• Title/Summary/Keyword: 평형도

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Measurement of Langmuir Adsorption Equilibrium by Elution-curve Method and Frontal Analysis (용출곡선법과 Frontal Analysis를 이용한 Langmuir 흡착평형식의 측정)

  • Choi, Yong Seok;Lee, Chong Ho;Row, Kyung Ho
    • Applied Chemistry for Engineering
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    • v.10 no.5
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    • pp.672-676
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    • 1999
  • Adsorption isotherm is the most fundamental information in adsorption separation-process. Directly from the elution profile of a peak, the elution-curve method and frontal analysis(FA) were utilized to measure the adsorption isotherm in this work. Using RP-HPLC, sample and the buffer added in mobile phase were 5'-GMP and sodium phosphate, respectively. In this experimental condition, the retention time was decreased with increase in the injected mass of sample. And the front part of a peak was very stiff, so Langmuir adsorption isotherm might be applied. By the elution-curve method, the parameters used in the isotherm were obtained by optimization method, while by the FA, the concentrations of stationary phase were measured from the elution curve and the isotherm was determined by regression analysis. Compared to FA, the consumption of sample was less, and only one or two injections were needed by the elution-curve method. Finally, the effect of concentration of sodium phosphate in mobile phase on the parameters of the isotherm was investigated.

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Comparison and Estimation of Equilibrium Constants for Deoxyribonucleosides by Plate Theory and Moment Method (단이론과 모멘트방법을 이용한 데옥시리보뉴클레오사이드의 평형상수의 계산 및 비교)

  • Lee, Ju Weon;Row, Kyung Ho
    • Applied Chemistry for Engineering
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    • v.8 no.3
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    • pp.403-409
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    • 1997
  • The equilibrium constants of five deoxyribonucleosides (dDyd, dUrd, dGuo, dThd, dAdo) were estimated by the plate theory and the moment method under isocratic conditions of the Reversed-Phase High Performance Liquid Chromatography (RP-HPLC). The mobile phase in this system was composed of water and organic modifiers(acetonitrile and methanol) The plate theory of linear adsorption isotherm was treated on the basis of continuous flow of eluent through the plates of the column. The moment method was utilized to find the equilibrium constant from the first absolute moment of experimental data. The equilibrium constants of five deoxyribonucleosides in the two methods were very close, and also the equilibrium constants calculated by capacity factor were similar to those by both the plate theory and the moment method. The equilibrium constant was expressed as a semi-log function of the quantity of organic modifier. Excellent agreements between the calculated elusion profile by the plate theory and the experimental data were observed.

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Radiative Properties of King Sejong Station in West Antarctica with the Radiative Transfer Model: Climate Change using Radiative Convective Equilibrium Model (대기 복사 모형에 의한 세종기지에서의 복사학적 특징: 복사 대류 평형 모형을 이용한 기후 변화 연구)

  • Lee, Gyu-Tae;Lee, Bang-Yong;Jee, Joon-Bum;Yoon, Young-Jun;Lee, Won-Hak
    • Journal of the Korean Geophysical Society
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    • v.9 no.1
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    • pp.27-36
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    • 2006
  • The radiative convective equilibrium (RCE) temperature was calculated for the climate change study at King Sejong Station in West Antarctica. As a result of RCE model sensitivity test, the increases of surface albedo, solar zenith angle, and cloud optical thickness decrease surface temperature. On the other hand, the increases of carbon dioxide and cirrus cloud amount are caused by surface warming due to the greenhouse effect. According to the model calculation result, annual mean surface temperature shows a upward trend of 0.012oC/year during the period of 1958-2001. During the period of 1989∼2001, the trend of monthly mean surface temperature by model calculation is 0.01oC/month and the observation trend is 0.005oC/month.

