• Title/Summary/Keyword: 티탄철석

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Petrography and mineral chemistry of Fe-Ti oxides for the Mesozoic granitoids in South Korea : a reconsideration on the classification of magnetite- and ilmenite-series (남한의 중생대 화강암의 Fe-Ti 산화광물에 대한 암석기재와 광물화학: 계열분류에 대한 재고찰)

  • 조등룡;권성택
    • The Journal of the Petrological Society of Korea
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    • v.3 no.1
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    • pp.1-19
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    • 1994
  • We present petrography, mode and chemistry data for Fe-Ti oxide minerals from the Mesozoic granitoids in South Korea. Magnetites from the Daebo Uurassic) granites are nearly pure $Fe_3O_4$, while those from the Bulgugsa (Cretaceous) granites contain considerable amounts of Mn and Ti. This is probably related to rapid cooling of the Bulgugsa granites compared with slow cooling of Daebo granites, which is supported by geologic relations and hornblende geobarometry results of Cho and Kwon (1994) on the emplacement depth for these granites. The composition of ilmenite does not shew appreciable difference between the Daebo and Bulgugsa granites. However, $Fe_2O_3$ contents are higher for the ilmenites coexisting with magnetite than for those without magnetite. In the temperature vs. oxygen fugacity diagram, the Bulgugsa granites plot near Ni-NiO and QFM buffer curves, although only two samples show greater than the granite solidus temperature. The mode data suggest that both magnetite- and ilmenite-series exist in Daebo and Bulgusa granites from the Kyonggi massif, Ogcheon belt and Youngnam massif, while only magnetite-series exists in Bulgugsa granites from the Kyongsang basin. Many ilmenite-series granites occur in the Ogcheon belt, which might be related to assimilation of carboniferous sediments in the belt. The proportion (44 : 56) between ilmenite- and magnetite-series for the Daebo granites is significantly different from that of Ishihara et al. (1981) who showed, using magnetic susceptibility data, predominance of ilmenite-series (more than 70%) for the Daebo granites, which can be mainly attributed to preference in sampling and to wrong assignment of age for some plutons. We also found magnetite in weakly-magnetized Kanghwa granite which was formerly classified as ilmenite-series by Ishihara et al. (1981). The proportion of ilmenite-series increases in the order of hornblende biotite granite, biotite granite and two mica granite. We conclude from these observations that the ilmeniteseries granites might have originated from contamination of carboniferous crustal material and/or such source material.

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Changes on Physical Property of Ilmenite due to Microorganism (미생물에 의한 티탄철석의 물리적 특성 변화)

  • Park, Young Ho;Kang, Dae Wan;Kang, Seong-Seung
    • Tunnel and Underground Space
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    • v.22 no.5
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    • pp.321-329
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    • 2012
  • Laboratory tests for measuring absorption, porosity, P-wave velocity and uniaxial compressive strength (UCS) were performed to examine weathering characteristics of ilmenite by microorganism. Physical property changes were quantitatively estimated with comparing culture period on the condition of abiotic oxidation without microorganism and biooxidation with microorganism. As a result, the measured pH during 45 days was distributed in the range from 3.82 to 4.26, on the other hand, biooxidation showed the range from 2.20 to 2.57. The measured absorption according to microorganism and culture period represented 0.052% at final stage in the case of abiotic oxidation and 0.073% in the case of biooxidation. Porosity showed 0.206% at final stage in the case of abiotic oxidation and 0.281% in the case of biooxidation. In general, the values by biooxidation showed higher than that by abiotic oxidation. Change range of P-wave velocity with culture period showed that the measured value as 1410 m/s at final stage in the case of biooxidation was lower than 1886 m/s of that in the case of abiotic oxidation. The UCS was decreased with increasing culture period in all specimens and represented 241.1 MPa at final stage in the case of abiotic oxidation and 140.0 MPa in the case of bioxidation. In conclusion, it implies that influence of physical property on ilmenite by biooxidation related with microorganism was larger than that by abiotic oxidation.

