• Journal of the Korean Chemical Society
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• v.55 no.3
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• pp.346-353
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• 2011

Base hydrolysis of 7-hydroxy-2H-chromen-2-one (HC) and 7-hydroxy-2H-chromen-2-one-4-acetic acid (HCA) in aqueous-methanol and aqueous-acetone mixtures were studied kinetically at temperature range from 283 to 313 K. The activation parameters of the reactions were evaluated and discussed. Moreover, the change in the activation energy barrier of the investigated compounds from water to water-methanol and water-acetone mixtures was estimated from the kinetic data. It is observed that the change in activation barriers is more or less the same for the hydrolysis of HC and HCA. Base hydrolysis of HC and HCA follows a rate law with $k_{obs}=k_2[OH^-]$. The decrease in the rate constants of HC and HCA as the proportion of methanol or acetone increases is due to the destabilization of $OH^-$ ion. The high negative values of entropy of activation support the proposal mechanism, i.e. the investigated reaction takes place via the formation of an intermediate complex. Moreover, these values refer to the rigidity and stability of the intermediate complex. Thus, the ring opening of the intermediate complex would be the rate controlling step.

• Journal of Advanced Marine Engineering and Technology
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• v.39 no.6
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• pp.633-641
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• 2015

Several complex processes that are employed in industries, such as shipping, power plants, and the petrochemical industry, involve time-varying behavior as well as strong nonlinear behavior during operation. The fixed-parameter proportional-integral-derivative (PID) controllers have difficulty in dealing with control problems that occur in such processes. In this paper, we propose a method of designing a nonlinear PID controller for industrial processes that exhibit a large number of nonlinearities and time-varying behavior. The gains of the nonlinear PID controller are characterized by a simple nonlinear function of the error and/or error rate depending on the process set-point and output. We tune the user-defined parameters using a genetic algorithm by minimizing the integral of time absolute error (ITAE) index. We verify the effectiveness of the proposed method by performing a comparison of the proposed method and two other nonlinear and adaptive methods that are employed for reference tracking, disturbance-rejection performances, and robustness to parameter changes on a continuously stirred tank reactor.

• Journal of Oral Medicine and Pain
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• v.30 no.4
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• pp.427-432
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• 2005

This study have been compared and analyzed voice parameter under the condition of normal voice and auditory condition(noise and music) for 29 patients of orofacial pain and 31 normal people to investigate voice feature and vocal variation for auditory condition of orofacial pain patient. 1. Compared to normal voice, orofacial pain patient showed lower and unstable voice feature which has low F0 rate and high jitter and shimmer rate. 2. Voice of orofacial pain patient showed more relaxed and stable voice feature with low F0 and shimmer rate in the music condition than noise condition. 3. Normal people's voice has no significant difference between music and noise condition even though it has high F0 rate under the noise condition. As a result, orofacial pain patient showed difference of feature and different response for external auditory condition compared to normal voice. Providing of positive emotional environment such as music could be considered for better outcome of oral facial pain patient's functional disability.

• Geophysics and Geophysical Exploration
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• v.7 no.3
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• pp.174-183
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• 2004

The knowledge of rock strength is important in assessing wellbore stability problems, effective sanding, and the estimation of in situ stress field. Numerous empirical equations that relate unconfined compressive strength of sedimentary rocks (sandstone, shale, and limestone, and dolomite) to physical properties (such as velocity, elastic modulus, and porosity) are collected and reviewed. These equations can be used to estimate rock strength from parameters measurable with geophysical well logs. Their ability to fit laboratory-measured strength and physical property data that were compiled from the literature is reviewed. While some equations work reasonably well (for example, some strength-porosity relationships for sandstone and shale), rock strength variations with individual physical property measurements scatter considerably, indicating that most of the empirical equations are not sufficiently generic to fit all the data published on rock strength and physical properties. This emphasizes the importance of local calibration before one utilizes any of the empirical relationships presented. Nonetheless, some reasonable correlations can be found between geophysical properties and rock strength that can be useful for applications related to wellhole stability where haying a lower bound estimate of in situ rock strength is especially useful.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.39 no.1
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• pp.89-95
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• 2015

A surge phenomenon cause noise and pulsations in a turbo compressor, which is an unstable operating regime. Because surge protection ensures a safe compressor operation, it is important to understand the physics of the surge phenomenon. In this study, the surge characteristics of a 250-hp class turbo-compressor were evaluated experimentally. The experimental parameters were the rotational speed, opening angles of the inlet guide vane and exit valve, and inlet pipe diameter and flow rates of the inlet gases. The results showed that the compressor surge was very sensitive to the gas flow rates, exit pressure, rotational speed, and bypass flow rates.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2018.05a
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• pp.457-459
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• 2018

Solar power generation system is a energy generation technology that produces electricity from solar power, and it is growing fastest among renewable energy technologies. It is of utmost importance that the solar power system supply energy to the load stably. However, due to unstable energy production due to weather and weather conditions, accurate prediction of energy production is needed. In this paper, an Artificial Neural Network(ANN) that predicts solar energy using 15 kinds of meteorological data such as precipitation, long and short wave radiation averages and temperature is implemented and its performance is evaluated. The ANN is constructed by adjusting hidden parameters and parameters such as penalty for preventing overfitting. In order to verify the accuracy and validity of the prediction model, we use Mean Absolute Percentage Error (MAPE) and Mean Absolute Error (MAE) as performance indices. The experimental results show that MAPE = 19.54 and MAE = 2155345.10776 when Hidden Layer $Sizes=^{\prime}16{\times}10^{\prime}$.

