• Title/Summary/Keyword: 팽윤율

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Anatomical and Physical Characteristics of Pinus densiflora Wood Damaged by Thecodiplosis japonensis Uchida et Inouye (솔잎혹파리 피해 소나무재의 해부 및 물리학적 특성)

  • Hwang, Won-Joong;Kwon, Goo-Joong;Lee, Chan-Young;Kim, Nam-Hun
    • Journal of Forest and Environmental Science
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    • v.17 no.1
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    • pp.37-46
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    • 2001
  • The objective of this work is to examine anatomical and physical characteristics of wood damaged by pine needle gall midge(PNGM, Thecodiplosis japonensis Uchida et Inouye) in Pinus densiflora. In anatomical characteristics, it was noted that the number of axial and radial resin canals in the damaged wood was higher than that in sound wood. In damaged wood, green moisture content of sapwood and swelling and shrinkage was higher than sound wood. Both longitudinal compressive strength and bending strength of the damaged wood were lower than those of sound wood. On the other hand, shearing strength of damaged wood was similar to that of sound wood.

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Preparation and Physical Properties of Blend Films of Natural Rubber and Chloroprene Rubber Latex (NR/CR 라텍스 블렌드 필름의 제조 및 물리적 특성)

  • Kim, Kong Soo;Park, Jun Ha;Eum, Ju Song
    • Applied Chemistry for Engineering
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    • v.7 no.4
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    • pp.691-697
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    • 1996
  • The NR films were prepared with mixing of natural rubber latex(NRL) with various additives, and NR/CR films were prepared by blend ratio of chloroprene rubber latex(CRL). The swelling degree and the mechanical properties of these films were measured according to the procure time. As a result, optimum condition were showed the swelling degree : 80~85%, precure time : 48~60hrs., and tensile strength was reduced but elongation was increased as increasing the blend ratio of CRL. On the mechanical properties of films prepared by different dipping process in these optimum condition, the tensile strength and tear strength of NR/CR films by one dipping process are better than NR-d-CR films by two dipping process. The surface of these films were observed with scanning electron microscopy(SEM). It was found that phase separation was occured as increasing the blend ratio of CRL.

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Development of 400 kV Oil-filled Power Cable and Joints Insulated with Polypropylene Laminated Paper (400 kV급 반합성지 전력케이블 및 접속함 개발)

  • Youn, B.H.;Kim, D.W.;Kim, J.N.;Kim, Seong-Yun;Lee, S.J.;Kim, J.S.;Shin, H.Y.;Lee, I.H.;Lim, C.H.;Park, W.K.
    • Proceedings of the KIEE Conference
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    • 2006.10a
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    • pp.155-157
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    • 2006
  • 송전전압이 점차 초고압화되면서 절연체의 유전특성을 개선하여 송전용량을 향상시키고, 절연내력을 높여 케이블 외경을 저감시키려는 시도에 따라 우수한 유전특성 및 절연내력을 갖는 폴리머 절연층과 기계적 특성, 절연유와의 적합성이 우수한 크라프트지의 장점을 혼합시킨 반합성지가 개발되어 전력케이블의 주절연재료로 사용되고 있다. 본 논문은 LS전선이 국내최초로 개발한 400 kV급 반합성지 전력케이블 및 접속함 개발과정 및 이와 관련된 요소기술에 대해 기술하였다. 송전시스템에서 요구되는 유전특성의 반합성지를 설계 제작하여, 기존 크라프트 절연지 대비 유전손실은 50% 수준, 절연내력은 125%이상의 반합성지를 개발하였고, 반합성지 고유의 특성인 팽윤율을 조절하여 케이블을 제조하였다. 반합성지 절연 케이블에 필요한 접속함에서는 보강절연재로 케이블과 동일한 반합성지를 사용하여 전체적인 3기를 감소시키고, 열저항성을 줄이고자 노력하였다. 또한, 접속함 조립공정에 필요한 저온연공법을 개발하여 반합성지에 열적 스트레스를 최소화하였다. 상기 관련기술의 개발 결과로, IEC 60141, AEIC CS2-97 및 NGTS 3.5.1에 근거하여 400 kV급 반합성지 OF 케이블 및 접속함에 대해 국제 공인기관인 KEMA의부터 Type Test을 인증받았다.