Iron-bearing Minerals in the Kaolin from Hadong-Sancheong Area (하동-산청 고령토 중의 함철광물 연구)

  • 김수진
    • Journal of the Mineralogical Society of Korea
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    • v.1 no.1
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    • pp.1-14
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    • 1988
  • 최근 국내에서의 고령토의 다양한 공업적 이용추세는 다량의 고품위 고령토를 필요로 하게 되었다. 그러나 하동-산청지역의 고령토 광석은 저품위가 대부분인 반면 그 양은 막대하다. 고령토의 저품위 현상은 산화철광물과 함철 규산염광물등 고령토 이외의 광물들이 고령토 광석에 다량 함유된데 기여한다. 그릴제거, 자력분리 및 디티오나이트에 의한 침출등 종래의 정제 방법에 의하여 제작된 고령토 정광에는 아직도 상당량의 철분이 함유되어 있어서 정광의 품위가 높지 않다. 고령토 광석으로부터 분리해낸 순수한 할로이사이트는 평균 Fe2O3 0.4%를 함유하고 있으며 이 철분은 할로이사이트내에 구조철로 함유되어 있다. 고령토에 함유되어 있는 함철광물로는 산화광물(적철석, 자철석, 침철석, 티탄철석)과 규산염광물(감섬석, 버미큘라이트, 일라이트, 녹니석)이 있다. 종래의 정제방법으로는 대부분의 산화철광물들은 제거 되었지만 버미큘라이트(Fe2O3 0.9%)와 일라이트 (Fe2O3 1.2%)는 고령토 정광에 계속 남아 있어서 저품위 정광이 되고 있다. 버미큘라이트와 일라이트의 함유가 주로 고령토 정광의 저품위의 원인이 되고 있기 때문에 고품위 고령토 정광을 생산하기 위해서는 이들 두 광물을 제거해야 한다.

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Effect of Cooling-rate Dependence on the Magnitude of Thermoremanent Magnetization (냉각률이 자화에 미치는 영향)

  • Yu, Yong-Jae
    • 한국지구물리탐사학회:학술대회논문집
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    • 2010.10a
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    • pp.43-45
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    • 2010
  • Acquisition of thermoremanent magnetization follows a Boltzman statistics, as such long reaction time in a slowly cooled environment allows more chance to align individual magnetic particles parallel to the external magnetic field. Hence it has been proposed that the slowly cooled rocks often acquire stronger magnetization than the rapidly cooled ones. Such a proposition has been experimentally validated to be true for the fine-grained magnetite- or titanomagnetite bearing basaltic rocks collected from the mid-ocean ridges. However, the effect of cooling-rate on the remanence intensity appears to be insignificant for nominal grain ranges.

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Separation and Mineralogy of Marine Sand Near Haeju bay, North Korea (북한 해주만 부근 해사의 선별 및 광물학적 특성)

  • Chae, Soo-Chun;Shin, Hee-Young;Bae, In-Kook;Kwon, Sung-Won;Lee, Soo-Jung;Kim, Wan-Tae;Lee, Chun-Oh;Jang, Young-Nam
    • Journal of the Mineralogical Society of Korea
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    • v.22 no.3
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    • pp.217-227
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    • 2009
  • Heavy minerals in the marine sand near Haeju bay, Hwanghae-do, North Korea were separated using the gravity and the magnetic separators. And their mineralogical study was carried out. Ilmenite, magnetite, hematite, zircon and monazite were observed as the valuable minerals, and quartz, orthoclase, muscovite, hornblende and garnet existed as gangue minerals. In the result of quantitative analysis with SIROQUANT program, the contents of the valuable minerals separated with the 2nd gravity separation (the shaking table separation), the 1st magnetic separation (rare earth magnetic separation) and the 2nd magnetic separation (the Eddy current magnetic separation) were increased into 4%, 10% and 76~89% (under the condition of 7000 G and 10000 G in magnetic strength), respectively. The contents of ilmenite, monazite and zircon recalculated from the chemical composition differed from the results of the quantitative analyses by SIROQUANT program, but the entire tendency bears some analogy with it. Under the conditions of 7000 G and 10000 G in 2nd magnetic separation the contents of ilmenites were concentrated with 53% and 66%, respectively. The content of monazite was 1.2% in the magnetic fractions of the 1st magnetic separation. The content of zircon was shown 1.4% under the condition of 10000 G in the 2nd magnetic separation, and was displayed 9% in +50 mesh of non-magnetic fraction of 1st magnetic separation, especially.