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A Re-examination of the Applicability of the Concept and Formulas of Equilibrium Riverbed Slope to River Engineering Practice (평형하상(平衡河床) 개념(槪念)과 공식(公式)의 하천실무(河川實務)에의 적용성(適用性)의 재고찰(再考察))

  • Woo, Hyo Seop;Yu, Kwon Kyu
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.12 no.2
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    • pp.101-108
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    • 1992
  • A careful re-examination has been conducted on the applicability of the concept of equilibrium riverbed slope to river engineering practice and on the validity of Aki's and Mononobe's formulas that are widely used in Korea for determination of equilibrium riverbed slope. A stream in equilibrium is one in which, over a period of years, slope is naturally adjusted to provide, with available water discharge and with prevailing channel characteristics, just the velocity required for transportation of the sediment load supplied from the upstream. The equilibrium riverbed slope is the bed slope of such river. The present river engineering practice to analyze the riverbed characteristics by applying so called 'the equilibrium riverbed slope formula' to such rivers, therefore, should be avoided. Also, the validities of Aki's and Mononobe's formulas, that are presently used for determination of stable channel slope, are very dubious and should not be used in river engineering practice.

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Design of a New Balanced Power Amplifier Utilizing the Reflected Input Power (입력단 반사전력을 이용하는 새로운 구조의 평형전력증폭기 설계)

  • Park, Chun-Seon;Lim, Jong-Sik;Cha, Hyeon-Won;Han, Sang-Min;Ahn, Dal
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.10 no.5
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    • pp.947-954
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    • 2009
  • This paper proposed a new balanced power amplifier using the reflected input of conventional balanced power amplifiers composed of branch line hybrid coupler. In general, the single-ended amplifier in balanced amplifiers does not have the perfect matching, so the reflected input power, in other words the leakage power, is terminated conventionally at the isolation port of hybrid coupler. However in this work, the leakage power is injected into the auxiliary amplifier, and its output power is combined to the output power of balanced amplifier. Therefore output power, efficiency, and 2-tone IMD3 performances of the proposed balanced amplifier are highly improved compared to the conventional balanced amplifier. For the verification of the proposed balanced amplifier, a conventional balanced amplifier and the proposed balanced amplifier are designed, fabricated and measured, and the measured results are compared. The proposed balanced amplifier shows the improvement in the output power(Pout), power added efficiency (PAE), and 2-tone IMD3 by 3dB, 5.2%, and $5{\sim}10dBc$, respectively, from the measurement.

The Prediction of Vapor-Liquid Equilibrium Data for Cyclohexanol-Cyclohexanone System at Subatmospheric Pressure (감압하에서 2성분 Cyclohexanol-Cyclohexanone계에 대한 기-액평형치의 추산)

  • Shim, Hong-Seub;Kim, Jong-Shik
    • Applied Chemistry for Engineering
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    • v.10 no.5
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    • pp.677-681
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    • 1999
  • For the binary cyclohexanol-cyclohexanone system the vapor-liquid equilibrium data, which are the necessary ones for the design of the distillation columns in separation process of volatile liquid-mixtures, are measured at subatmospheric pressure of 150, 300 and 500 mmHg. An empirical relation between logarithmic values of relative volatility(log $\alpha$) and liquid phase composition(x), which predicts the vapor-liquid equilibrium data, is obtained from above measured data of 150, 300 and 500 mmHg and the published ones of 30, 100, 200, 395 and 750 mmHg. The predicted data are compared with the measured and published ones to be in good agreement.

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Stability Analysis of TSK Fuzzy Systems (TSK퍼지 시스템의 안정도 해석)

  • 강근택;이원창
    • Journal of the Korean Institute of Intelligent Systems
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    • v.8 no.4
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    • pp.53-61
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    • 1998
  • This paper describes the stability analysis of TSK (Takagi-Sugeno-Kang) fuzzy systems which can represent a large class of nonlinear systems with good accuracy. A TSK fuzzy model consists of TSK fuzzy rules and the consequent of each fuzzy rule is a linear input-output equation with a constant term. There may exist equilibrium points more than one in the TSK fuzzy model and each equilibrium point rnay also have different nature of stability. The local stability of an equilibrium point is determined by eigenvalues of the Jacobian matrix of the linearized TSK fuzzy model around the equilibrium point. Stability of both the continuous-time and the discrete-time systems is analyzed in this paper.