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Selective Adsorption Properties of Nitrate ion in Sulfate and Nitrate Solution by Bead and Fibrous Hybrid Ion Exchange Bed (비드와 섬유 혼성이온교환 베드를 이용한 황산이온과 질산이온 혼합용액에서 질산이온의 선택 흡착 특성)

  • 황택성;박명규
    • Polymer(Korea)
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    • v.27 no.1
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    • pp.69-74
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    • 2003
  • In this study, we have investigated the adsorption properties for nitrate ion in ground water using mixed resin type hybrid ion exchange (HIXF) and fiber type ion exchanger. Their swelling ratio (4.45 g/g) and ion exchange capacities (2.45 meq/g) were higer than the swelling ratio of IEC and IXF. Adsorption yield increased for nitrate $NO_3^-$ and sulfate $SO_4^{2-}$ ions were optimal at the concentration ratios of nitrate and sulfate below 1.0 and the adsorption yields were 100% and 20%, respectively. On the other hand it was shown that the degree of adsorpted for nitrate to pH 3, but it was little changed in the other pH range. We found that the selective adsorption capacity for nitrate was the optimal the mixing ratios of resin and fibrous ion exchanger of below 0.5.

Physical and Mechanical Properties of Major Korean Ash Species (한국산 물푸레나무속(屬) 주요 수종의 물리 및 역학적 특성)

  • Hwang, Won-Joong;Kwon, Goo-Joong;Kim, Nam-Hun
    • Journal of the Korean Wood Science and Technology
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    • v.30 no.2
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    • pp.95-101
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    • 2002
  • Physical and mechanical properties of major Korean ash species were examined. For Fraxinus rhynchophylla and Fraxinus sieboldiana, green moisture content of sapwood was almost the same value as heartwood. Heartwood of Fraxinus mandshurica, however, had slightly higher moisture content than sapwood. Green and oven dry densities of F. mandshurica were lower than those of F. rhynchophylla and F. sieboldiana. Swelling and shrinkage of sapwood in F. sieboldiana showed somewhat higher value than those of F. rhynchophylla. Longitudinal compressive strength and modulus of elasticity in F. sieboldiana were lower values than those in the other species. Shearing strength in radial section was higher than that in tangential section of all samples. It could be noted that shearing strength of F. sieboldiana demonstrated higher value than that of the other species. Three species had excellent bending properties in MOR and MOE. Impact bending absorbed energy for F. rhynchophylla and F. mandshurica did not show any significant differences.

Determination of Equilibrium Moisture Content of Outdoor Woods by Using Hailwood-Horrobin Equation in Korea (Hailwood-Horrobin 방정식을 이용한 한국의 야외 목재평형함수율 결정)

  • Ra, Jong-Bum
    • Journal of the Korean Wood Science and Technology
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    • v.42 no.6
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    • pp.653-658
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    • 2014
  • This research was carried out to investigate equilibrium moisture content (EMC) of wood in outdoor locations in Korea. EMC was calculated using Hailwood-Horrobin equation for 73 different locations in Korea using the 1981 to 2010 climate normal data obtained from the Korea Meteorological Admnistration (KMA). Daegu showed the lowest values of EMC (11.5), and the highest EMC values (15.8) was found in Heuksando. Considering the season effect, summer (June, July, August) showed the highest values 15.3, followed by autumn (September, October, November) 13.7, winter (December, January, February) 12.2, and spring (February, March, April) 12.0. Monthly EMC showed the lowest values 11.6 in April and July showed the highest EMC values 16.1. The smallest changes in monthly EMC were found in Jeju island and Heuksando showed the largest values 8.7. A proper wood drying based on average EMC is more required in the regions with larger variation in EMC.