• The Journal of the Acoustical Society of Korea
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• v.32 no.5
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• pp.408-414
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• 2013

The famous filtered-x least mean square (FxLMS) algorithm for active noise control (ANC) systems may become unstable in non-stationary noise environment. To solve this problem, Sun's algorithm and Akhtar's algorithm are developed based on modifying the reference signal in update of FxLMS algorithm, but these two algorithms have dissatisfactory stability in dealing with sustaining impulsive noise. In proposed algorithm, probability estimation and zero-crossing rate (ZCR) control are used to improve the stability and performance, at the same time, an optimal parameter selection based on fuzzy system is utilized. Computer simulation results prove the proposed algorithm has faster convergence and better stability in non-stationary noise environment.

• Journal of the Korean Society of Propulsion Engineers
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• v.21 no.5
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• pp.46-53
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• 2017

This paper deals with an acoustic model for a lean premixed gas turbine combustor composed of three stages: premixing chamber, nozzle and flame tube. Our model is given as an acoustic transfer function whose input is a heat release rate perturbation and output is a velocity perturbation at a flame location. We have shown that the resonance frequencies are functions of three round-trip frequencies of acoustic wave in each stage, and area ratios between stages. By analyzing poles of the acoustic transfer function, we could characterize resonant frequencies and their dependency on various system parameters of a combustor. It was found that our analytic findings match with existing numerical and experimental results in literature.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2008.11a
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• pp.178-178
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• 2008

ZnO 바리스터는 인가되는 전압에 따라 저항이 변하는 전압 의존형 저항체이며 각종 전기 전자 정보통신용 제품에 정전기(ESD) 대책용 소자로 폭 넓게 사용되는 전자 세라믹스 부품이다. 특별히 Bi-based ZnO 바리스터는 다양한 상(phase)으로 구성되어 있으며 그 입계의 전기적 특성은 소량 첨가되는 dopant의 종류에 따라 다양하게 변하는 것으로 알려져 있다. 본 연구에서는 Bi-based ZnO 바리스터 (ZnO-$Bi_2O_3$, ZnO-$Bi_2O_3-Mn_3O_4$)에서 각종 유전함수$(Z^*,M^*,\varepsilon^*,Y^*,tan{\delta})$를 이용하여 입계의 주파수-온도에 대한 특성을 살펴 보았다. 일반적인 ZnO 바리스터 제조법으로 시편을 제작하여 78K~800K 온도 범위에서 각종 유전함수를 이용하여 복소 평면도(complex plane plot)와 주파수 응답도(frequency explicit plot)의 방법으로 defect level과 입계 특성(활성화 에너지, 정전용량, 저항, 입계 안정성 등)에 대하여 고찰하였다. ZnO-$Bi_2O_3$(ZB)계와 ZnO-$Bi_2O_3-Mn_3O_4$(ZBM)계 모두 상온 이하의 온도에서 $Zn_i$와 $V_o$의 결함이 나타났으며, 이들의 결함 준위는 각 유전함수에 따라 다소 차이가 났다. 입계 특성으로 ZB계는 이상구간(560~660K)을 전후로 1.15 eV $\rightarrow$ 1.49 eV의 활성화 에너지의 변화가 나타났지만, ZBM계는 이러한 현상이 나타나지 않았다. 또한 입계 전위 장벽의 온도 안정성에 대해서는 Cole-Cole model을 적용하여 분포 파라미터 (distribution parameter; $\alpha$)를 구하여 고찰하였다. ZB계의 입계 안정성은 온도에 따라 불안정해 졌지만, ZBM계는 안정하였다.

• Journal of Advanced Marine Engineering and Technology
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• v.38 no.6
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• pp.710-715
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• 2014

This paper investigates the design scheme of fuzzy-based adaptive controller to give adaptability for controlling nonlinear systems. For this, a nonlinear system is linearized by the several subsystems depending on the operating point or parameter changes. Then, the sub-controller is designed by linear control scheme for each subsystem and the sub-controllers are fused with each gain of sub-controllers using fuzzy rules. The proposed method is applied to an inverted pole system which has structurally instability and nonlinearity, and simulation works are shown to illustrate the effectiveness by comparison with the interpolation-based adaptive Controller.