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An Analysis of Long & Short Term Variation for Riverbed in the Moonsancheon (문산천의 장.단기 하상변동 분석)

  • Kang, Kyung-Seok;Park, Mun-Hyun;Kim, Seo-Young;Kim, Kook-Il;Park, Bong-Jin
    • Proceedings of the Korea Water Resources Association Conference
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    • 2006.05a
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    • pp.1535-1540
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    • 2006
  • 하천의 평형상태를 판단하기위해 필요한 두가지 관점은 첫째, 대상 하천이 현재 평형상태에 있는 가이고 둘째, 하천에 하상변동을 일으킬 수 있는 인위적인 영향을 가한 후에 하천반응을 통해 궁극적으로 결정되는 평형상태를 예측하는 것이다. 따라서 본 연구는 하도의 특성을 토대로 하여 현 하도의 평형상태를 정성적인 측면에서 검토하고, 흐름과 유사 이송에 관련된 수학모형을 수치적으로 해석하는 하상변동모형의 분석을 통한 현하도의 안정성 및 하상변동 양상을 파악하는데 그 목적이 있다. 본 연구는 임진강 유역의 충적하천인 문산천을 대상으로 지배유량을 산정한 후 지배유량 유하시의 마찰속도와 무차원 소류력 등의 하도특성량을 산정하여 토사이송이 크게 발생하는 구간을 정성적으로 예측하였다. 예측된 구간의 현장조사결과 $No.29{\sim}No.35$ 구간의 하상의 상승은 개수공사와 수해복구공사로 인한 인위적인 굴착에 대한 퇴적으로 하천이 평형상태로 환원하고자 하는 것으로 판단되었고, $No.41{\sim}No.54$ 구간의 하상저하는 문산천 상류구간의 큰 하상경사와 보의 영향인 것으로 조사되었다. 또한 1, 2차원 모형에 의한 장 단기 하상변동 분석결과 하도특성량을 이용한 하도의 안정성 평가와 유사한 결과를 보였다. 따라서 문산천의 경우 하상변동의 양상 파악 및 하도의 안정성 판단을 하는데 있어 하도특성량을 근거로 판단하는 방법의 적용가능성을 파악할 수 있었다.

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Common-Mode Suppression Balanced Filter based on Composite Right/Left-Handed Transmission Line (CRLH 전송선로를 이용한 공통 모드 억압 평형 필터)

  • Kim, Young;Yun, Jeong-Ho;Yoon, Young-Chul
    • Journal of Advanced Navigation Technology
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    • v.15 no.4
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    • pp.571-577
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    • 2011
  • This paper presents a novel balanced filter design based on a metamaterial structure applicable to differential-mode excitation. The metamaterial structure is based on a unit-cell which under a differential-mode excitation behaves like composite right/left-handed(CRLH) metamaterial with filter characteristics. In contrast, the metamaterial unit-cell is below cut-off under a common-mode excitation. Experimental results are used to verify the proposed metamaterial's differential-mode characteristics. The metamaterial is fabricated with a balanced filter design resulting in an operating frequency range of 960~1000 MHz with a insertion loss of 4.1 dB.

A Study on Developing Profit Model and Analyzing Validity for Remodelling of Apartment Houses (공동주택 리모델링의 수익모델 개발과 타당성 분석 연구)

  • Kim, Eui-Sik;Pyo, Ji-Myung;An, Min-Jae
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.8 no.4
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    • pp.257-264
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    • 2004
  • The physical factor having a great influence among components of making values of profit model in apartment houses is equilibrium change of house and this study suggests an alternative of remodelling. It sets profit models including model dividing household of large scale into that of small scale using value making factor of apartment house and spatial composition techniques and model integrating households of small scale and converting them into those of large scale and finds that its economy is good as over 'average', evaluative value of economy is reduced as discount rate increases and economy of remodelling is superior.