Synthesis of Shape Reconfigurable Janus Particles by External pH Stimuli (산세기 조절을 통해 모양 변형이 가능한 야누스 입자의 제조)

  • Eom, Naye;Kim, Jongmin;Kang, Sung-Min;Lee, Chang-Soo
    • Clean Technology
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    • v.20 no.3
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    • pp.226-231
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    • 2014
  • This study presents a micromolding for the synthesis of Janus particles with reconfigurable shape by pH stimuli. First, we use acrylic acid (AA) as pH responsive monomer in the hydrophilic part and trimethylolpropane triacylate (TMPTA) in the hydrophobic part, respectively. The change of acidity in solvent induces the swelling of hydrophilic part in the Janus particles. The pH-responsive Janus particles show different swelling ratio of hydrophilic part in according to composition of acrylic acid in diverse range (0-70% v/v) and pH (3-11). As the concentration of acrylic acid in the hydrophilic part and environmental pH increase, the hydrophilic part in the Janus particles is proportionally swelled. Second, we fabricate novel type of Janus particles with two different hydrophilicities. As a proof of concept, we have applied acrylic acid (AA) and 2-(dimethylamino)ethyl methacrylate (DAEMA) into each part because the monomers provide reverse responsive activity. As expected, these Janus particles show different shape anisotropies with reconfigurable property in accordance with the polarity of each part at same acidity of environmental solvent. We envision that the stimuli responsive Janus particles have a wide application from fundamental science to diagnostic apparatus.

Effect of the Radiation Crosslinking and Heating on the Heat Resistance of Polyvinyl Alcohol Hydrogels (PVA 하이드로겔의 내열특성에 방사선 가교와 열처리가 미치는 효과)

  • Park, Kyoung Ran;Nho, Young Chang
    • Applied Chemistry for Engineering
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    • v.16 no.3
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    • pp.354-360
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    • 2005
  • Polyvinyl alcohol (PVA) hydrogels were prepared by the irradiation and heating. Irradiation and heating processes were carried out to improve the heat resistance of PVA hydrogels at high temperature. The physical properties such as gel content, degree of swelling and gel strength for the synthesized hydrogels were examined. The structure variations were investigated using the following techniques: differential scanning calorimetry (DSC) and X-ray diffraction (XRD). Gel content and gel strength of the hydrogels were higher when the two steps of irradiation followed by heat treatment were used rather than only with the irradiation. The hydrogels prepared by the irradiation and the two steps had good heat resistance at high temperature.

The Effect of Fines on the Property of High Yield Pulp (미세섬유(微細纖維)가 고수율(高收率)펄프의 지질(紙質)에 미치는 영향(影響))

  • Cho, Nam Seok
    • Journal of Korean Society of Forest Science
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    • v.57 no.1
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    • pp.14-19
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    • 1982
  • Fines in high-yield sulfite pulp have much higher water retention value as compared with fines in Stone groundwood pulp. Therefore, they are apt to adhere partially or entirely onto the fiber surface during the paper making. This tendency is greatly enhance with decrease of the pretreated yield and increase of the water retention value of fines. Fines, which adhere onto the fiber surface in paper, contribute to the light scattering of the paper. Accordingly, the specific scattering coefficient of fines in high-yield sulfite pulp is considerably lower than that of fines in stone groundwood pulp, which hardly adhere onto the fiber surface. The fact that high-yield sulfite pulp is inferior to stone groundwood pulp in opacity is explained on the basis of the high degree of swelling of fined in addition to the softening of fiber fraction.

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Synthesis of PVA/PVP Hydrogel by Irradiation Crosslinking (방사선 가교에 의한 PVA/PVP 하이드로겔 제조 및 드레싱에의 응용)

  • 김태훈;노영창
    • Polymer(Korea)
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    • v.25 no.2
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    • pp.270-278
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    • 2001
  • Hydrogels for wound dressing were manufactured using poly(vinylalcohol)(PVA) and poly(N-vinylpyrrolidone)(PVP). The hydrogels were obtained by exposing to $^{60}$ Co${\gamma}$-rays after freezing and thawing of aqueous solutions of PVA and PVP to improve mechanical strength. Mechanical properties such as gelation, water absorptivity and gel strength were examined after repeating the \"freezing and thawing\" of PVA/PVP hydrogels, and then irradiating them at 40 kGy. The PVA/PVP ratio was in the range of 30:70 ~ 100:0, and the solid concentration of PVA/PVP was 20 wt%. The gelation and strength of hydrogels were much higher when \"freezing and thawing\" and the irradiation process were used than when only the irradiation process was utilized. In addition, the mechanical properties of PVA/PVP hydrogels after repetition of \"freezing and thawing\" are discussed. thawing\" are discussed.ssed.

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