• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
• /
• v.6 no.1
• /
• pp.55-63
• /
• 2008

A swelling clay should remain physically and chemically stable for a long time to perform its functions as a buffer material of a high-level waste (HLW) repository. The longevity issues in the swelling clay were reviewed to evaluate their importance in the performance of a repository. The review results suggest that an elevated temperature due to decay heat, groundwater chemistry, high pH environment by concrete, organic matter and microbes, radiation, and mechanical disturbance might significantly affect the long-term performance of a swelling clay as a buffer material. This paper will be used as basic informations to design the swelling clay buffer for a HLW repository.

• Polymer(Korea)
• /
• v.35 no.1
• /
• pp.94-98
• /
• 2011

Poly(2-hydroxyethyl methacrylate), PHEMA, hybrid gels containing Pluronic and acrylic acid (AAc) were prepared as new biocompatible and stimuli-responsive hydrogels by photo-polymerization technique. The prepared hybrid gel showed reversible, temperature-responsive swelling behavior due to the presence of Pluronic component, which underwent sol-gel transition at an elevated temperature to cause gel shrinkage. The hydrogel also exhibited increased swelling degrees and pH-sensitivity due to the AAc component with ionizable carboxylic acid groups. The microporous gel morphology and its changes upon stimuli was observed by scanning electron microscopy.

• Membrane Journal
• /
• v.6 no.4
• /
• pp.227-235
• /
• 1996

poly(acrylic acid)(PAA)-poly(vinyl alcohol)(PVA) membranes have been prepared by crosslinking reaction between the carboxylic acid groups of PAA and the hydroxylic groups of PVA. In the measurements of the swelling and preferential sorption of the membranes, sorption behaviors of the membranes in pure water, pure acetic acid and a mixture of them have been investigated, respectively. From the measurements of the preferential sorption in 90wt% acetic acid of aqueous mixture, the sorption of water component was found to be more enhanced at high PAA content in the membrane than that of acetic acid component due to the interaction of water with acetic acid. The sorption behavior and the degree of crosslinking influenced competitively the permeation behavior of permeants. Permeation behavior of perrecants through the membranes was analyzed by using permeation activation energies which had been obtained from the Arrhenius plots of fluxes.

• Polymer(Korea)
• /
• v.37 no.4
• /
• pp.478-485
• /
• 2013

In this study, hydrogels with fast swelling and high absorbent properties were prepared using biopolymers approved as a food additive and their swelling properties were characterized. To improve the swelling properties of conventional hydrogels, we formed gas bubbles using a foaming agent in the process of preparing hydrogels and characterized in terms of equilibrium swelling ratio, swelling kinetics and cytotoxicity. In particular, alginate hydrogels observed by a digital microscope have an open-pore channels structure with the sizes of hundreds micrometers. Also, the cell viability of all hydrogels were found to be much higher than that of poly(acrylic acid).

• Proceedings of the KIEE Conference
• /
• 2006.07c
• /
• pp.1363-1363
• /
• 2006

PPLP를 절연지로 사용하는 OF 케이블 절연지의 팽윤 특성은 전력 케이블 절연특성에 크게 영향을 줄 뿐만 아니라, 케이블 제조나 운전시에도 영향을 미치므로 매우 중요한 설계 관리 요소이다. 특히 PPLP 케이블 제조시 PPLP의 팽윤 정도에 따라 지권장력의 설정이 달라지므로 반드시 고려해야만 한다. 기존의 일반적인 Kraft지를 절연지로 사용하는 OF 케이블의 경우는 팽윤 현상이 거의 없어 지권장력 설정시 이를 고려하지 않아도 되지만, PPLP는 이를 고려하지 않고 지권을 찬다면 케이블 제조 후 절연지의 끊어짐 현상, 절연층의 butt-gap 현상 둥 Polypropylene laminated paper를 절연지로 사용하는 케이블의 경우, 팽윤 현상의 발생으로 인해 절연파괴가 일어날 수 있다. 그러나 PPLP 절연지를 사용하는 이유는 케이블의 장거리 운전시 기존 Kraft지를 사용했을 때 보다 유전손실이 더 개선될 뿐만 아니라 절연체의 두께를 저감하여 포설이 용이하기 때문이다. 이에 본 논문에서는 PPLP에서 고분자의 팽윤이 일어나는 정도에 따라 결정화도의 변화와 전기적인 성능(체적저항, AC 파괴)과의 연관성을 검토하였다.

• Korean Journal of Food Science and Technology
• /
• v.28 no.3
• /
• pp.580-586
• /
• 1996

Gelatinization behavior and morphology of epichlorohydrin-crosslinked potato starches (XPs) were investigated. Native potato starch showed a very steep single stage swlling pattern, but crosslinked starches showed various patterns with the degree of crosslinking. Swelling power, solubility and light transmittance were reduced drastically as the degree of crosslinking increased. Brabender initial pasting temperature and peak temperature of crosslinked starches increased because the crosslinking reinforces the intermolecular net work of the starches. Although the swelling of the potato starch granule was inhibited by crosslinking as compared to that of the native one, Brabender peak viscosities (6.5% w/v, db) were on the order of 2,500 units for the native potato starch, 3,700 for the XP with 2.300 anhydroglucose units per crosslinking (AGU/CL) and 3,400 for the XP with 2,100 AGU/CL, due to the decreased breakdown of the swollen granule resulting from the resistance to heat and shear. The XP with 1,900 AGU/CL, however, did not show the peak viscosity and the viscosity was on the order of 500 units because of the excessive unhibition of the swelling. Unlike the native potato starch, 6.5%(m/v, db) pastes of the crosslinked potato starches could form gels, which could be predicted from the Brabender setback and consistency index. When the degree of crosslinking is low, random contraction and radial swelling of the granule was possible. As the degree of crosslinking increased, morphological change became similar to the single dimensional tangential swelling observed from the lenticular wheat starch. These morphological change during heating in excess water explained the gelatinization behaviors of crosslinked starches tested.