Occurrence and Deformation of Fe-Ti ores from the Proterozoic Hadong Anorthosites, Korea (원생대 하동회장암체 내 철-티탄 광체의 산상과 변형)

  • Jung, Jae-Sung;Kim, Jong-Sun;Cho, Hyeong-Seong;Song, Cheol-Woo;Son, Moon;Ryoo, Chung-Ryul;Chi, Sei-Jeong;Kim, In-Soo
    • The Journal of the Petrological Society of Korea
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    • v.19 no.1
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    • pp.31-49
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    • 2010
  • Nearly NS-trending Fe-Ti ore bodies intermittently occur in the Hadong anorthosites, south Korea, irrespective of the rock types of the anorthosites. In order to determine their occurrence mode and deformation history, we collected the features of occurrence and geological structures in the field, petrographic features using thin sections of the principal constituent rocks, and geochemical data of ilmenites in the ore body using electron probe microanalysis. Fe-Ti ore bodies examined in this study are divided into two types: dike- and lamina-types. It is steadily supported that the dike-type has intruded into the anorthositic rocks after their emplacement and solidification. And the laminar-type is probably a result of the mylonitization and transposition of the dike-type ore bodies parallel to the shear planes, due to later strong dextral ductile shearing. In the meantime, the Fe-Ti ore bodies have experienced the stronger dextral shearing in the more northern part of the study area, i.e. Cheongryong-ri, Wolhoeng-ri, Jonghwa-ri, and Jayangri and Baekun-ri in ascending order of its strength, together with the less content of $TiO_2$. All ilmenites of the ore bodies have very similar chemical composition, as pure ilmenite of 52~55 wt.% in $TiO_2$ content, irrespective of the occurrence mode and degree of later ductile shearing of the ore bodies. And they didn't experience to exsolve into magnetite. The structural data indicate that the Hadong anorthosites have deformed by NNE-trending folding, intrusion of the Fe-Ti ore bodies, NNW~NNE-trending dextral ductile shearing, NW~NNW-trending sinistral semi-brittle shearing, and intrusion of NNE~NE-trending mafic dykes in descending order of chronology after the formation of foliation of the anorthositic rocks. The foliation is interpreted as a result of the accumulation of crystals that settle out from the magma by the action of gravity.

Mineralogy of Sea Sand Near Ongjingun through the Separation Processes (옹진군 해사의 선별공정에 따른 광물학적 특성)

  • Chae, Soo-Chun;Shin, Hee-Young;Bae, In-Kook;Kwon, Sung-Won;Lee, Chun-Oh;Kim, Jung-Yoon;Jang, Young-Nam
    • Journal of the Mineralogical Society of Korea
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    • v.24 no.1
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    • pp.1-17
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    • 2011
  • Mineralogical study was carried out for heavy minerals in the sea sand near Ongjingun bay, Kyonggi-do separated using the gravity and magnetic separators. Ilmenite, zircon and minor monazite and garnet were valuable minerals with gangue minerals of quartz, K-feldspar, plagioclase, muscovite, hornblende, epidote and chlorite. Quantitative analysis with SIROQUANT program showed that the contents of ilmenite separated with the gravity separation (the shaking table separation), the 1st step magnetic separation (rare earth magnetic separation) and the 2nd step magnetic separation (the Eddy current magnetic separation) were increased into 0.8, 18.3, and 48.7%, respectively. The content of ilmenite, monazite and zircon were recalculated based on the chemical composition of the representative and heavy fraction products of raw sand, the 1 step and 2 step gravity separations, and the 1 step and 2 step magnetic separations. The content increased to 0.23, 0.55, 5.22, 16.17, and 44.99% in ilmenite, 0.11, 0.02, 0.16, 0.51, and 1.19% in monazite. Although the zircon content did not differ over the processes (0.13, 0.12, 0.11, 0.15, and 0.10%), the improved recovery of zircon is expected by applying sieving process because of its high content (27%) in the fine grain size fraction (< 140#) of the 2 step gravity separation.