is similar to continental margins or oceanic area. The low rigidity could be explained by many tectonic and thermal activities such as orogenic activities, magmatic intrusions, volcanic activities, foldings, faultings, etc.

• Applied Biological Chemistry
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• v.45 no.1
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• pp.30-36
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• 2002

A bioconcentration experiment was performed for killifish using nonradioactive and radioactive butachlor. At 0.036 ppm concentration, the highest bioconcentration ratio $(C_f/C_w)$ and BCF at steady state recorded as 296 and 87 respectively. And at 0.0036 ppm concentration, the highest $C_f/C_w$ ratio was 169 and the BCF was 51 at steady state. Considering the experimental variation of the BCF's, the BCF of butachlor was tentatively determined to be $69{\pm}28$. And the $^{14}C-butachlor$ and its metabolites depurated about 50% within 12 hours and 90% within 30 hours after depuration experiment started. And in vivo metabolites, designated as M-I, M-II, and M-III, were found in killifish and the excretes as butachlor was metabolised.

• Applied Chemistry for Engineering
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• v.24 no.3
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• pp.327-332
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• 2013

Batch experiments were carried out for adsorption equilibrium, kinetics and thermodynamic parameters of the brilliant brown R onto granular activated carbon. The operating variables studied were the initial dye concentration, contact time and temperature. Experimental equilibrium adsorption data were fitted to Langmuir and Freundlich adsorption isotherm by linear regression method. The equilibrium process was well described by Freundlich isotherm model and from the determined separation factor (1/n), granular activated carbon could be employed as an effective treatment for the removal of bismarck brown R. From kinetic experiments, the adsorption processes were found to confirm the pseudo second order model with a good correlation and the adsorption rate constant ($k_2$) increased with increasing adsorption temperature. Thermodynamic parameters like the activation energy, change of Gibbs free energy, enthalpy, and entropy were also calculated to predict the nature of adsorption in the temperature range of 298~318 K. The activation energy was determined as 8.73 kJ/mol for 100 mg/L. It was found that the adsorption of bismarck brown R on the granular activated carbon was physical process. The negative Gibbs free energy change (${\Delta}G$ = -2.59~-4.92 kJ/mol) and the positive enthalpy change (${\Delta}H$ = +26.34 kJ/mol) are indicative of the spontaneous and endothermic nature of the adsorption process.

• Journal of the Korean Chemical Society
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• v.54 no.5
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• pp.500-505
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• 2010

Two different dyes containing the same molecular weight but different chemical structure have been utilized for the study of thermodynamic parameters. In this study, {3-(4-(diethylamino)phenyl)-3-(1-ethyl-2-methyl-1H-indol-3-yl)isobenzofuran-1(3H)-one} (Blue 502) and {3-(4-(diethylamino)-2-methylphenyl)-3-(1,2-dimethyl-1H-indol-3-yl)isobenzofuran-1(3H)-one} (Blue 402) were used. It has been performed by measuring UV spectra of the two dyes. In general, the blue shift has been observed from both dyes in higher carbon number alcohol solvents. Interestingly, Blue 502 showed higher stability than Blue 402 in the same conditions used in this study. And, the equilibrium constants (0.9~1.0) of the dyes depending upon temperature change were also calculated using UV absorbance. The standard enthalpy calculated from equilibrium constants and molar absorptivity($\varepsilon$) are 10.94 kJ/mol in Blue 402 and 9.010 kJ/mol in Blue 502, respectively.

• Korean Chemical Engineering Research
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• v.43 no.4
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• pp.458-466
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• 2005

Full-scale utilizations of batch separation process often require knowledge about thermodynamics and correlation techniques of physical properties of complex mixture consisting of a great number of many unknown components. Various empirical correlations have been proposed to predict the physical properties mostly about the pseudocomponent of petroleum. In this study, one parameter correlations are developed for the calculations of the critical physical properties and ideal heat capacity of the pseudo-component of coal tar fractions. Developed model can provide a tool for the design and operations for the batch distillation of coal tar mixture.

• Bulletin of the Society of Naval Architects of Korea
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• v.26 no.1
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• pp.1-10
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• 1989

When a ship is travelling in following seas, the encounter frequency is reduced to be very low. n that case surf-riding, broaching-to and capsizing phenomena are most likely to occur. In the present paper, the emphasis is laid upon the transverse stability of ships in following seas, which is related to capsizing phenomenon. The authors intend to clarify the mechanism of the stability variation in following seas. In order to predict that variation, the theoretical calculation method and computer programming are developed. The theoretical calculation is based on Froude-Krylov Hypothesis and static equilibrium condition in waves. Through the application of present calculation method to cargo vessel and fishing boat, it is verified that the transverse stability in following seas with crest amidships can be reduced to a half extent in comparison with calm water stability. On the other hand, the present calculation results are compared with existing experimental data.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2017.05a
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• pp.1036-1037
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• 2017

This study investigated the aging reactions of three kinds of igniters(BKNO3, THPP, ZPP). The life-time of igniter depends on oxygen and moisture in the air. For example, Magnesium contained in the $BKNO_3$ reacts with oxygen and water to form oxide and hydrate. This reaction has an adverse effect on ignition reaction and could be information to analyze aging. Thermodynamic calculation could interpret the aging reaction by calculating flame temperature applying several variables(initial temperature, composition, etc.). If combustion is not completed because of aging igniters, flame temperature will be formed at a low range. The result of this research is expected to support the analysis of igniters aging reactions.

• Transactions of the Korean Society of Mechanical Engineers
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• v.5 no.3
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• pp.170-177
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• 1981

1,200.deg.C에서의 단조철은 점소성을 나타내며 인발과 압출시 변형영역이 구형수렴형태가 됨을 실험을 통하여 나타난다. 이 변형역 모델로부터 평형방정식을 사용하여 평균 압출 및 인발응력과 정수압을 계산해 낸다. 평균 압출 및 임발응력은 상계 해석 방법에 의한 결과와 비교하여 본 연구의 해석방법의 유효성을 타진하고 정수압은 다른 연구자들의 결과와 비교 검토되며 특히 냉간가공의 경우와 비교 검토 된다. 그 외에 마찰계수, 급형각도와 단면감소율의 영향에 대해서도 논의 된다.

• The Proceedings of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.11 no.4
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• pp.45-50
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• 1997

I본 논문은 저압 수은-아르곤 기체방전을 이용한 콤팩트 형광램프에 대한 모델링으로서 방전관 내 기체의 반경방향 입자밀도 변화를 고려한 입자평형식, 에너지보존식 및 회로방정식 등의 모델 방정식을 구성하여 이를 상용전원 구동회로와 결합한 13[W] PL 콤팩트 형광램프에 적용하였다. 계산된 전류와 램프전압의 실효치 및 파형을 실험치와 비교하여 모델이 타당함을 보였다.