• Journal of the Korean Geotechnical Society
• /
• v.40 no.2
• /
• pp.29-40
• /
• 2024

This study aimed to evaluate the swelling behavior characteristics of KJ-II buffer blocks by performing numerical analysis of swelling pressure measurement experiments using the nonlinear elasticity model of COMSOL Multiphysics. The analysis was conducted under boundary conditions that included isotropic constraints and water injection pressure, mirroring the experimental settings. Validation of the numerical model was achieved by comparing its outputs with experimental results. The validated model was then used to simulate swelling deformations under unconfined conditions and to analyze swelling pressure as influenced by dry density and the geometric shape of the buffer material. The results accurately represented the swelling deformation observed during the saturation process and demonstrated that swelling pressure increases with higher dry density. Moreover, simulations concerning the geometric shape of the buffer material indicated a markedly faster rate of pressure increase in U-shaped samples compared to cylindrical ones. Analysis suggested that stress manifested preemptively near the internal edges of U-shaped samples during saturation. To enhance the simulation's fidelity to actual buffer material behavior, further refinement of the analysis model using a nonlinear elasticity model is recommended.

• Microbiology and Biotechnology Letters
• /
• v.14 no.5
• /
• pp.407-413
• /
• 1986

In an agitated bead reaction system, the enzymatic saccharification of uncooked starch was substantially enhanced. The enhancement mechanism was investigated front the view of the structural aspect of starch. The mechanical impact caused by the movement of the attrition-milling media resulted neither the destruction of microcrystalline structure nor the fragmentation of starch granule. instead, the most distinct phenomenon was the swelling of starch granule up to about 2.5 times, and the swelling mechanism was not similar with that caused by cooking. However, in the case of the enzyme addition in the attrition coupled reaction system, the swollen starch was easily fragmented into the large number of small particles by the synergistic action of the enzyme and milling-media. The exposed surface area of the fragmented particles plays the major role in enhancing the saccharification. The saccharification rate was quite different depending on the source of starch, the reason was discussed in terms of the granular structure of uncooked starches.

• Korean Journal of Food Science and Technology
• /
• v.33 no.1
• /
• pp.157-160
• /
• 2001

RS yields and swelling powers of cross-linked RS 4 starches and effects of RS 4 starches on the pasting profiles of RS 4 added wheat starch were measured using RVA. RS yields by AOAC method were different among RS 4 starches and RS levels were higher in low swelling RS 4 starches than moderate swelling RS 4 starches. Swelling power was different with botanical source of starch and preparing procedure of RS 4 starches. The pasting curves of RS 4 added wheat starches showed increasing initial pasting temperature and lower viscosity but the patterns were similar to those of wheat starch. The pasting viscosity pattern of RS 4 added wheat starches was related with swelling power of RS 4 starch.

• Journal of the Korean Wood Science and Technology
• /
• v.24 no.3
• /
• pp.57-64
• /
• 1996

제지공장에서 사용하는 습윤제는 물의 표면장력을 낮춤으로써 목재섬유가 물을 빨리 흡수하여 팽윤하도록 도와준다. 목재섬유가 물을 흡수하여 팽윤하는 과정을 밝히지 위한 연구가 많이 진행되어 왔지만 목재섬유와 물의 상호작용을 상세히 연속적으로 측정할 방법이 전에는 별로 없었다. 목재섬유가 팽윤할 때 발생하는 팽윤압력은 음향방사를 동반하기 때문에 이를 측정하여 팽윤과정을 알아내는 기술이 개발되었다. 본 연구에서는 이 방법을 이용하여 목재를 여러 농도의 습윤제에 담갔을 때 발생하는 음향방사와 중량증가를 측정하여 이 두 변량의 상관을 조사하고 이 방법이 목재의 습윤과정 연구에 유용하게 사용될 수 있는지를 조사하였다. 아까시나무와 라디에타 파인의 두 수종을 사용하였는데 두 수종의 흡수 형태는 매우 달랐다. 5분 동안 용액에 침지하였을 때 후자가 전자보다 10배 정도 더 많이 중량증가하였으며, 발생한 음향방사도 후자가 전자보다 훨씬 많았다. 아까시나무의 중량증가와 음향방사는 습윤제 농도에 거의 무관하였으나 라디에타 파인의 음향방사는 습윤제 농도의 증가에 따라 증가하였으며 라디에타 파인의 중량증가는 습윤제의 표면장력 변화와 일치하였다. 수종별 중량증가와 음향방사의 관계는 아까시나무가 음의 상관을 나타냈으나 라디에타 파인은 양의 상관을 나타내었다. 자비처리 시편은 무처리 시편보다 음향방사가 적었다.